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1. 发明申请

WO2004024322A3 A CATALYST SYSTEM COMPRISING A 1,2-BIS-(PHOSPHINOALKYL) FERROCENE LIGAND 审中-公开
标题翻译：包含1,2-双（磷酰基烷基）二茂铁配体的催化剂体系
公开(公告)号：WO2004024322A3
公开(公告)日：2004-05-06
申请号：PCT/GB0303936
申请日：2003-09-10
申请人： LUCITE INT UK LTD , EASTHAM GRAHAM
发明人： EASTHAM GRAHAM
IPC分类号： B01J31/24 , B01J35/00 , C07C67/03 , C07C67/38
CPC分类号： B01J31/1895 , B01J31/2295 , B01J31/24 , B01J31/2414 , B01J31/2433 , B01J31/2457 , B01J31/2485 , B01J35/0013 , B01J2231/321 , B01J2531/0205 , B01J2531/0258 , B01J2531/60 , B01J2531/80 , B01J2531/824 , B01J2531/842 , C07C67/30 , C07C67/38 , C07C2603/74 , C07C69/68 , C07C69/675 , C07C69/67
摘要： A catalyst suitable for carbonylating ethylenically unsaturated compounds comprising a Group VIIIB metal or compound thereof and a metallocene.
摘要翻译：适用于羰基化包含VIIIB族金属或其化合物和金属茂的烯属不饱和化合物的催化剂。

2. 发明申请

WO2002085516A1 錯体触媒、該錯体触媒の製造方法及び該錯体触媒を用いるアルコール誘導体の製造方法审中-公开
标题翻译：复合催化剂，生产复合催化剂的方法和用复合催化剂生产醇的方法
公开(公告)号：WO2002085516A1
公开(公告)日：2002-10-31
申请号：PCT/JP2002/003791
申请日：2002-04-17
申请人：住友化学工業株式会社 , 佐々木和明
发明人：佐々木和明
IPC分类号： B01J31/22
CPC分类号： B01J31/2243 , B01J2231/48 , B01J2531/0252 , B01J2531/60 , B01J2531/72 , B01J2531/845 , C07D213/64
摘要： An (asymmetric) complex catalyst comprising a Lewis acid and a metal complex represented by the formula (1): (wherein R , R , R , R , R , R , R , and R are the same or different and each represents hydrogen, halogeno, alkyl, etc.; one of R and R represents hydrogen and the other represents C1-4 alkyl, etc.; Q represents a single bond, C1-4 alkylene, etc.; M represents a metal ion; and A represents a counter ion or ligand for balancing); a process for producing an (optically active) alcohol derivative, characterized by reacting a cyclic ether compound with a phenol derivative in the presence of the complex catalyst; and a process for producing an (optically active) nitrogenous heterocyclic compound which comprises reacting the alcohol derivative with a halogenated nitrogenous heterocyclic compound in the presence of a base.
摘要翻译：包含路易斯酸和由式（1）表示的金属络合物的（不对称）复合催化剂：其中R 1，R 2，R 3，R 4，R 5，R 5， R 7和R 8相同或不同，各自表示氢，卤代，烷基等; R 9和R 10之一表示氢，另一个表示C1- 4烷基等; Q表示单键，C 1-4亚烷基等; M表示金属离子; A表示用于平衡的抗衡离子或配体）; 一种（光学活性）醇衍生物的制备方法，其特征在于在络合催化剂存在下使环醚化合物与苯酚衍生物反应; 以及制备（光学活性）含氮杂环化合物的方法，其包括在碱的存在下使醇衍生物与卤代含氮杂环化合物反应。

