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    • 2. 发明授权
    • Process for preventing development defect and composition for use in the same
    • 用于预防发展缺陷和组合物的方法
    • US07799513B2
    • 2010-09-21
    • US10518105
    • 2003-06-10
    • Yasushi AkiyamaYusuke TakanoKiyohisa TakahashiSung-Eun HongTetsuo Okayasu
    • Yasushi AkiyamaYusuke TakanoKiyohisa TakahashiSung-Eun HongTetsuo Okayasu
    • G03F7/00
    • G03F7/11G03F7/168
    • The composition for preventing development-defects containing (1) an ammonium salt, a tetraalkylammonium salt or a C1 to C4 alkanolamine salt of C4 to C15 perfluoroalkylcarboxylic acid, C4 to C10 perfluoroalkylsulfonic acid and perfluoroadipic acid, or (2) a fluorinated alkyl quaternary ammonium salt of inorganic acid, wherein said surfactant is formed at the equivalent ratio of acid to base of 1:1-1:3 is applied on a chemically amplified photoresist coating on a substrate having a diameter of 8 inches or more. The chemically amplified photoresist coating is baked before and/or after applying the composition for preventing development-defects described above. Then, the baked coating with the development-defect preventing composition coating is exposed to light, post-exposure-baked, and developed. By this process, compared with the case of not using the composition for preventing development-defects, the amount of reduction in film thickness of the photoresist subsequent to development treatment is made further bigger by 100 Å to 600 Å, and the development-defects on a substrate having a diameter of 8 inches or more is reduced as well as a resist pattern having a good cross section form can be formed without T-top form etc.
    • (1)C4〜C15全氟烷基羧酸,C4〜C10全氟烷基磺酸和全氟己二酸的铵盐,四烷基铵盐或C1〜C4烷醇胺盐的预防显影缺陷用组合物,或(2)氟化烷基季铵 无机酸的盐,其中所述表面活性剂以相对于酸与碱的比例为1:1-1:3的比例形成在直径为8英寸或更大的基材上的化学放大的光致抗蚀剂涂层上。 在施加用于防止上述显影缺陷的组合物之前和/或之后烘烤化学放大的光致抗蚀剂涂层。 然后,将具有显影缺陷防止组合物涂层的烘烤涂层曝光,曝光后烘烤和显影。 通过该方法,与不使用用于防止显影缺陷的组合物的情况相比,显影处理后的光致抗蚀剂的膜厚减少量进一步大于100埃至600埃,并且显影缺陷在 直径为8英寸以上的基板减少,并且可以形成具有良好横截面形状的抗蚀剂图案而不具有T形顶端形式等。
    • 3. 发明授权
    • Water soluble resin composition and method for pattern formation using the same
    • 水溶性树脂组合物及其形成方法
    • US07745093B2
    • 2010-06-29
    • US11547707
    • 2005-04-08
    • Takeshi NishibeSung Eun HongYusuke TakanoTetsuo Okayasu
    • Takeshi NishibeSung Eun HongYusuke TakanoTetsuo Okayasu
    • G03F7/40G03F7/11
    • G03F7/40H01L21/0273Y10S430/106Y10S430/11Y10S430/115Y10S430/162Y10S430/165
    • In the present invention, in a water soluble resin composition for use in a method for pattern formation in which a covering layer is provided on a resist pattern formed of a radiation-sensitive resin composition capable of coping with ArF exposure to increase the width of the resist pattern and thus to realize effective formation of higher density trench or hole pattern, the size reduction level of the resist pattern layer can be further increased as compared with that in the prior art technique, and, in addition, the size reduction level dependency of the coarse-and-fine resist pattern can be reduced. A method for pattern formation using the water soluble resin composition is also provided. The water soluble resin composition which is usable for the method for pattern formation applicable to ArF excimer laser irradiation comprises a water soluble resin, an acid generating agent capable of generating an acid upon heating, a surfactant, a crosslinking agent, and a water-containing solvent.
