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    • 10. 发明申请
    • FLAME-RESISTANT POLYAMIDE, METHOD FOR THE PRODUCTION OF SAID FLAME-RESISTANT POLYAMIDE, AND USE OF SAID FLAME-RESISTANT POLYAMIDE.
    • 耐火聚酰胺,生产耐火耐火聚酰胺的方法,以及耐火耐火聚酰胺的用途。
    • US20160039975A1
    • 2016-02-11
    • US14780897
    • 2014-03-27
    • DEUTSCHE INSTITUTE FÜR TEXTILUND FASERFORSCHUNG DENKENDORF
    • Rainer GUTMANNSabine GNEITING
    • C08G69/42C08J5/00
    • C08G69/42C08G69/02C08J5/00C08J2377/06C08L77/06C08L2205/02
    • The invention relates to a flame-resistant polyamide as a product of the condensation of dicarboxylic acids with diamines and with a flame-retardant phosphorus compound, which flame-resistant polyamide is characterized in that the flame-resistant polyamide FR contains, in the main chain thereof, phosphinic acid amide structural units of formula (II) —PO(R1)—NH— (II) in addition to the amide structural units of formula (I) —CO—NH— (I), in which formula (II) R1 means hydrogen or an organic group and can differ in the individual phosphinic acid amide structural units within the main chain, and that the polyamide FR achieves a relative viscosity, measured as a 1% solution in 96% sulfuric acid at 25° C., of at least 2.0 (in accordance with DIN 51562). The invention further relates to a method for producing said flame-resistant polyamide FR. In said method, one or more diamines are polycondensed with one or more dicarboxylic acids under pressure and at elevated temperature in the presence of water and with one or more diphosphinic acids and/or one or more phosphino-carboxylic acids by means of a polyamide synthesis. After the polycondensation, the pressure in the reaction chamber is reduced to less than 1 bar. The flame-resistant polyamide can be advantageously used to produce molded bodies, in particular films, components, and filaments or filament yarns.
    • 本发明涉及作为二羧酸与二胺与阻燃磷化合物的缩合产物的阻燃聚酰胺,该阻燃聚酰胺的特征在于阻燃聚酰胺FR在主链中含有 除了式(I)-CO-NH-(I)的酰胺结构单元之外,式(II)-PO(R 1)-NH-(II)的次膦酸酰胺结构单元,其中式(II) R1表示氢或有机基团,并且在主链中的各个次膦酸酰胺结构单元可以不同,并且聚酰胺FR获得相对粘度,其在25℃在96%硫酸中以1%溶液测量, 至少2.0(符合DIN 51562)。 本发明还涉及一种制造所述阻燃聚酰胺FR的方法。 在所述方法中,一种或多种二胺与一种或多种二羧酸在压力和升高的温度下在水的存在下与一种或多种二磷酸和/或一种或多种膦酰基羧酸通过聚酰胺合成进行缩聚 。 缩聚后,反应室中的压力降至小于1巴。 阻燃聚酰胺可有利地用于生产成型体,特别是薄膜,部件,细丝或长丝纱线。