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    • 4. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH01298758A
    • 1989-12-01
    • JP12839588
    • 1988-05-27
    • HITACHI LTD
    • KANEKO HIROKO
    • H01L21/3205H01L21/31H01L21/822H01L27/04H01L27/108
    • PURPOSE:To suppress the formation of a spontaneous oxide film on a polycrystalline silicon electrode and to reduce the thickness of an insulating film by forming a conductive layer on a capacity lower layer electrode by a sputtering method, and then forming the insulating layer and a capacity upper layer electrode on the conductive layer. CONSTITUTION:A conductive film is formed on a whole semiconductor substrate 1 by sputtering technique on a capacity lower layer electrode 9, and an unnecessary part is selectrively etched to form a conductive layer 10. As the conductive film, a film made of titanium nitride or titanium oxide is, for example, employed. Then, an insulating film is formed on the whole substrate 1. The insulating film is formed, for example, of a 2-layer film of an Si3N4 film obtained by a CVD technique and an SiO2 film obtained by thermally oxidizing the Si3N4 film. then, polycrystalline silicon is formed on the whole substrate 1, which is reduced in its resistance by ion implanting phosphorus or arsenic, and an unnecessary part is selectively etched to form a capacity insulating film 11 and a capacity upper layer electrode 12. Thus, the thickness of the insulating film can be substantially reduced.
    • 7. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPS61150216A
    • 1986-07-08
    • JP27086284
    • 1984-12-24
    • HITACHI LTD
    • KANEKO HIROKOKOYANAGI MITSUMASA
    • H01L21/28
    • PURPOSE:To contrive to miniaturize an element preventing short circuit in a metallic siliside film by a method wherein a metallic film is formed on an Si substrate and then heat-treatment is performed thereto in temperature range of almost 400-600 deg.C. CONSTITUTION:A field oxide film 2 and a gate oxide film 3 are formed on a P-type Si substrate 1 and a gate electrode 4 is formed thereon. P-ion implanting layer 5 is formed covering whole face. Secondly a side wall 6 is formed to both side of the gate electrode 4, then a Ti film 7 is formed. Then As implanting layer 8 is formed covering whole face. Thereafter, a Ti siliside 9 is formed by siliciding the Ti film 7 on the As driving layer 8. At this time, a Ti silicide 10 is formed on the gate electrode 4, too. If low temperature at less than 600 deg.C, anealing is performed, the metallic silicide to be formed does not expand to lateral direction by means that reaction of metal, the field oxide film 2 and the side wall 6 with SiO2 and the movement of Si are suppressed.
    • 8. 发明专利
    • Manufacture of semiconductor integrated circuit device
    • 半导体集成电路器件的制造
    • JPS6195550A
    • 1986-05-14
    • JP21619684
    • 1984-10-17
    • Hitachi Ltd
    • KANEKO HIROKOKOYANAGI MITSUMASA
    • H01L29/78H01L21/768H01L21/8246H01L27/10H01L27/112
    • PURPOSE:To reduce a sheet resistance value by forming a thin metal layer which reacts with a silicon oxide film on a semiconductor region and forming a silicide layer through formation of a thick metal layer which does not react with silicon oxide film. CONSTITUTION:An n type impurity is doped to a semiconductor substrate 1 and semiconductor regions 6a and 6b are formed by thermal diffusion. Thereafter, a metal layer such as Ti, Pt, Pa or Hf is formed on the semiconductor region 6b, GL and field insulation film 2. Heat processing is carried out, causing the silicon oxide film to react with a metal layer such as Ti and causing the metal to react with semiconductor region 6b and GL, in order to form a conductive layer 10a. Moreover, a conductive layer 11a is formed by reaction with the gate electrode 5, word line WL and metal layer. A metal layer such as Mo, W, Ta which shows lower reaction rate with silicon than that of Ti is formed on the conductive layers 10a, 11a, side wall 12 and field insulation film 2. The conductive layers 10a, 11a are formed by heat processing and the conductive layer 10b, 11b are formed by reaction between semiconductor substrate 1 and silicon in the gate electrode 5. Thereby, a sheet resistance value can be reduced.
    • 目的:通过在半导体区域上形成与氧化硅膜反应的薄金属层,通过形成不与氧化硅膜反应的厚金属层形成硅化物层来降低薄层电阻值。 构成:将n型杂质掺杂到半导体衬底1中,并且通过热扩散形成半导体区域6a和6b。 此后,在半导体区域6b,GL和场绝缘膜2上形成诸如Ti,Pt,Pa或Hf的金属层。进行热处理,使得氧化硅膜与诸如Ti的金属层反应 导致金属与半导体区域6b和GL反应,以便形成导电层10a。 此外,通过与栅电极5,字线WL和金属层反应形成导电层11a。 在导电层10a,11a,侧壁12和场绝缘膜2上形成诸如Mo,W,Ta的与硅相比显示出比硅低的反应速率的金属层。导电层10a,11a由热 处理和导电层10b,11b通过半导体衬底1和栅电极5中的硅之间的反应形成。由此,可以减小薄层电阻值。
    • 10. 发明专利
    • Manufacture of semiconductor integrated circuit device
    • 半导体集成电路器件的制造
    • JPS61137367A
    • 1986-06-25
    • JP25914484
    • 1984-12-10
    • Hitachi Ltd
    • KOYANAGI MITSUMASAKANEKO HIROKO
    • H01L29/78H01L21/285H01L21/321H01L21/3213H01L29/45H01L29/49
    • H01L21/32134H01L21/28518H01L21/3211H01L29/456H01L29/4933
    • PURPOSE: To integrate an IC by coating a titanium silicide layer when forming a barrier metal on a region for preventing aluminum for forming signal wirings and power source wirings from diffusing in a semiconductor region, and annealing in N
      2 gas to form a titanium nitride layer, thereby eliminating a mask alignment.
      CONSTITUTION: A thick field insulating film 2 is formed with a P
      + type channel stopper region 3 laid on the periphery of a P
      - type Si substrate 1, and a polycrystalline Si gate electrode 5 is formed through a gate insulating film 4 at the center of the surface of the substrate 1 surrounded by the film 2. Then, the side wall of the electrode 5 is coated by an insulating film 6, P ions are first implanted to form a deep N
      + type source and drain regions 7b, and As impurity is then diffused to form shallow N
      - type source and drain regions 7a for coupling them. Then, titanium silicide layers 9, 8 are coated only on the region 7b and the electrode 5, heat treated in N
      2 gas to alter to titanium nitride layers 12, 11. Thus, a barrier metal is formed in a self-aligned manner.
      COPYRIGHT: (C)1986,JPO&Japio
    • 目的:通过在形成用于防止铝形成信号布线和电源布线的区域中形成阻挡金属的区域上涂覆硅化钛层,以在半导体区域中扩散,并且在N 2气中退火以形成氮化钛层,来集成IC, 从而消除了掩模对准。 构成:在P型Si基板1的周围形成有P +型沟道截止区域3的厚场绝缘膜2,通过栅极绝缘膜形成多晶硅栅电极5 在由膜2包围的基板1的表面的中心处形成4个。然后,用绝缘膜6涂覆电极5的侧壁,首先将P离子植入以形成深N +型源, 漏极区域7b,然后As杂质扩散以形成用于耦合它们的浅N +型源极和漏极区域7a。 然后,将硅化钛层9,8仅涂覆在区域7b和电极5上,在N2气中进行热处理以改变氮化钛层12,11。于是,以自对准的方式形成阻挡金属。