    • 在本发明中,在用于图案形成方法的水溶性树脂组合物中,其中在由能够应对ArF曝光的辐射敏感性树脂组合物形成的抗蚀剂图案上设置覆盖层以增加其宽度 抗蚀剂图案,从而实现有效形成更高密度的沟槽或孔图案,与现有技术相比,抗蚀剂图案层的尺寸减小水平可以进一步提高,另外,尺寸缩小级依赖性 可以减少粗细和抗蚀剂图案。 还提供了使用水溶性树脂组合物的图案形成方法。 可用于适用于ArF准分子激光照射的图案形成方法的水溶性树脂组合物包括水溶性树脂,加热时能产生酸的酸产生剂,表面活性剂,交联剂和含水的 溶剂。
    • 4. 发明申请
    • WATER-SOLUBLE RESIN COMPOSITION FOR THE FORMATION OF MICROPATTERNS AND METHOD FOR THE FORMATION OF MICROPATTERNS WITH THE SAME
    • 用于形成微波炉的水溶性树脂组合物及其形成微波炉的方法
    • US20100119717A1
    • 2010-05-13
    • US12451150
    • 2008-05-01
    • Sung-Eun HongYusuke TakanoWen-Bing Kang
    • Sung-Eun HongYusuke TakanoWen-Bing Kang
    • B05D3/00C08K5/17
    • H01L21/0271G03F7/40H01L21/3085H01L21/3086H01L21/3088
    • A process which comprises applying a water-soluble resin composition comprising a water-soluble vinyl resin, a compound having at least two amino groups in the molecule, a solvent, and, if necessary, an additive such as a surfactant on a resist pattern (2) formed on a substrate (1) to form a water-soluble resin film (3) , modifying part of the water-soluble resin film adjacent to the resist pattern through mixing to form a water-insolubilized layer (4) which cannot be removed by water washing on the surface of the resist pattern, and removing unmodified part of the water-soluble resin film by water washing and which enables the effective scale-down of separation size and hole opening size of a resist pattern to a level finer than the limit of resolution of the wave length of exposure. It is preferable to use as the water-soluble vinyl resin a homopolymer of a nitrogen-containing vinyl monomer such as acrylamine, vinylpyrrolidone or vinylimidazole, a copolymer of two or more nitrogen-containing vinyl monomers, or a copolymer of at least one nitrogen-containing vinyl monomer and at least one nitrogen-free vinyl monomer.
    • 一种方法,其包括将包含水溶性乙烯基树脂的水溶性树脂组合物,分子中具有至少两个氨基的化合物,溶剂和必要时在抗蚀图案上添加表面活性剂等添加剂 2)形成在基板(1)上以形成水溶性树脂膜(3),通过混合将与抗蚀剂图案相邻的水溶性树脂膜的一部分进行改性以形成不可溶的水不溶层(4) 通过在抗蚀剂图案的表面上进行水洗除去,并且通过水洗除去未改性的水溶性树脂膜的部分,并且能够将抗蚀剂图案的分离尺寸和开孔尺寸有效地缩小到比 曝光波长分辨率的极限。 作为水溶性乙烯基树脂,优选使用丙烯酰胺,乙烯基吡咯烷酮或乙烯基咪唑等含氮乙烯基单体的均聚物,两种以上含氮乙烯基单体的共聚物,或至少一种含氮乙烯基单体的共聚物, 含有乙烯基单体和至少一种无氮乙烯基单体。
    • 5. 发明申请
    • COMMUNICATION NETWORK CONTROL SYSTEM, RADIO COMMUNICATION APPARTUS, AND COMMUNICATION NETWORK CONTROL METHOD
    • 通信网络控制系统,无线电通信协议和通信网络控制方法
    • US20080045204A1
    • 2008-02-21
    • US11755255
    • 2007-05-30
    • Yusuke TAKANOToshiyuki TAMURA
    • Yusuke TAKANOToshiyuki TAMURA
    • H04Q7/20
    • H04W28/06H04W48/06
    • The present invention can provide a radio communication apparatus comprising an antenna which receives a restriction signal from a radio base station, a reception circuit which decodes the restriction signal received by said antenna, and a control circuit which controls the radio communication apparatus, in which the control circuit can be adapted to select appropriately a speech outgoing/incoming scheme for performing communication with the radio base station on the basis of the restriction signal from the radio base station. As the speech outgoing/incoming scheme, a domain scheme or a speech communication scheme is used. In addition, the present invention further provides a communication network control system using the radio communication apparatus, and a communication network control method.
