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1. 发明申请

WO2017087710A2 PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS 审中-公开
标题翻译：通过烯烃产物生产脂肪族烯烃衍生物
公开(公告)号：WO2017087710A2
公开(公告)日：2017-05-26
申请号：PCT/US2016/062595
申请日：2016-11-17
申请人： PROVIVI, INC. , ONDI, Levente , MEHDI, Hasan
发明人： ONDI, Levente , MEHDI, Hasan , WAMPLER, Keith M. , MEINHOLD, Peter , COELHO, Pedro , BUI, Vu
IPC分类号： C07C67/293 , C07C69/533
CPC分类号： B01J31/2278 , B01J2231/543 , B01J2531/64 , B01J2531/66 , C07B2200/09 , C07C6/04 , C07C29/147 , C07C45/41 , C07C67/08 , C07C67/293 , C07C67/343 , C07C2531/22 , C07C69/533 , C07C33/025 , C07C69/145 , C07C47/21 , C07C11/21
摘要： The invention provides a method for synthesizing a fatty olefin derivative. In some embodiments, the method includes: a) contacting an unsaturated olefin with an unsaturated fatty acid ester in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product and b) converting the metathesis product to the fatty olefin derivative. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is an insect pheromone. Pheromone compositions and methods of using them are also described.
摘要翻译：本发明提供了用于合成脂肪烯烃衍生物的方法。在一些实施方案中，该方法包括：a）在足以形成复分解产物的条件下，在易位催化剂存在下，使不饱和烯烃与不饱和脂肪酸酯接触，和b）将复分解产物转化为脂肪烯烃衍生物。在某些实施方案中，复分解催化剂是钨催化剂或钼催化剂。在不同的实施方案中，脂肪烯烃衍生物是昆虫信息素。还介绍了信息素组合物及其使用方法。

2. 发明申请

WO2015164464A1 HIGH ACTIVITY HYDROTREATING CATALYSTS 审中-公开
标题翻译：高活性加氢催化剂
公开(公告)号：WO2015164464A1
公开(公告)日：2015-10-29
申请号：PCT/US2015/027017
申请日：2015-04-22
申请人： ADVANCED REFINING TECHNOLOGIES LLC
发明人： ZHANG, Shuguang , YU, Xianghua , MALICK, Gill , NESCI, Bruno , SATERNUS, Henry , JIA, Jifei , RADLOWSKI, Cecelia , MAESEN, Theodorus Ludovicus Michael , MIEDONA, Colleen
IPC分类号： B01J31/04 , C10G45/08
CPC分类号： B01J31/04 , B01J23/85 , B01J27/19 , B01J35/002 , B01J35/026 , B01J37/0203 , B01J37/08 , B01J37/086 , B01J37/20 , B01J2231/648 , B01J2531/64 , B01J2531/845 , B01J2531/847 , C10G45/06 , C10G45/08 , C10G2300/104 , C10G2300/1044 , C10G2300/1055 , C10G2300/202 , C10G2300/70 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： This disclosure relates to supported multi-metallic catalysts for use in the hydrotreating of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIB metal, at least one Group VIII metal and an organic acid. The catalyst precursor is thermally treated to partially decompose the organic acid, then sulfided. The catalysts have a high carbon-as-carboxyl to total carbon ratio (C carboxy /C total ) as a result of a unique post-metal calcination method employed during the manufacture of the catalyst. As a result, the hydrotreating catalysts have lower percent weight loss-on-ignition, higher activity and longer catalyst life.
摘要翻译：本公开涉及用于烃进料加氢处理的负载型多金属催化剂，以及制备这种催化剂的方法。催化剂由包含至少一种VIB族金属，至少一种第Ⅷ族金属和有机酸的催化剂前体制备。将催化剂前体进行热处理以部分分解有机酸，然后硫化。由于在制造催化剂期间采用独特的后金属煅烧方法，催化剂具有高碳 - 羧 - 总碳比（C羧基/ C总量）。因此，加氢处理催化剂具有较低的失重重量百分比，更高的活性和更长的催化剂寿命。

