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    • 4. 发明专利
    • SILICIDE FORMING METHOD AND MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH07111253A
    • 1995-04-25
    • JP3945794
    • 1994-03-10
    • HITACHI LTD
    • SUWA TAKESHIKASAHARA OSAMU
    • H01L21/285H01L21/205H01L21/28
    • PURPOSE:To form a tungsten silicide film having a uniform composition on a polycrystalline silicon film by a method wherein initial nuclei are formed while the pressure in a reaction chamber is set to a relatively high value and the surface of a formed film is kept clean and a film is formed while the pressure in the reaction chamber is set to a relatively low value. CONSTITUTION:After the heating of a wafer 12 is finished, the pressure in a reaction chamber 11 is set to 950mTorr and a required quantity of SiH2Cl2 gas which is one of reactive gases is supplied into the reaction chamber 11 and then a required quantity of WF6 gas which is the other reactive gas is supplied to form initial nuclei. After that, a very thin film 6 is formed. Then the supply of the gases is stopped and the reaction chamber 11 is evacuated and the surface of the very thin film 6 is cleaned. Then a pressure in the reaction chamber 11 is reset to a normal value of 150mTorr and the SiH2Cl2 gas which is one of the reactive gases is supplied into the reaction chamber 11 and, after an elapse of time for stabilizing conditions in the reaction chamber 11, the WF6 gas which is another reactive gas is supplied. As a result, a WSi2 film 3 having a uniform composition can be formed on a polycrystalline silicon film 1.
    • 5. 发明专利
    • VAPOR GROWTH DEVICE
    • JPH06177049A
    • 1994-06-24
    • JP32913892
    • 1992-12-09
    • HITACHI LTD
    • WATANABE KAZUNORIMISE NOBUYUKIKASAHARA OSAMUUDO TSUTOMU
    • C23C14/50H01L21/205H01L21/31H01L21/68
    • PURPOSE:To obtain a uniform film thickness within a wafer surface by providing a means for controlling the distance between a wafer and a wall in response to the shape of the wafer in a vapor growth device for forming film by guiding a reaction gas into a reaction pipe. CONSTITUTION:A number of wafers 32 are laminated inside a reaction pipe 31 with a constant wafer spacing by a wafer retention rod 33. A heater 34 is located outside reaction pipe 31 and the temperature of the wafer 32 is maintained to be constant by heating the inside of the reaction pipe 31. A cover pipe 35 is located between the wafers 32 and the reaction pipe 31. A mating part 37 which becomes nearly parallel to an orientation flat 36 of a wafer 33 is provided at the cover pipe 35, thus maintaining the distance between the wafer 32 and the cover pipe 35 to be nearly constant and making uniform the film quality as well as the distribution of the film thickness by taking the same structure as that of the cover pipe 35 for example by drilling. In this manner, the film thickness uniformity within the wafer surface can be increased.