    • 本发明可以提供一种无线电通信装置,其包括从无线电基站接收限制信号的天线,对由所述天线接收的限制信号进行解码的接收电路和控制无线电通信装置的控制电路, 控制电路可以适于根据来自无线电基站的限制信号适当地选择用于与无线电基站进行通信的语音输出/输入方案。 作为语音输出/输入方案,使用域方案或语音通信方案。 另外,本发明还提供一种使用该无线通信装置的通信网络控制系统和通信网络控制方法。
    • 7. 发明申请
    • Micropattern formation material and method of micropattern formation
    • 微图案形成材料和微图案形成方法
    • US20070059644A1
    • 2007-03-15
    • US10557926
    • 2004-06-04
    • Kiyohisa TakahashiYusuke Takano
    • Kiyohisa TakahashiYusuke Takano
    • G03C5/00
    • H01L21/0274G03F7/0035G03F7/40
    • The present invention provides a method of forming a fine pattern, comprising the steps of forming a resist pattern 3 made of a chemically amplified photoresist on a substrate 1 with a diameter of 6 inches or more, applying a fine pattern forming material containing a water-soluble resin, a water-soluble crosslinking agent and water or a mixed solvent of water and a water-soluble organic solvent to form a coated layer 4, baking the chemically amplified photoresist pattern and the coated layer, and developing the coated layer after baking, wherein the water-soluble resin in the fine pattern forming material is a water-soluble resin, the peak temperature of heat of fusion of which in a DSC curve is higher than the baking temperature in the above baking step and simultaneously higher than 130° C.
    • 本发明提供一种形成精细图案的方法,包括以下步骤:在直径为6英寸或更大的基底1上形成由化学放大光致抗蚀剂制成的抗蚀剂图案3,施加含有水溶性聚合物的精细图案形成材料, 可溶性树脂,水溶性交联剂和水或水和水溶性有机溶剂的混合溶剂形成涂层4,烘烤化学放大的光致抗蚀剂图案和涂层,并烘烤后显影涂层, 其中精细图案形成材料中的水溶性树脂是水溶性树脂,其DSC曲线中的熔化热的峰值温度高于上述烘烤步骤中的烘烤温度,同时高于130℃ 。
    • 8. 发明授权
    • Method for forming pattern and treating agent for use therein
    • 用于形成图案和处理剂的方法
    • US07018785B2
    • 2006-03-28
    • US10416412
    • 2001-10-24
    • Kazuyo OnoYusuke TakanoHatsuyuki TanakaSatoru Funato
    • Kazuyo OnoYusuke TakanoHatsuyuki TanakaSatoru Funato
    • G03F7/00
    • G03F7/0382G03F7/0392G03F7/168
    • A method of forming resist patterns comprises the steps of (a) applying and forming a chemically amplified photoresist film, (b) applying a treating agent with a pH value of 1.3 to 4.5 onto said chemically amplified photoresist film, (c) baking said chemically amplified photoresist film after at least one of the steps of applying and forming said chemically amplified photoresist film and applying said treating agent, (d) selectively exposing said chemically amplified photoresist film, (e) post exposure-baking said chemically amplified photoresist film, and (f) developing said chemically amplified photoresist film, wherein the contact angle of a non-exposed portion of said chemically amplified photoresist film to a developing solution after wash with water to remove the treating agent on the photoresist and spin-drying before development is made lower by 10° to 110° than that in the case where said treating agent is not applied. In this method, the wetting property of the developing solution to the photoresist film are improved and the influence of floating basic species are reduced by the action of an acid component such as organic acid contained in the treating agent to form resist patterns with good shape.
