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    • 91. 发明申请
    • SEMICONDUCTOR DEVICE FABRICATION PROCESS
    • 半导体器件制造工艺
    • WO99060620A1
    • 1999-11-25
    • PCT/US1999/009392
    • 1999-04-29
    • H01L21/28H01L21/302H01L21/304H01L21/306H01L21/3065H01L21/311H01L21/336
    • H01L21/0206H01L21/31116H01L21/31138H01L29/665H01L29/6656H01L29/66575
    • In a process for treating a semiconductor substrate (25), polymeric etchant deposits (190), silicon lattice damage (195), and native silicon dioxide layers (185), are removed in sequential process steps. The polymeric etchant deposits (190) are removed using an activated cleaning gas comprising inorganic fluorinated gas and an oxygen gas. Silicon lattice damage (195) are etched using an activated etching gas. Thereafter, an activated reducing gas comprising a hydrogen-containing gas is used to reduce the native silicon dioxide layer (185), on the substrate (25), to a silicon layer. Subsequently, a metal layer (200) is deposited on the substrate (25) and the substrate annealed to form a metal silicide layer (205). Removal of the polymeric etchant deposits (190), the silicon lattice damage (195), and the native silicon oxide layer (185) increases the interfacial conductivity of the metal silicide layer (205) to the underlying silicon-containing substrate (25).
    • 在处理半导体衬底(25)的方法中,在顺序的工艺步骤中去除聚合物蚀刻剂沉积物(190),硅晶格损伤(195)和天然二氧化硅层(185)。 使用包含无机氟化气体和氧气的活性清洁气体除去聚合物蚀刻剂沉积物(190)。 使用活化的蚀刻气体蚀刻硅晶格损伤(195)。 此后,使用包含含氢气体的活化的还原气体将底物(25)上的天然二氧化硅层(185)还原成硅层。 随后,在衬底(25)上沉积金属层(200),并且将衬底退火以形成金属硅化物层(205)。 去除聚合物蚀刻剂沉积物(190),硅晶格损伤(195)和天然氧化硅层(185)增加金属硅化物层(205)与下面的含硅衬底(25)的界面导电性。
    • 92. 发明申请
    • METHOD FOR PRODUCING SEMICONDUCTOR INTEGRATED CIRCUIT DEVICE
    • 生产半导体集成电路器件的方法
    • WO99035696A1
    • 1999-07-15
    • PCT/JP1998/000058
    • 1998-01-09
    • H01L21/265H01L21/28H01L21/336H01L21/768H01L21/8238H01L29/78
    • H01L29/665H01L21/26506H01L21/28052H01L21/76895H01L21/823835
    • A method for producing a semiconductor integrated circuit device having field effect transistors, comprising the step of forming a parent body layer having the shape of a gate electrode pattern made of a silicon film on the surface of a device formation area of a silicon substrate through a gate insulating film and then froming a pair of semiconductor areas as source and drain regions in a surface layer portion of the device formation area of the silicon substrate, the step of forming an amorphous layer by implanting ions of a Group IV element heavier than silicon into the surface layer portion of the parent body layer and into the surface layer portion of the semiconductor area, and the step of forming a high melting metal film on the surface of the silicon substrate inclusive of the surface of the amorphous layer, applying then the first heat-treatment to form a silicide layer, removing selectively the high melting metal film and thereafter applying the second heat-treatment to activate the silicide layer. Ion implantation of a Group IV element heavier than silicon is effected in an energy quantity such that the range of the implanted ion is greater than the thickness of the high melting metal film. Ion implantation of the Group IV element heavier than silicon is effected in a dose in the range of 1x10 [atoms/cm ] to 1x10 [atoms/cm ].
    • 一种具有场效应晶体管的半导体集成电路器件的制造方法,其特征在于,包括以下工序:在硅衬底的器件形成区域的表面上形成由硅膜形成的栅电极图案的母体层, 栅极绝缘膜,然后从硅衬底的器件形成区域的表面层部分中的一对半导体区域作为源极和漏极区域,通过将比硅重的IV族元素的离子注入到非晶层中形成非晶层的步骤 母体层的表层部分和半导体区域的表层部分,以及在包括非晶层的表面的硅衬底的表面上形成高熔点金属膜的步骤,然后施加第一 热处理以形成硅化物层,选择性地除去高熔点金属膜,然后将第二热处理施加到活性物质上 吃了硅化物层。 离子注入比硅更重的IV族元素以能量的形式实现,使得注入离子的范围大于高熔点金属膜的厚度。 比硅重的IV族元素的离子注入以1×10 14 [原子/ cm 2]至1×10 15 [原子/ cm 2]的剂量进行。
    • 94. 发明申请
    • SELF-ALIGNED CMOS PROCESS
    • 自对准CMOS工艺
    • WO1995006328A1
    • 1995-03-02
    • PCT/US1994007181
    • 1994-06-24
    • NATIONAL SEMICONDUCTOR CORPORATION
    • NATIONAL SEMICONDUCTOR CORPORATIONDEMIRLIOGLU, Esin, KutluARONOWITZ, Sheldon
    • H01L21/225
    • H01L29/66575H01L21/2254H01L21/823835H01L29/41783H01L29/456H01L29/4925H01L29/665H01L29/66545
    • A method for manufacturing CMOS semiconductor devices wherein damage to the active regions of the devices due to the direct implantation of impurities is suppressed. A material is selectively deposited on a semiconductor substrate, the material having a characteristic such that formation of the material occurs on some substances such as silicon and polysilicon, and formation of the material is suppressed on other substances such as silicon dioxide and silicon nitride. Impurities are introduced into the material rather than into the substrate. The impurities are then diffused into the active regions by standard processes such as rapid thermal anneal (RTA) or furnace anneal. The material generally contains germanium, and usually is a polycrystalline silicon-germanium alloy. The diffusion depth of the impurities may be controlled with great precision by manipulating several parameters. The parameters include the thickness of the material, the energy of the impurity implants, the density of the impurity implants, and the concentration of germanium in the material.
    • 制造CMOS半导体器件的方法,其中由于直接注入杂质而损坏器件的有源区被抑制。 材料被选择性地沉积在半导体衬底上,该材料具有这样的特性,使得在诸如硅和多晶硅的某些物质上发生材料的形成,并且材料的形成被抑制在其它物质如二氧化硅和氮化硅上。 杂质被引入材料而不是衬底中。 然后通过诸如快速热退火(RTA)或炉退火的标准工艺将杂质扩散到活性区域。 该材料通常含有锗,通常是多晶硅锗合金。 可以通过操作几个参数以高精度控制杂质的扩散深度。 参数包括材料的厚度,杂质植入物的能量,杂质植入物的密度以及材料中锗的浓度。