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    • 8. 发明授权
    • Curable copolymers, a process for their preparation and their use
    • 可固化共聚物,其制备方法及其用途
    • US4704442A
    • 1987-11-03
    • US826789
    • 1986-02-06
    • Christoph JustDieter PlathGerd Walz
    • Christoph JustDieter PlathGerd Walz
    • C08F222/22C09D135/00C08F24/00
    • C08F222/22C09D135/00
    • Copolymers based on (A) 5-95% by weight of at least one polymerizable carbamoyloxyalkyldicarboxylic acid ester, carrying hydroxyl groups, of the general formula I ##STR1## in which R.sup.1 represents hydrogen or alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, R.sup.2 represents alkyl or hydroxyalkyl having in each case 1 to 30 carbon atoms in the alkyl radical, or the radical ##STR2## subject to the proviso that R.sup.1 is hydrogen and x is an integer from 2 to 10, R.sup.3 represents linear or branched alkylene having 2 to 5 carbon atoms, R.sup.4 represents hydrogen or methyl and R.sup.5 represents hydroxyalkyl or hydroxyaminoalkyl having in each case 2 to 20 carbon atoms in the alkyl radical, or an alkyl radical of this type which also contains ester groups and/or ether groups, and (B) 5-95% by weight of at least one copolymerizable monomer belonging to the group comprising (a) .alpha.,.beta.-olefinically unsaturated monocarboxylic acid and alkyl and hydroxyalkyl esters thereof having in each case 1 to 18 carbon atoms in the alkyl radical, and amides and nitriles thereof, and also monoalkyl and dialkyl esters of .alpha.,.beta.-olefinically unsaturated dicarboxylic acids having 1 to 18 carbon atoms in the alkyl radical, (b) vinyl-aromatic monomers, (c) vinyl esters of organic monocarboxylic acids having 1 to 18 carbon atoms in the carboxylic acid radical, and (d) glycidyl esters of unsaturated monocarboxylic and/or dicarboxylic acids, the sum of the components (A) and (B) being in all cases 100% by weight, and a process for their preparation.The copolymers are used for the preparation of shaped articles and/or coatings which have excellent properties.
    • 基于(A)5-95重量%的至少一种带有羟基的可聚合的氨基甲酰氧基烷基二羧酸酯,其通式为Ⅰ,其中R1代表氢或烷基或羟基烷基,其中在每种情况下为1-30碳 烷基中的原子,R 2表示在每个情况下在烷基中具有1至30个碳原子的烷基或羟烷基,或者基团,条件是R 1是氢且x是2至10的整数,R 3 表示具有2至5个碳原子的直链或支链亚烷基,R4表示氢或甲基,R5表示在烷基中各自为2至20个碳原子的羟基烷基或羟基氨基烷基,或还含有酯基的这种类型的烷基, /或醚基,和(B)5-95重量%的至少一种可共聚单体,其属于包含(a)α,β-烯属不饱和一元羧酸及其烷基和羟烷基酯的组 在每种情况下,烷基中的1至18个碳原子,以及其酰胺和腈,以及在烷基中具有1至18个碳原子的α,β-烯属不饱和二羧酸的单烷基和二烷基酯,(b)乙烯基 - 芳族单体,(c)在羧酸基团中具有1至18个碳原子的有机单羧酸的乙烯基酯,和(d)不饱和一元羧酸和/或二羧酸的缩水甘油酯,组分(A)和( B)在所有情况下为100重量%,以及其制备方法。 共聚物用于制备具有优异性能的成型制品和/或涂层。
    • 10. 发明授权
    • Thermosetting compositions
    • 热固性组合物
    • US4208488A
    • 1980-06-17
    • US877868
    • 1978-02-15
    • Kurt KraftGerd WalzThaddaus Wirth
    • Kurt KraftGerd WalzThaddaus Wirth
    • C09D5/08C08G59/00C08G59/42C08L1/00C08L23/00C08L27/00C08L33/00C08L33/02C08L67/00C08L67/08C08L101/00C09D163/00C09D167/00C09J133/04C09J163/00C09J167/00C08L63/00
    • C09D167/00C08K5/04C09J167/00
    • A thermosetting coating or adhesive composition based on (A) at least one component selected from the group consisting of oligomeric and polymeric compounds containing at least one of the functional groups hydroxyl and epoxy groups, and (B) a polycarboxylic acid mixture comprising trimellitic acid and a major amount of at least one compound of one of the formulae ##STR1## wherein R, R' and R'", being the same or different, each represents a di- to hexavalent hydrocarbon radical having a total of from 1 to 12 carbon atoms, said radical containing from zero to 2 olefinic double bonds, said radical without double bonds being interrupted by up to 3 ether bridges:x and y which may be the same or different, each represents an integer of from 2 to 6;t an integer of from 1 to 5; andz and u, which may be the same or different, each represents zero or an integer of from 1 to 5 and a process for coating a substrate with said composition.
    • 一种基于(A)选自包含至少一个官能团羟基和环氧基团的低聚物和聚合物的至少一种成分的组合物的热固性涂料或粘合剂组合物,和(B)包含偏苯三酸和 主要量的至少一种下式之一的化合物:其中R,R'和R“'相同,其中R,R'和R”'相同 或不同的,每个表示总共具有1至12个碳原子的二价至六价烃基,所述基团含有0至2个烯属双键,所述无双键的基团被多达3个醚桥隔开:x和 y可以相同或不同,各自表示2〜6的整数; t为1〜5的整数; 和可以相同或不同的z和u各自表示0或1〜5的整数,以及用所述组合物涂布基材的方法。