3. 发明申请

WO2015079321A3 ALKANE METATHESIS CATALYST, METHODS OF USE AND THE PREPARATION THEREOF 审中-公开
标题翻译： ALKANE METATHESIS催化剂，使用方法及其制备方法
公开(公告)号：WO2015079321A3
公开(公告)日：2015-07-23
申请号：PCT/IB2014003060
申请日：2014-11-26
申请人： UNIV KING ABDULLAH SCI & TECH
发明人： BASSET JEAN-MARIE MAURINCE , CALLENS EMMANUEL , RIACHE NASSIMA , SAMANTARAY MANOJA KUMAR , ABOU-HAMAD EDY
IPC分类号： B01J31/22 , B01J21/08 , B01J31/12 , B01J37/08 , C07C6/10
CPC分类号： B01J31/122 , B01J21/08 , B01J31/1625 , B01J31/2226 , B01J31/2265 , B01J31/26 , B01J37/0203 , B01J37/0209 , B01J2231/54 , B01J2531/50 , B01J2531/56 , B01J2531/58 , B01J2531/60 , B01J2531/64 , B01J2531/66 , B01J2531/70 , C07C6/10 , C07C2531/12 , C07C2531/26 , C07F11/00 , C07C13/02
摘要： The invention concerns an alkane metathesis catalyst, its production and use. The catalyst comprises a Group V, VI or VII metal alkyl with the metal in its highest oxidation state, preferably Ta or W, and the alkyl of C1-C4, preferably together with alkylidene and/or alkylidyne ligands, in particular -Me, =CH2 and ≡CH, on a metal oxide support, preferably silica partially dehydroxylated at 200 or 700 °C. Substrates include cycloalkanes, preferably cyclooctane.
摘要翻译：本发明涉及烷烃复分解催化剂，其生产和使用。该催化剂包括V，VI或VII族金属烷基，其金属处于最高氧化态，优选为Ta或W，且C 1 -C 4的烷基优选与亚烷基和/或亚烷基炔配体一起，特别是Me = CH2和≡CH，在金属氧化物载体上，优选在200或700℃下部分脱羟基化的二氧化硅。底物包括环烷烃，优选环辛烷。

4. 发明申请

WO2015056117A3 SULFOXIDATION CATALYSTS AND METHODS FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：氧化催化剂及其制备和使用方法
公开(公告)号：WO2015056117A3
公开(公告)日：2015-06-18
申请号：PCT/IB2014064308
申请日：2014-09-08
申请人： INDIAN INST TECHNOLOGY MADRAS
发明人： CHAND DILLIP KUMAR , CHAKRAVARTHY RAJAN DEEPAN
IPC分类号： B01J31/02 , B01J31/22
CPC分类号： C07F11/005 , B01J31/0239 , B01J31/2213 , B01J31/2239 , B01J31/2295 , B01J37/031 , B01J37/12 , B01J2231/70 , B01J2231/72 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/96 , C07C211/63 , C07C315/02 , C07D319/06
摘要： Methods and compositions of catalysts for sulfoxidation reaction processes are disclosed. The sulfoxidation reaction process can be performed in an aqueous medium, and the catalysts can be recycled for further use. In some embodiments, a method of making a catalyst may include contacting a transition metal compound with an oxidizing agent to form a first solution, contacting a carboxylic acid compound with a cationic surfactant to form a second solution, mixing the first solution and the second solution to form a precipitate, and isolating the precipitate.
摘要翻译：公开了用于磺化氧化反应过程的催化剂的方法和组合物。磺化氧化反应过程可以在含水介质中进行，并且催化剂可以循环使用以供进一步使用。在一些实施方案中，制备催化剂的方法可以包括使过渡金属化合物与氧化剂接触以形成第一溶液，使羧酸化合物与阳离子表面活性剂接触以形成第二溶液，混合第一溶液和第二溶液形成沉淀物，分离沉淀物。

