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1. 发明申请

WO2016149027A2 PROCESS FOR OLIGOMERIZATION 审中-公开
标题翻译：低分子化过程
公开(公告)号：WO2016149027A2
公开(公告)日：2016-09-22
申请号：PCT/US2016/021709
申请日：2016-03-10
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： KLOSIN, Jerzy , MILBRANDT, Kara A. , BOELTER, Scott D. , WILSON, David R. , ROSEN, Mari S. , WELSH, Dean M. , MARGL, Peter M. , KOH, Kyoung Moo , PEARSON, David M. , HUACUJA, Rafael
IPC分类号： B01J31/24
CPC分类号： B01J31/2433 , B01J31/143 , B01J31/188 , B01J31/2208 , B01J31/2438 , B01J31/2457 , B01J31/2476 , B01J31/2495 , B01J2231/20 , B01J2531/62 , B01J2540/10 , B01J2540/22 , B01J2540/225 , B01J2540/30 , B01J2540/34 , B01J2540/444 , C07C2/36 , C07C2531/14 , C07C2531/18 , C07C2531/24 , C07F9/6568 , C07F9/65683 , C07F9/65685 , C07F9/6571 , C07F9/657154 , C07F9/65842 , C07F9/65844 , C07F9/65846 , C07F9/65848 , C07F11/005 , C07F17/02 , C07C11/02 , C07C11/107
摘要： The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Addtionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
摘要翻译：本发明涉及使用包括a）铬源b）一种或多种活化剂的催化剂体系将烯烃如乙烯低聚成高级烯烃，例如1-己烯和1-辛烯的混合物，和c）含磷酸基的连接化合物。此外，本发明涉及含有磷酸酯基的连接化合物和制备所述化合物的方法。

2. 发明申请

WO2013057289A3 CATALYST COMPOSITIONS COMPRISING A GRUBBS - HOVEYDA TYPE COMPLEX AND A TERMINAL OLEFIN AND THEIR USE FOR HYDROGENATION OF NITRILE RUBBER 审中-公开
标题翻译：含有GRUBBS - HOVEYDA型复合物和终端烯烃的催化剂组合物及其用于氢化NITRILE橡胶的用途
公开(公告)号：WO2013057289A3
公开(公告)日：2013-09-26
申请号：PCT/EP2012070815
申请日：2012-10-19
申请人： LANXESS DEUTSCHLAND GMBH
发明人： OBRECHT WERNER , DAVID SARAH , LIU QINGCHUN , WEI ZHENLI
IPC分类号： B01J31/22 , B01J31/02 , C08C19/02
CPC分类号： B01J31/2295 , B01J31/0204 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J2231/543 , B01J2231/641 , B01J2231/645 , B01J2531/821 , B01J2531/825 , B01J2540/22 , B01J2540/34 , B01J2540/62 , C08C19/02 , C08C2019/09
摘要： This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts of the Grubbs- Hoveyda, Grela or Zhan type and specific co-catalysts comprising at least one vinyl group, pref. ethyl vinyl ether, and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions, preferably with a preceding metathesis step using the same complex catalyst as in the hydrogenation step.
摘要翻译：本发明涉及基于Grubbs-Hoveyda，Grela或Zhan型的钌或锇基络合物催化剂和包含至少一种乙烯基的特定助催化剂的新型催化剂组合物。乙基乙烯基醚，以及在这种催化剂组合物的存在下选择性氢化丁腈橡胶的方法，优选使用与氢化步骤中相同的络合催化剂的前述复分解步骤。

