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    • 1. 发明授权
    • Transparent electrically conductive film and process for producing the same
    • 透明导电膜及其制造方法
    • US07883837B2
    • 2011-02-08
    • US11918700
    • 2006-04-18
    • Kohei YamadaHidekazu ShiomiHideyuki Yamada
    • Kohei YamadaHidekazu ShiomiHideyuki Yamada
    • G03F1/00H01L21/00
    • H05K9/0096B32B27/00H05K3/185H05K2203/0565H05K2203/1415
    • This invention provides a transparent electrically conductive film, which, while maintaining the light transparency of a transparent film, has excellent electrical conductivity, can be utilized for electromagnetic wave shielding, and does not cause inclusion of air bubbles in the lamination onto other base material, and a process for producing the same. The production process comprises the steps of forming a large number of concaves and convexes having an average height of not more than 0.1 μm on both sides or one side of a transparent film, forming a resist layer having a pattern shape opposite to the electrically conductive part in the electrically conductive film on the transparent film on its concave-convex side, applying a catalyst for plating onto the resist layer-formed face, separating the resist layer, forming a metal layer by plating, and blackening the metal layer, the metal layer satisfying 1≦W/T≦500 wherein W represents the width of the metal layer and T represents the height of the metal layer.
    • 本发明提供了一种透明导电膜,其在保持透明膜的透光性的同时具有优异的导电性,可用于电磁波屏蔽,并且不会在叠层到其它基材上引起气泡, 及其制造方法。 制造方法包括在透明膜的两面或一侧形成平均高度不大于0.1μm的大量凹凸的步骤,形成具有与导电部分相对的图案形状的抗蚀剂层 在透明膜的凹凸侧的导电膜中,在抗蚀剂层形成面上涂布电镀用催化剂,分离抗蚀剂层,通过电镀形成金属层,使金属层变黑,金属层 满足1≦̸ W / T≦̸ 500其中W表示金属层的宽度,T表示金属层的高度。
    • 2. 发明申请
    • Transparent electrically conductive film and process for producing the same
    • 透明导电膜及其制造方法
    • US20090042150A1
    • 2009-02-12
    • US11918700
    • 2006-04-18
    • Kohei YamadaHidekazu ShiomiHideyuki Yamada
    • Kohei YamadaHidekazu ShiomiHideyuki Yamada
    • G03C1/74G03C1/00
    • H05K9/0096B32B27/00H05K3/185H05K2203/0565H05K2203/1415
    • This invention provides a transparent electrically conductive film, which, while maintaining the light transparency of a transparent film, has excellent electrical conductivity, can be utilized for electromagnetic wave shielding, and does not cause inclusion of air bubbles in the lamination onto other base material, and a process for producing the same. The production process comprises the steps of forming a large number of concaves and convexes having an average height of not more than 0.1 μm on both sides or one side of a transparent film, forming a resist layer having a pattern shape opposite to the electrically conductive part in the electrically conductive film on the transparent film on its concave-convex side, applying a catalyst for plating onto the resist layer-formed face, separating the resist layer, forming a metal layer by plating, and blackening the metal layer, the metal layer satisfying 1≦W/T≦500 wherein W represents the width of the metal layer and T represents the height of the metal layer.
    • 本发明提供了一种透明导电膜,其在保持透明膜的透光性的同时具有优异的导电性,可用于电磁波屏蔽,并且不会在叠层到其它基材上引起气泡, 及其制造方法。 制造方法包括以下步骤:在透明膜的两侧或一侧形成平均高度不大于0.1μm的大量凹凸,形成具有与导电部分相对的图案形状的抗蚀剂层 在透明膜的凹凸侧的导电膜中,在抗蚀剂层形成面上涂布电镀用催化剂,分离抗蚀剂层,通过电镀形成金属层,使金属层变黑,金属层 满足1 <= W / T <= 500其中W表示金属层的宽度,T表示金属层的高度。
    • 5. 发明授权
    • Preparation of photoformed plastic multistrate by via formation first
    • 首先通过通孔形成制备光致变形塑料多药
    • US4572764A
    • 1986-02-25
    • US681189
    • 1984-12-13
    • Roxy N. Fan
    • Roxy N. Fan
    • H05K3/00H05K3/10H05K3/18H05K3/24H05K3/46B44C1/22B05D5/12G03C5/00
    • H05K3/0023H05K3/184H05K3/4661H05K2201/0347H05K2201/0376H05K2201/09509H05K2203/0525H05K2203/072H05K2203/1415H05K3/102H05K3/246Y10T29/49155Y10T29/49165Y10T29/49204
    • Process for preparing multilayer printed circuits comprising laminating to a substrate bearing a circuit pattern or electrically conductive surface a photosensitive layer which is tacky or becomes tacky upon exposure; exposing the laminate to actinic radiation through a via image related to the underlying circuit pattern, if present; optionally removing the removable via image of the photosensitive layer in either the exposed or unexposed areas, e.g., with a solvent or peeling apart by removal of a cover sheet, if present; laminating to the remaining tacky photosensitive layer a layer of a second photosensitive composition; exposing the laminate to actinic radiation through a registered image pattern of at least one overlying segment of the via image area and conductive circuit pattern to form an image surface having nontacky areas and removable circuit image areas; removing the removable circuit image areas of the photosensitive layer in the exposed or unexposed areas with a solvent therefor, or peeling apart by means of a cover sheet, if present, the removable via image areas of the lower photosensitive, if present, are removed by a solvent therefor; embedding finely divided material, e.g., copper, into the tacky areas; optionally curing the laminate by means of actinic radiation and/or heat; plating electrolessly to form an interconnected electrically conductive circuit. Additional circuit layers can be added.