5. 发明申请

WO2015056117A2 SULFOXIDATION CATALYSTS AND METHODS FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：硫化催化剂及其制备和使用方法
公开(公告)号：WO2015056117A2
公开(公告)日：2015-04-23
申请号：PCT/IB2014/064308
申请日：2014-09-08
申请人： INDIAN INSTITUTE OF TECHNOLOGY MADRAS
发明人： CHAND, Dillip Kumar , CHAKRAVARTHY, Rajan Deepan
IPC分类号： B01J31/02
CPC分类号： C07F11/005 , B01J31/0239 , B01J31/2213 , B01J31/2239 , B01J31/2295 , B01J37/031 , B01J37/12 , B01J2231/70 , B01J2231/72 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/96 , C07C211/63 , C07C315/02 , C07D319/06
摘要： Methods and compositions of catalysts for sulfoxidation reaction processes are disclosed. The sulfoxidation reaction process can be performed in an aqueous medium, and the catalysts can be recycled for further use. In some embodiments, a method of making a catalyst may include contacting a transition metal compound with an oxidizing agent to form a first solution, contacting a carboxylic acid compound with a cationic surfactant to form a second solution, mixing the first solution and the second solution to form a precipitate, and isolating the precipitate.
摘要翻译：公开了用于磺化氧化反应方法的催化剂的方法和组合物。该磺化氧化反应方法可以在水性介质中进行，并且催化剂可以再循环使用。在一些实施方案中，制备催化剂的方法可包括使过渡金属化合物与氧化剂接触以形成第一溶液，使羧酸化合物与阳离子表面活性剂接触以形成第二溶液，将第一溶液和第二溶液以形成沉淀物，并分离沉淀物。

6. 发明申请

WO2014139679A8 METATHESIS CATALYSTS AND REACTIONS USING THE CATALYSTS 审中-公开
标题翻译：使用催化剂的METATHESIS催化剂和反应
公开(公告)号：WO2014139679A8
公开(公告)日：2014-12-11
申请号：PCT/EP2014000671
申请日：2014-03-13
申请人： XIMO AG
发明人： ONDI LEVENTE , VARGA JENO , BUCSAI AGOTA , TOTH FLORIAN , LORINCZ KRISZTIAN , HEGEDUS CSABA , ROBE EMMANUEL , FRÁTER GEORG
IPC分类号： B01J31/22
CPC分类号： B01J31/2265 , B01J31/143 , B01J31/1608 , B01J31/1805 , B01J31/181 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J2231/543 , B01J2531/0266 , B01J2531/0288 , B01J2531/64 , B01J2531/66 , B01J2540/20 , B01J2540/22 , B01J2540/225 , C07C6/04 , C07C67/293 , C07C67/347 , C07C2531/12 , C07C2531/22 , C07C2601/10 , C07F11/00 , C08G61/08 , C08G2261/418 , C07C11/02
摘要： The invention relates to a method of forming an olefin from a first olefin and a second olefin in a metathesis reaction, comprising step (i): (i) reacting the first olefin with the second olefin in the presence of a compound that catalyzes said metathesis reaction such that the molar ratio of said compound to the first or the second olefin is from 1 : 500 or less, and the conversion of the first or the second olefin to said olefin is at least 50 %, characterized in that as compound that catalyzes said metathesis reaction a compound of formula (A) is used: wherein M is Mo or W; R1 is aryl, heteroaryl, alkyl, or heteroalkyl; optionally substituted; R2 and R3 can be the same or different and are hydrogen, alkyl, alkenyl, heteroalkyl, heteroalkenyl, aryl, or heteroaryl; optionally substituted; R5 is alkyl, alkoxy, heteroalkyl, aryl, heteroaryl, silylalkyl, silyloxy, optionally substituted; and R4 is a residue R6-X-, wherein X = O and R6 is aryl, optionally substituted; or X = S and R6 is aryl, optionally substituted; or X = O and R6 is (R7, R8, R9)Si; wherein R7, R8, R9 are alkyl or phenyl, optionally substituted; or X = O and R6 is (R10, R11, R12)C, wherein R10, R11, R12 are independently selected from phenyl, alkyl; optionally substituted; and to the catalysts used in the method.
摘要翻译：本发明涉及一种在复分解反应中由第一种烯烃和第二种烯烃形成烯烃的方法，包括步骤（i）：（i）在催化所述复分解的化合物存在下，使第一种烯烃与第二种烯烃反应使得所述化合物与第一或第二烯烃的摩尔比为1:500以下，第一或第二烯烃向所述烯烃的转化率为至少50％，其特征在于，作为催化剂的化合物所述复分解反应使用式（A）化合物：其中M是Mo或W; R 1是芳基，杂芳基，烷基或杂烷基; 任选取代; R2和R3可以相同或不同，为氢，烷基，烯基，杂烷基，杂烯基，芳基或杂芳基; 任选取代; R5是烷基，烷氧基，杂烷基，芳基，杂芳基，甲硅烷基烷基，甲硅烷基氧基，任意取代的; R4为残基R6-X-，其中X = O，R6为芳基，任选取代; 或X = S和R 6为芳基，任选取代; 或X = O，R6是（R7，R8，R9）Si; 其中R 7，R 8，R 9为烷基或苯基，任选取代; 或X = O，R 6是（R 10，R 11，R 12）C，其中R 10，R 11，R 12独立地选自苯基，烷基，任选取代; 以及该方法中使用的催化剂。

