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    • 9. 发明授权
    • Production of fibers or films using specific forming solutions and the
fibers of films obtainable thereby
    • 使用特定的成形溶液生产纤维或薄膜以及由此获得的薄膜的纤维
    • US5646234A
    • 1997-07-08
    • US416148
    • 1995-04-04
    • Holger JungRichard NeuertPeter KleinGeorg-Emerich Miess
    • Holger JungRichard NeuertPeter KleinGeorg-Emerich Miess
    • B29C55/02B29K77/00B29L7/00C08G69/32C08G69/42C08J5/18C08L77/00C08L77/10D01F6/60D01F6/80D01F6/90C08G69/12
    • C08J5/18C08G69/32C08G69/42D01F6/805C08J2377/10Y10T428/2969Y10T428/2971Y10T428/31725
    • A process for producing fibers or films by the steps of:a) preparing an aromatic polyamide by polycondensation of dicarbonyl dihalides or mixtures thereof with at least two diamines in N-alkyllactams as a solvent, the polycondensation being of at least 90 mol %, based on the total amount of dicarbonyl dihalides in the reaction mixture, of compounds of the formula I or mixtures of such compoundsHal--OC--Ar.sup.1 --CO--Hal (I)with at least 90 mol%, based on the total amount of diamines in the reaction mixture, of compounds of the formula II and optionally III or mixtures of such compoundsH.sub.2 N--Ar.sup.2 --NH.sub.2 (II), H.sub.2 N--Ar.sup.3 --NH.sub.2 (III)where Ar.sup.1, Ar.sup.2 and Ar.sup.3 are independently of each other a bivalent aromatic radical, the proportion of structural repeat units in the aromatic polyamide derived from the compounds of the formula II, based on the proportion of the structural repeat units derived from the compounds of the formulae II and III, being at least 50 mol %, and said aromatic polyamide is soluble in organic solvents,b) forcing the solution of the aromatic polyamide obtained in step a) through dies of the desired cross-sectional shape at temperatures from 40.degree. to 120.degree. C. to form fibers or films,c) removing the organic solvent in a conventional manner to produce solvent-leaner or -free fibers or films sufficiently mechanically stable and nontacky for further processing.The process of the invention omits the customary neutralization after the aromatic polyamide has been prepared.
    • 一种通过以下步骤制备纤维或薄膜的方法:a)通过二羰基二卤化物或其混合物与N-烷基内酰胺中的至少两种二胺作为溶剂进行缩聚来制备芳族聚酰胺,所述缩聚为至少90mol%,基于 对于反应混合物中二羰基二卤化物的总量,式I化合物或这些化合物Hal-OC-Ar1-CO-Hal(I)的混合物与至少90mol%的二胺的总量相比, 反应混合物,式II和任选III的化合物或这些化合物H 2 N-Ar 2 -NH 2(II),H 2 N-Ar 3 -NH 2(III)的混合物,其中Ar 1,Ar 2和Ar 3彼此独立地是二价芳族基团 衍生自式II化合物的芳族聚酰胺中结构重复单元的比例基于衍生自式II和III的化合物的结构重复单元的比例为至少50mol%,所述芳族 聚酰胺可溶于或 粗制溶剂,b)在40℃至120℃的温度下,将步骤a)中获得的芳族聚酰胺溶液强迫所需的横截面形状,以形成纤维或膜,c)将 以常规的方式制备足够机械稳定和非粘性以进行进一步处理的溶剂稀的或无 - 纤维或薄膜。 在制备芳族聚酰胺之后,本发明的方法省略了常规中和。