3. 发明申请

WO2013079421A1 VERFAHREN ZUR UMSETZUNG VON KOHLENDIOXID UND BIKARBONATEN ZU AMEISENSÄUREDERIVATEN UNTER VERWENDUNG EINES KOBALTKOMPLEXES ALS KATALYTISCHES SYSTEM 审中-公开
标题翻译：程序履行二氧化碳和碳酸氢盐使用钴复合催化体系FORMIC衍生物
公开(公告)号：WO2013079421A1
公开(公告)日：2013-06-06
申请号：PCT/EP2012/073550
申请日：2012-11-26
申请人： BAYER TECHNOLOGY SERVICES GMBH
发明人： JACKSTELL, Ralf , ZIEBART, Carolin , FEDERSEL, Christopher , BELLER, Matthias
IPC分类号： B01J31/24 , B01J31/18 , B01J31/22 , C07C51/00 , C07C53/06 , C07C69/06 , C07C233/03
CPC分类号： B01J31/2409 , B01J31/1805 , B01J31/189 , B01J31/2208 , B01J31/226 , B01J2231/62 , B01J2231/625 , B01J2531/0247 , B01J2531/845 , C07C51/00 , C07C51/41 , C07C67/00 , C07C67/08 , C07C231/10 , C07C231/14 , C07C233/03 , C07C69/06 , C07C53/06
摘要： Die Erfindung betrifft ein Verfahren zur Umsetzung von Kohlendioxid oder Bikarbonaten zu Ameisensäurederivaten, d.h. Formiat-Salze, Formiat-Ester und Formamide, unter Verwendung von molekularem Wasserstoff und eines katalytischen Systems bestehend aus einem Kobaltkomplex aus Kobaltsalz und mindestens einem tripodalen tetradentaten Liganden. Der Katalysatorkomplex kann als homogener Katalysator Verwendung finden. Gegenstand der Erfindung sind auch die Kobaltkomplexe an sich.
摘要翻译：本发明涉及一种用于二氧化碳向甲酸或碳酸氢盐衍生物，即转换甲酸盐，甲酸酯和甲酰胺，使用分子氢和由钴盐的钴络合物的催化体系与至少一种三足四齿配体。所述催化剂复合物可以用作均相催化剂。本发明还钴配合物本身。

4. 发明申请

WO2013056400A1 CATALYST COMPOSITIONS AND THEIR USE FOR HYDROGENATION OF NITRILE RUBBER 审中-公开
标题翻译：催化剂组合物及其用于氢化橡胶的用途
公开(公告)号：WO2013056400A1
公开(公告)日：2013-04-25
申请号：PCT/CN2011/001753
申请日：2011-10-21
申请人： LANXESS DEUTSCHLAND GMBH , LIU, Qingchun , WEI, Zhenli , OBRECHT, Werner , DAVID, Sarah
发明人： LIU, Qingchun , WEI, Zhenli , OBRECHT, Werner , DAVID, Sarah
IPC分类号： C07F15/00 , C08F4/80
CPC分类号： B01J31/2295 , B01J31/0204 , B01J31/1805 , B01J31/2208 , B01J31/2273 , B01J31/2278 , B01J31/2404 , B01J2231/543 , B01J2231/641 , B01J2231/645 , B01J2531/821 , B01J2531/825 , B01J2540/22 , B01J2540/34 , B01J2540/62 , C08C19/02 , C08C2019/09
摘要： Novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and specific co-catalyst and a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions are disclosed.
摘要翻译：公开了基于钌或锇基络合物催化剂和特定助催化剂的新型催化剂组合物和在这种催化剂组合物存在下选择性氢化腈橡胶的方法。

5. 发明申请

WO2013036550A1 HAFNIUM CONTAINING COMPLEX AND CONDENSATION REACTION CATALYSTS, METHODS FOR PREPARING THE CATALYSTS, AND COMPOSITIONS CONTAINING THE CATALYSTS 审中-公开
标题翻译： HAFNIUM包含复杂和缩合反应的催化剂，其制备方法的催化剂和组合物含催化剂
公开(公告)号：WO2013036550A1
公开(公告)日：2013-03-14
申请号：PCT/US2012/053821
申请日：2012-09-06
申请人： DOW CORNING CORPORATION , BRANDSTADT, Kurt , COOK, Simon , DIAMOND, Gary , HALL, Keith , LOWER, Loren , SURGENOR, Avril , TAYLOR, Richard , TONGE, James , TZOU, Ming-shin
发明人： BRANDSTADT, Kurt , COOK, Simon , DIAMOND, Gary , HALL, Keith , LOWER, Loren , SURGENOR, Avril , TAYLOR, Richard , TONGE, James , TZOU, Ming-shin
IPC分类号： C08L83/04 , C08K5/00 , C08L101/10 , B01J31/38
CPC分类号： C08G77/08 , B01J31/2208 , B01J31/2226 , B01J31/223 , B01J31/2243 , B01J31/2247 , B01J31/226 , B01J2531/49 , C08L83/04
摘要： A composition is capable of curing via condensation reaction. The composition uses a new condensation reaction catalyst. The new condensation reaction catalyst is used to replace conventional tin catalysts. The composition can react to form a gum, gel, rubber, or resin.
摘要翻译：组合物能够通过缩合反应固化。该组合物使用新的缩合反应催化剂。新的缩合反应催化剂用于代替常规的锡催化剂。组合物可以反应以形成胶，凝胶，橡胶或树脂。