7. 发明申请

WO2012167171A3 Z-SELECTIVE RING-CLOSING METATHESIS REACTIONS 审中-公开
标题翻译： Z选择性环闭合细胞反应
公开(公告)号：WO2012167171A3
公开(公告)日：2014-05-01
申请号：PCT/US2012040574
申请日：2012-06-01
申请人： MASSACHUSETTS INST TECHNOLOGY , TRUSTEES BOSTON COLLEGE , HOVEYDA AMIR H , YU MIAO , WANG CHENBO , SCHROCK RICHARD R
发明人： HOVEYDA AMIR H , YU MIAO , WANG CHENBO , SCHROCK RICHARD R
IPC分类号： C07C4/02
CPC分类号： C07F11/00 , B01J31/2208 , B01J31/2265 , B01J31/2278 , B01J31/2295 , B01J2231/543 , B01J2531/64 , B01J2531/66 , C07B37/10 , C07D225/02 , C07D245/02 , C07D267/00 , C07D313/00 , C07D417/06 , C07D491/18 , C07D491/22 , C07D493/04
摘要： The present invention relates generally to olefin metathesis. In some embodiments, the present invention provides methods for Z-selective ring-closing metathesis.
摘要翻译：本发明一般涉及烯烃复分解。在一些实施方案中，本发明提供了Z选择性闭环复分解的方法。

8. 发明申请

WO2013043767A3 RHENIUM CONTAINING HYDROSILYLATION CATALYSTS AND COMPOSITIONS CONTAINING THE CATALYSTS 审中-公开
标题翻译：含有氢化催化剂的铑和含有催化剂的组合物
公开(公告)号：WO2013043767A3
公开(公告)日：2013-06-27
申请号：PCT/US2012056173
申请日：2012-09-20
申请人： DOW CORNING
发明人： BRANDSTADT KURT , COOK SIMON , NGUYEN BINH THANH , SURGENOR AVRIL , TAYLOR RICHARD , TZOU MING-SHIN , DASH ASWINI
IPC分类号： C07F13/00
CPC分类号： B01J31/2295 , B01J31/0272 , B01J31/22 , B01J31/24 , B01J31/2414 , B01J31/2433 , B01J37/00 , B01J2231/323 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/49 , B01J2531/56 , B01J2531/64 , B01J2531/74 , B01J2531/821 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C209/66 , C07C213/08 , C07C217/92 , C07D213/32 , C07D213/38 , C07D213/53 , C07D215/12 , C07D271/06 , C07D295/135 , C07D307/52 , C07D333/22 , C07D413/10 , C07D413/14 , C07F1/00 , C07F1/005 , C07F1/08 , C07F3/06 , C07F7/00 , C07F7/0809 , C07F7/0849 , C07F7/0867 , C07F7/0872 , C07F7/0879 , C07F7/0889 , C07F7/0896 , C07F7/1844 , C07F7/1864 , C07F7/1868 , C07F7/1876 , C07F9/5045 , C07F9/60 , C07F11/005 , C07F13/00 , C07F13/005 , C07F15/0033 , C07F15/0046 , C07F15/02 , C07F15/065 , C08G77/08 , C09K3/00 , G07F13/00
摘要： A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition ' capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
摘要翻译：组合物含有（A）氢化硅烷化反应催化剂和（B）具有每分子平均能够进行氢化硅烷化反应的一种或多种脂族不饱和有机基团的脂族不饱和化合物。该组合物能够通过氢化硅烷化反应反应形成反应产物，例如硅烷，胶，凝胶，橡胶或树脂。成分（A）含有可以通过使金属前体和配体反应的方法制备的金属 - 配体络合物。