    • 制备多层印刷电路的方法包括层压到承载电路图形或导电表面的基底上,所述光敏层在曝光时发粘或变粘, 通过与底层电路图案相关的通孔图像将层压体暴露于光化辐射(如果存在) 任选地在暴露或未曝光的区域(例如用溶剂)中去除感光层的可移除通孔图像,或者通过去除覆盖片(如果存在)剥离; 将第二感光组合物的层层压到剩余的粘性感光层上; 通过所述通孔图像区域和导电电路图案的至少一个覆盖段的注册图像图案将所述层压体暴露于光化辐射,以形成具有非粘性区域和可移除电路图像区域的图像表面; 通过其溶剂去除曝光或未曝光区域中的感光层的可移除电路图像区域,或者通过覆盖片剥离(如果存在),可以通过下部光敏剂的可移除通孔图像区域(如果存在的话)被 其溶剂; 将细碎的材料例如铜嵌入粘性区域中; 任选地通过光化辐射和/或加热固化层压体; 电化学镀以形成互连的导电电路。 可以添加额外的电路层。
    • 8. 发明授权
    • Through-hole plate printed circuit board with resist and process for
manufacturing same
    • 通孔板印刷电路板与抗蚀剂及其制造方法相同
    • US5373629A
    • 1994-12-20
    • US836261
    • 1992-02-28
    • Jurgen HupeWalter Kronenberg
    • Jurgen HupeWalter Kronenberg
    • C08G61/10C08G61/12C25D5/56C25D7/00H05K3/10H05K3/40H05K3/42H05K3/46H01K3/10B32B3/10
    • H05K3/424C08G61/123H05K3/4038H05K2201/0329H05K2203/0796H05K2203/107H05K2203/122H05K2203/1415H05K3/108H05K3/427Y10T29/49144Y10T29/49165Y10T428/24322Y10T428/24802Y10T428/24917Y10T428/31
    • A process is described for manufacturing through-hole plated single-layer or multi-layer printed circuit boards based on a polymeric substrate material or on a ceramic material provided optionally on both sides with at least one photoresist layer temporarily exposing the electroconductive circuit pattern by electroplating or electroless plating with a metal layer also on those surfaces which have not been coated with a conductive metal layer, characterized in thata) the surfaces of the substrate, after hole-drilling and a subsequent mechanical surface-treatment, are laminated with a suitable photoresist, exposed to light and developed so that the circuit pattern image is exposed,b) the surfaces of the substrate are pre-treated in a solution having oxidizing activity,c) after removal of the residual solution by rinsing, the substrate is introduced into a solution which contains at least one heterocyclic monomer, and more specifically pyrrole, thiophene, furane or derivative(s) thereof, which in a polymeric form is electrically conductive,d) the substrate is then transferred into an acidic solution whereby an electrically conductive polymeric layer is formed,whereupon, if desired or required, any residual solution is removed by rinsing, and the through-holes and the circuit pattern image are metallized in one step by galvanic or, preferably, electroless metallization.
    • PCT No.PCT / EP90 / 01326 Sec。 一九九二年二月二十八日 102(e)日期1992年2月28日PCT 1990年8月11日PCT PCT。 公开号WO91 / 03920 日本1991年3月21日。描述了一种用于制造基于聚合物基材的通孔电镀单层或多层印刷电路板的工艺,或者在任选地在两侧设置有至少一个光致抗蚀剂层的陶瓷材料 在没有涂覆有导电金属层的那些表面上也用金属层进行电镀或无电镀来暴露导电电路图案,其特征在于:a)所述基板的表面,在钻孔后和随后的机械表面 - 处理,与合适的光致抗蚀剂层合,暴露于光并显影,使得电路图案图像被曝光,b)基板的表面在具有氧化活性的溶液中预处理,c)在通过 将底物引入含有至少一种杂环单体的溶液中,更具体地说是吡咯,噻吩,呋喃或d 以聚合形式导电,d)然后将基底转移到酸性溶液中,由此形成导电聚合物层,然后如果需要或需要,通过冲洗除去任何残留的溶液, 并且通过电流或优选地,无电金属化在一个步骤中对通孔和电路图案图像进行金属化。