    • 形成抗蚀剂图案的方法包括以下步骤:(a)施加和形成化学放大的光致抗蚀剂膜,(b)将pH值为1.3至4.5的处理剂施加到所述化学放大的光致抗蚀剂膜上,(c) 在施加和形成所述化学放大光致抗蚀剂膜并施加所述处理剂的步骤中的至少一个步骤之后,(d)选择性地暴露所述化学放大的光致抗蚀剂膜,(e)曝光后曝光烘烤所述化学放大的光致抗蚀剂膜,以及 (f)显影所述化学放大型光致抗蚀剂膜,其中使用所述化学放大的光致抗蚀剂膜的未曝光部分与水洗涤后的显影溶液的接触角,以除去光刻胶上的处理剂并在显影前进行旋转干燥 比不使用所述处理剂的情况低10°〜110°。 在该方法中,改善了显影液对光致抗蚀剂膜的润湿性能,并且由于处理剂中所含的有机酸等酸成分的作用,漂浮的碱性物质的影响降低,形成具有良好形状的抗蚀剂图案。
    • 9. 发明授权
    • Apparatus for detecting defects of wires on a wiring board wherein
optical sensor includes a film of polymer non-linear optical material
    • 用于检测布线板上的导线缺陷的装置,其中光学传感器包括聚合物非线性光学材料的薄膜
    • US5844249A
    • 1998-12-01
    • US779571
    • 1997-01-07
    • Yusuke TakanoShizuo OguraTsunetoshi SugiyamaWen-Bing Kang
    • Yusuke TakanoShizuo OguraTsunetoshi SugiyamaWen-Bing Kang
    • G01N21/956G01R31/309G01N21/86
    • G01N21/956G01R31/309
    • A detecting apparatus capable of supporting even narrow wire widths and of detecting defects of wires in a non-contact manner is provided. The detecting apparatus comprises an optical sensor, a sensor head, and a signal processing unit. The optical sensor comprises a transparent substrate, a transparent electrode disposed on the transparent substrate, a thin film of a polymer non-linear optical material disposed on the transparent electrode, and a reflective film disposed on the thin film, and is positioned in close approximation to and without contacting an electrode to be measured on the wiring board. The sensor head comprises a light source, optical means for guiding light from the light source into the optical sensor, and detecting means for detecting reflected light from the optical sensor. The detecting means supplies the signal processing unit with a signal corresponding to the intensity of the reflected light when the electrode on the wiring board is applied with a voltage.
    • 提供能够以非接触方式支持甚至窄线宽度和检测线的缺陷的检测装置。 检测装置包括光学传感器,传感器头和信号处理单元。 光学传感器包括透明基板,设置在透明基板上的透明电极,设置在透明电极上的聚合物非线性光学材料的薄膜和设置在薄膜上的反射膜,并且近似定位 在接线板上接触和不接触要测量的电极。 传感器头包括光源,用于将来自光源的光引导到光学传感器中的光学装置,以及用于检测来自光学传感器的反射光的检测装置。 当施加电压时,检测装置向信号处理单元提供与反射光的强度对应的信号。
    • 10. 发明授权
    • Communication network control system, radio communication apparatus, and communication network control method
    • 通信网络控制系统,无线通信装置和通信网络控制方法
    • US08929884B2
    • 2015-01-06
    • US13861811
    • 2013-04-12
    • Yusuke TakanoToshiyuki Tamura
    • Yusuke TakanoToshiyuki Tamura
    • H04W28/06H04W48/06
    • H04W28/06H04W48/06
    • The present invention can provide a radio communication apparatus comprising an antenna which receives a restriction signal from a radio base station, a reception circuit which decodes the restriction signal received by said antenna, and a control circuit which controls the radio communication apparatus, in which the control circuit can be adapted to select appropriately a speech outgoing/incoming scheme for performing communication with the radio base station on the basis of the restriction signal from the radio base station. As the speech outgoing/incoming scheme, a domain scheme or a speech communication scheme is used. In addition, the present invention further provides a communication network control system using the radio communication apparatus, and a communication network control method.
    • 本发明可以提供一种无线电通信装置,其包括从无线电基站接收限制信号的天线,对由所述天线接收的限制信号进行解码的接收电路和控制无线电通信装置的控制电路, 控制电路可以适于根据来自无线电基站的限制信号适当地选择用于与无线电基站进行通信的语音输出/输入方案。 作为语音输出/输入方案,使用域方案或语音通信方案。 另外,本发明还提供一种使用该无线通信装置的通信网络控制系统和通信网络控制方法。