6. 发明申请

WO2012078002A3 HYDROPROCESSING CATALYST AND METHOD FOR PREPARING SAME 审中-公开
标题翻译：加氢催化剂及其制备方法
公开(公告)号：WO2012078002A3
公开(公告)日：2012-08-02
申请号：PCT/KR2011009495
申请日：2011-12-09
申请人： SK INNOVATION CO LTD , LEE SANG IL , KIM DO WOAN , KOH JAE HYUN , OH SEUNG HOON , JEON HEE JUNG , MOON SANG HEUP , CHO A RA , PARK YOUNG MOO
发明人： LEE SANG IL , KIM DO WOAN , KOH JAE HYUN , OH SEUNG HOON , JEON HEE JUNG , MOON SANG HEUP , CHO A RA , PARK YOUNG MOO
IPC分类号： B01J31/12 , B01J21/12 , B01J29/076 , C01B3/40
CPC分类号： B01J31/38 , B01J23/88 , B01J23/882 , B01J23/888 , B01J31/0201 , B01J31/0207 , B01J31/0208 , B01J31/0209 , B01J31/12 , B01J31/2208 , B01J31/2213 , B01J31/2234 , B01J31/34 , B01J35/023 , B01J37/0201 , B01J37/0205 , B01J37/0219 , B01J37/06 , B01J37/18 , B01J37/20 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847
摘要： The present invention relates to a hydroprocessing catalyst comprising: (i) one or more hydrogenation metal components selected from a group consisting of VIB group metal, VIIB group metal and VIII group metal; and (ii) an organic compound expressed by the following chemical formula 1 or an organic metal compound expressed by the following chemical formula 2. Chemical formula 1: R1COCH2COR2 (where, R1 and R2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy). Chemical formula 2: X( R1COCH1COR2)n (where, X is selected from a group consisting of VIB group metal, VIIB group metal and VIII group metal, R1 and R2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy, and n is an integer of 1 to 6).
摘要翻译：本发明涉及加氢处理催化剂，其包含：（i）选自由VIB族金属，VIIB族金属和VIII族金属组成的组的一种或多种氢化金属组分; 和（ii）由以下化学式1表示的有机化合物或由以下化学式2表示的有机金属化合物：化学式1：R1COCH2COR2（其中，R1和R2彼此相同或不同，并且是一个或更多个选自C1-C12烷基，C6-C12烯丙基，C1-C12烷氧基和羟基的基团。化学式2：X（R1COCH1COR2）n（其中，X选自由VIB族金属，VIIB族金属和VIII族金属组成的组，R1和R2彼此相同或不同，并且是一个或多个基团选自C1至C12烷基，C6至C12烯丙基，C1至C12烷氧基和羟基，并且n是1至6的整数。

7. 发明申请

WO2012004246A2 CATALYST PREPARATION REACTORS FROM CATALYST PRECURSOR USED FOR FEEDING REACTORS TO UPGRADE HEAVY HYDROCARBONACEOUS FEEDSTOCKS. 审中-公开
标题翻译：催化剂制备反应物，用于催化剂前驱体用于反应器升级重质烃源岩。
公开(公告)号：WO2012004246A2
公开(公告)日：2012-01-12
申请号：PCT/EP2011/061284
申请日：2011-07-05
申请人： TOTAL RAFFINAGE MARKETING , BORREMANS, Didier , LACROIX, Maxime , LE LANNIC - DROMARD, Katell , VENDRELL, Gloria
发明人： BORREMANS, Didier , LACROIX, Maxime , LE LANNIC - DROMARD, Katell , VENDRELL, Gloria
IPC分类号： C10G49/00 , C10G49/12 , C10G49/04 , C10G65/02 , B01J27/047 , B01J27/049 , B01J31/22
CPC分类号： B01J31/2295 , B01J23/22 , B01J23/28 , B01J23/70 , B01J23/88 , B01J31/2208 , B01J35/12 , B01J37/18 , B01J37/20 , B01J2231/645 , B01J2231/646 , B01J2531/56 , B01J2531/64 , B01J2531/842 , C10G49/00 , C10G49/04 , C10G49/12 , C10G65/02 , C10G65/12 , C10G2300/1011 , C10G2300/107 , C10G2300/1077 , C10G2300/703 , C10G2300/708 , Y02P30/20
摘要： The invention concerns a process for upgrading heavy hydrocarbonaceous feedstocks in at least one hydroconversion reactor for hydroconversion of said heavy hydrocarbonaceous feedstocks and in at least one hydrotreatment reactor for hydrotreatment of said heavy hydrocarbonaceous feedstocks, said process comprising the preparation of two or more catalysts, each catalyst being prepared from one or more catalyst precursor in at least one specific preparation reactor, said catalyst precursor containing at least one transition metal selected from group IIA, IIIB, IVB, VB, VIB,VIIB,VIII,IB or IIB of the periodic table of elements, and each preparation reactor feeding one or more hydroconversion or hydrotreatment reactor, each catalyst contained in preparation reactors being dedicated to hydroconversion or hydrotreatment of said feedstocks. Such a process permits to obtain, under continuous operating conditions, products of better quality.
摘要翻译：本发明涉及在至少一个加氢转化反应器中对重质烃原料进行升级的方法，用于加氢转化所述重质烃原料和用于加氢处理所述重质烃原料的至少一个加氢处理反应器，所述方法包括制备两种或更多种催化剂，每种催化剂由至少一种特定制备反应器中的一种或多种催化剂前体制备，所述催化剂前体含有选自元素周期表IIA，IIIB，IVB，VB，VIB，VIIB，VIII，IB或IIB族中的至少一种过渡金属并且每个制备反应器供应一个或多个加氢转化或加氢处理反应器，制备反应器中包含的各种催化剂专用于所述原料的加氢转化或加氢处理。这种过程允许在连续的操作条件下获得更好的产品。