9. 发明申请

WO2013043792A3 COPPER CONTAINING HYDROSILYLATION CATALYSTS AND COMPOSITIONS CONTAINING THE CATALYSTS 审中-公开
标题翻译：含铜的加氢甲硅烷基化催化剂和含催化剂的组合物
公开(公告)号：WO2013043792A3
公开(公告)日：2013-06-20
申请号：PCT/US2012056214
申请日：2012-09-20
申请人： DOW CORNING
发明人： BRANDSTADT KURT , COOK SIMON , NGUYEN BINH THANH , SURGENOR AVRIL , TAYLOR RICHARD , TZOU MING-SHIN
IPC分类号： C07F1/08
CPC分类号： B01J31/2295 , B01J31/0272 , B01J31/22 , B01J31/24 , B01J31/2414 , B01J31/2433 , B01J37/00 , B01J2231/323 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/49 , B01J2531/56 , B01J2531/64 , B01J2531/74 , B01J2531/821 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C209/66 , C07C213/08 , C07C217/92 , C07D213/32 , C07D213/38 , C07D213/53 , C07D215/12 , C07D271/06 , C07D295/135 , C07D307/52 , C07D333/22 , C07D413/10 , C07D413/14 , C07F1/00 , C07F1/005 , C07F1/08 , C07F3/06 , C07F7/00 , C07F7/0809 , C07F7/0849 , C07F7/0867 , C07F7/0872 , C07F7/0879 , C07F7/0889 , C07F7/0896 , C07F7/1844 , C07F7/1864 , C07F7/1868 , C07F7/1876 , C07F9/5045 , C07F9/60 , C07F11/005 , C07F13/00 , C07F13/005 , C07F15/0033 , C07F15/0046 , C07F15/02 , C07F15/065 , C08G77/08 , C09K3/00 , G07F13/00
摘要： A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.
摘要翻译：组合物含有（A）氢化硅烷化反应催化剂和（B）每分子具有一个或多个能够经历氢化硅烷化反应的脂族不饱和有机基团的脂族不饱和化合物。该组合物能够通过氢化硅烷化反应反应以形成反应产物，例如硅烷，树胶，凝胶，橡胶或树脂。成分（A）含有可通过包括使金属前体和配体反应的方法制备的金属 - 配体络合物。

10. 发明申请

WO2013043785A2 NICKEL CONTAINING HYDROSILYLATION CATALYSTS AND COMPOSITIONS CONTAINING THE CATALYSTS 审中-公开
标题翻译：含镍氢化催化剂和含有催化剂的组合物
公开(公告)号：WO2013043785A2
公开(公告)日：2013-03-28
申请号：PCT/US2012/056202
申请日：2012-09-20
申请人： DOW CORNING CORPORATION
发明人： BRANDSTADT, Kurt , COOK, Simon , NGUYEN, Binh, Thanh , SURGENOR, Avril , TAYLOR, Richard , TZOU, Ming-Shin
IPC分类号： C07F15/04
CPC分类号： B01J31/2295 , B01J31/0272 , B01J31/22 , B01J31/24 , B01J31/2414 , B01J31/2433 , B01J37/00 , B01J2231/323 , B01J2531/16 , B01J2531/17 , B01J2531/46 , B01J2531/49 , B01J2531/56 , B01J2531/64 , B01J2531/74 , B01J2531/821 , B01J2531/827 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C209/66 , C07C213/08 , C07C217/92 , C07D213/32 , C07D213/38 , C07D213/53 , C07D215/12 , C07D271/06 , C07D295/135 , C07D307/52 , C07D333/22 , C07D413/10 , C07D413/14 , C07F1/00 , C07F1/005 , C07F1/08 , C07F3/06 , C07F7/00 , C07F7/0809 , C07F7/0849 , C07F7/0867 , C07F7/0872 , C07F7/0879 , C07F7/0889 , C07F7/0896 , C07F7/1844 , C07F7/1864 , C07F7/1868 , C07F7/1876 , C07F9/5045 , C07F9/60 , C07F11/005 , C07F13/00 , C07F13/005 , C07F15/0033 , C07F15/0046 , C07F15/02 , C07F15/065 , C08G77/08 , C09K3/00 , G07F13/00
摘要： A composition contains (A) a hydrosi!ylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per moiecuie, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosiiyiaiion reaction. The composition is capable of reacting via hydrosiiyiation reaction to form a reaction product, such as a si!ane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metai-iigand complex that can be prepared by a method including reacting a metal precursor and a !igand,
摘要翻译：组合物包含（A）水解反应催化剂和（B）具有平均每摩尔一个或多个能够进行水解反应的脂族不饱和有机基团的脂族不饱和化合物。组合物能够通过加氢反应反应形成反应产物，例如硅胶，胶，凝胶，橡胶或树脂。成分（A）含有可通过包括使金属前体和配体反应的方法制备的均匀配合物，

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