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    • 10. 发明公开
    • High pressure process for the formation of crystallized ceramic films at low temperatures
    • 在低温下制备结晶陶瓷层的高压法
    • EP1195799A1
    • 2002-04-10
    • EP00308782.2
    • 2000-10-05
    • Lu, Chung-Hsin
    • Lu, Chung-Hsin
    • H01L21/316
    • C23C14/5806C23C14/08C23C16/40C23C16/56C23C18/1208H01L21/02175H01L21/02183H01L21/02186H01L21/02194H01L21/02197H01L21/02266H01L21/02282H01L21/02337H01L21/02356H01L21/31691H01L41/314
    • A process is disclosed for forming crystallized ceramic films at low temperatures by providing a higher pressure under which the formation of crystallized ceramic films from the amorphous or partially crystallized precursor films of ceramics can be significantly enhanced. The present invention not only improves quality, performance and reliability of the ceramic films, but also reduces the cost for production. By lowering the formation temperatures of crystallized ceramic films, the cost for thermal energy consumed during the heating process is greatly reduced. In addition, the interaction or interdiffusion occurring between films and substrates is significantly suppressed or essentially prevented, avoiding the off-stoichiometry and malfunction of thin films, which usually occur in the conventional high-temperature processes. The process of present invention also decreases the grain size of formed films, thus reducing the roughness of films and producing relatively smooth, good quality films. This process makes possible the fabrication of ceramic films with larger area at substantially low temperatures, and is applicable to very large scale integrated circuit technologies. The present invention finds broad applications including manufacturing ferroelectric memories, dynamic random access memories, nonvolatile random access memories, photo catalysis, optical lenses, magnetic devices, capacitors, actuators, piezoelectric devices, pyroelectric devices, sensors, electro-optic switching, glass coating, non-liner optical devices, reflective/antireflective coating, etc.
    • 一种方法是游离缺失盘通过提供更高的压力下,从陶瓷的无定形或结晶的部分的前体膜结晶化的陶瓷膜的形成可显着增强形成在低温下结晶的陶瓷膜。 本发明不仅提高了质量,性能和可靠性的陶瓷薄膜所以,但降低了生产成本。 通过降低结晶温度的陶瓷膜的形成中,在加热过程期间所消耗的热能的成本大大降低。 此外,相互作用或相互扩散膜与基板之间出现被抑制或显着本质上阻止,避免偏离化学计量和薄膜的故障,这在传统的高温工艺,通常会出现。 因此本发明的方法降低了形成的膜的晶粒尺寸,从而降低膜的粗糙度和产生相对光滑,良好的质量的膜。 这个过程使得有可能与更大面积的陶瓷膜的制造在低温度基本上,并适用于超大规模集成电路技术。 本发明发现有广泛的应用包括制造铁电存储器,动态随机存取存储器,非易失性随机存取存储器,光催化,光学透镜,磁器件,电容器,致动器,压电器件,热电装置,传感器,电 - 光开关,玻璃涂层, 非线性光学器件,反射/抗反射涂层等