8. 发明申请

WO2011069134A3 SUPPORTED OLEFIN METATHESIS CATALYSTS 审中-公开
标题翻译：支持的OLEFIN METATHESIS催化剂
公开(公告)号：WO2011069134A3
公开(公告)日：2011-11-17
申请号：PCT/US2010058997
申请日：2010-12-03
申请人： MATERIA INC , ALLEN DARYL , GIARDELLO MICHAEL
发明人： ALLEN DARYL , GIARDELLO MICHAEL
IPC分类号： B01J31/22 , C07C6/04 , C07F15/00 , C08F4/80
CPC分类号： B01J31/2278 , B01J31/1633 , B01J31/1641 , B01J31/2208 , B01J31/2273 , B01J31/2295 , B01J2231/543 , B01J2531/821 , C07B2200/11 , C07C6/04 , C07C67/333 , C07C67/475 , C07C2531/22 , C07C2601/10 , C07F15/0046 , C08G61/08 , C08G2261/418 , C08G2261/419 , Y02P20/52 , C07C11/02 , C07C69/74 , C07C69/593 , C07C69/18
摘要： Supported olefin metathesis catalysts are disclosed, and more particularly, a supported catalyst complex comprising a catalyst composed of a Group 8 transition metal complex comprising a labile ligand and a non-labile ligand and a support, wherein the metal complex and the support are linked together by one or more linkers, in which one of the linkers connects the labile ligand of the complex to the support and the same or a different linker connects the non-labile ligand of the complex to the support. A method for preparing a supported catalyst complex is further disclosed, comprising contacting at least one non-labile ligand precursor and at least one labile ligand precursor with at least one Group 8 transition metal complex having multiple coordinated ligands, in which the non-labile ligand and the labile ligand precursors are exchanged via ligand exchange reactions with the coordinated ligands of the metal complex. Both the non-labile and the labile ligands comprise linkers for attachment to a support. The metal complex is further contacted with a support in order to link the metal complex to the support via the linkers connected to the labile and the non-labile ligands. The invention further relates to the use of the supported olefin metathesis catalyst in performing metathesis reactions. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.
摘要翻译：公开了负载型烯烃复分解催化剂，更具体地说，包括由包含不稳定配体和非不稳定配体的第8族过渡金属络合物和支持体组成的催化剂载体，其中金属络合物和载体连接在一起一个或多个接头，其中一个接头将复合物的不稳定配体连接到载体上，并且相同或不同的接头将复合物的非不稳定配体连接到载体上。进一步公开了一种制备负载型催化剂配合物的方法，包括使至少一种非不稳定的配体前体与至少一种不稳定的配体前体与至少一个具有多个配位配体的第8族过渡金属络合物接触，其中非不稳定配体并且通过与金属络合物的配位配体的配体交换反应来交换不稳定配体前体。非不稳定性和不稳定性配体都包括用于附着到载体的接头。金属络合物进一步与载体接触，以便通过与不稳定配体和非不稳定配体连接的连接体将金属络合物与载体连接。本发明还涉及负载的烯烃复分解催化剂在进行复分解反应中的用途。本发明在催化，有机合成，聚合物化学，工业和精细化学品化学领域具有实用价值。

9. 发明申请

WO2011059803A3 RUTHENIUM-ALKYLIDENES CONTAINING ACYCLIC DIAMINOCARBENES FOR OBTAINING LOW E/Z RATIOS IN CROSS METATHESIS 审中-公开
标题翻译：含有交联二氨基甲酸酯的亚硝酸钠用于获得交叉分子中的低E / Z比例
公开(公告)号：WO2011059803A3
公开(公告)日：2011-11-17
申请号：PCT/US2010054661
申请日：2010-10-29
申请人： UNIV TEXAS , BIELAWSKI CHRISTOPHER W , ROSEN EVELYN
发明人： BIELAWSKI CHRISTOPHER W , ROSEN EVELYN
IPC分类号： B01J31/22 , C07B37/00 , C07C6/06 , C07C11/02 , C07F15/00
CPC分类号： B01J31/2273 , B01J31/2208 , B01J31/2265 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C67/475 , C07C2531/22 , C07C2531/24 , C07C2601/10 , C07F15/0046 , C07C11/02 , C07C69/74 , C07C69/157
摘要： According to one embodiment, the disclosure provides a ruthenium (Ru)-based olefin metathesis reaction catalyst containing a core including a ruthenium-based alkylidene and at least one acyclic diaminocarbene (ADC) ligand covalently bound to the core. The disclosure also provides a method of catalyzing an olefin metathesis reaction by reacting a first olefin and a second olefin in the presence of a ruthenium (Ru)-based olefin metathesis reaction catalyst comprising a core comprising a ruthenium-based alkylidene and at least one acyclic diaminocarbene (ADC) ligand covalently bound to the core to synthesize a third olefin mixture. Finally, the disclosure further provides methods of preparing ruthenium (Ru)-based catalysts.
摘要翻译：根据一个实施方案，本公开内容提供了一种含有钌（Ru）的烯烃复分解反应催化剂，其含有包含钌基亚烷基和至少一个与核共价结合的非环状二氨基碳（ADC）配体的核。本公开还提供了在基于钌（Ru）的烯烃复分解反应催化剂的存在下使第一烯烃和第二烯烃反应的催化烯烃复分解反应的方法，所述催化剂包含包含钌基亚烷基和至少一个无环的共价结合核心的二氨基卡宾（ADC）配体合成第三种烯烃混合物。最后，本发明还提供制备钌（Ru）基催化剂的方法。

10. 发明申请

WO2011110691A3 LEWIS ACID SOLUTIONS IN AN OXYGEN DONOR-CONTAINING SOLVENT OR SOLVENT MIXTURE 审中-公开
标题翻译： Lewis酸溶液中的SAUERSTOFFDONORHALTIGEN溶剂或溶剂混合物
公开(公告)号：WO2011110691A3
公开(公告)日：2011-11-10
申请号：PCT/EP2011053788
申请日：2011-03-14
申请人： CHEMETALL GMBH , WIETELMANN ULRICH , MURSO ALEXANDER , LANG SEBASTIAN
发明人： WIETELMANN ULRICH , MURSO ALEXANDER , LANG SEBASTIAN
IPC分类号： B01J31/22 , B01J31/02 , B01J31/26 , B01J31/30 , C01B35/06 , C01G9/04 , C01G49/10 , C07F19/00
CPC分类号： C09K3/00 , B01J31/0204 , B01J31/2208 , B01J31/26 , B01J31/30 , B01J2231/326 , B01J2231/342 , B01J2231/4205 , B01J2531/26 , B01J2531/30 , B01J2531/842 , B01J2531/90 , C01B35/06 , C01G9/04 , C01G49/10
摘要： The invention relates to solutions of Lewis acids selected from the halogen-containing Lewis acids of the elements of groups 8, 12 and 13 from the periodic table of elements, or mixtures of said Lewis acids, in aprotic, asymmetrically substituted ethers of formula (I) or in solvent mixtures that contain asymmetrically substituted ethers and hydrocarbons, and to the production of the solutions according to the invention. Said solutions can be used in the inorganic, organic and organometallic synthesis, where R1 ? R2 and R1, R2 independently of one another are selected from H, or from a functionalized or a non-functionalized branched or unbranched alkyl-, alkyloxy, cycloalkyl, cycloalkyloxy group having 1 to 20 C atoms or an aryl- or an aryloxy group having 1-12 C atoms, wherein in the event that R1 = H, R2 ? H.
摘要翻译：本发明涉及从第8，第12和第13组的在质子惰性的，不对称取代的式（I）的醚，这些路易斯酸的元素或其混合物的周期表中的元素的含卤素的路易斯酸中选择的路易斯酸溶液或在含有这种不对称取代的醚和烃以及生产本发明的解决方案的溶剂混合物。这些可以在无机，有机和有机金属合成中使用。其中：R1？ R2和R1，R2 =独立地H，或官能化或未官能化的支链或无支链烷基，烷氧基，环烷基，环烷氧基具有1至20个C原子或芳基或具有1-12个C原子的芳氧基中使用， ħR2为的情况是R1 = H.

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