3. 发明申请

WO1991009674A1 CATALYST FOR HYDROGENATION, DEHYDROSILYLATION OR HYDROSILYLATION, AND ITS USE 审中-公开
标题翻译：氢化，脱氢或氢化催化剂及其用途
公开(公告)号：WO1991009674A1
公开(公告)日：1991-07-11
申请号：PCT/JP1990001708
申请日：1990-12-26
申请人： SAGAMI CHEMICAL RESEARCH CENTER , FUCHIKAMI, Takamasa , UBUKATA, Yumiko , TANAKA, Yasutaka
发明人： SAGAMI CHEMICAL RESEARCH CENTER
IPC分类号： B01J31/20
CPC分类号： B01J31/20 , B01J2231/323 , B01J2231/643 , B01J2231/645 , B01J2531/60 , C07C5/03 , C07C5/05 , C07C5/08 , C07C5/09 , C07C29/145 , C07C29/172 , C07C45/62 , C07C51/36 , C07C67/31 , C07C209/48 , C07C209/52 , C07C231/12 , C07C2531/20 , C07F7/0801 , C07F7/0829 , C07F7/0896 , C07F7/1804 , C07F7/188 , C07C35/14 , C07C33/20
摘要： Catalyst used in hydrogenation, dehydrosilylation of ketones, and hydrosilylation of dienes or acetylenes, comprises complex of formula: A+(M2H(CO)10), A is alkali metal, ammonium, iminium or phosphonium cation, and M is chromium, molybdenum or tungsten atom; and processes for producing dehydrosilylated ketones and hydrosilylated dienes or acetylenes in presence of catalyst. @(51pp Dwg.No.0/0).

4. 发明申请

WO2004014552A1 A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM 审中-公开
标题翻译： PHOSPHA-ADAMANTANE（S）催化体系
公开(公告)号：WO2004014552A1
公开(公告)日：2004-02-19
申请号：PCT/GB2003/003419
申请日：2003-08-06
申请人： LUCITE INTERNATIONAL UK LIMITED , EASTHAM, Graham, Ronald , CAMERON, Paul, Andrew , TOOZE, Robert, Paul , CAVELL, Kingsley, John , EDWARDS, Peter, Gerald , COLEMAN, Dennis, Lee
发明人： EASTHAM, Graham, Ronald , CAMERON, Paul, Andrew , TOOZE, Robert, Paul , CAVELL, Kingsley, John , EDWARDS, Peter, Gerald , COLEMAN, Dennis, Lee
IPC分类号： B01J31/24
CPC分类号： B01J31/1895 , B01J31/2457 , B01J35/0013 , B01J2231/321 , B01J2531/0258 , B01J2531/60 , B01J2531/80 , B01J2531/824 , C07C67/38 , C07C2603/74 , C07F9/5018 , C07F9/5027 , C07F9/5045 , C07F9/52 , C07C69/24 , C07C69/67
摘要： A catalyst system capable of catalysing the carbonylation of an olefinally unsaturated compound is described. The 5 catalyst system is obtainable by combining: (a) a metal of Group VIB or Group VIII B or a compound thereof; and (b) a bidentate phosphine of general formula (I) Ad) s (CR 4 R 5 R 6 ) T Q 2 -A- (K, D) Ar (E, Z) -B-Q 1 (Ad) u (CR 1 R 2 R 3 ) v . Ad represents an optionally substituted adamantyl radical bonded to the phosphorous atom via any one of its tertiary carbon atoms. A method of production of the catalyst is also illustrated.
摘要翻译：描述了能够催化烯属不饱和化合物羰基化的催化剂体系。 5催化剂体系可通过以下方法获得：（a）VIB族或VIIIB族金属或其化合物; 和（b）通式（I）的二齿膦Ad）s（CR 4 R 5 R 6）TQ 2 -A-（K，D）Ar（E，Z）-BQ （Ad）u（CR 1 R 2 R 3）v。Ad表示任意取代的金刚烷基，其通过其叔碳原子中的任何一个与磷原子键合。还示出了催化剂的生产方法。

5. 发明申请

WO01074745A1 SUBSTITUTED POLYCYCLIC CYCLOPENTADIENES AND METHOD FOR THEIR PREPARATION 审中-公开
标题翻译：取代的多环环己烷二酮及其制备方法
公开(公告)号：WO01074745A1
公开(公告)日：2001-10-11
申请号：PCT/EP2001/003127
申请日：2001-03-20
IPC分类号： B01J31/22 , C07C13/54 , C07C13/547 , C07F7/00 , C07F7/28 , C07F17/00 , C08F4/42 , C08F4/44 , C08F4/62 , C08F4/6392 , C08F4/659 , C08F10/00 , C08F210/16 , C08F210/18
CPC分类号： B01J31/143 , B01J31/122 , B01J31/14 , B01J31/2295 , B01J2231/12 , B01J2231/645 , B01J2531/10 , B01J2531/11 , B01J2531/12 , B01J2531/20 , B01J2531/22 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , C07C13/54 , C07C13/547 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F210/16 , C08F210/18 , Y10S526/943 , C08F4/6592 , C08F4/65925 , C08F210/06 , C08F2500/03 , C08F2500/25 , C08F236/20
摘要： New polycyclic cyclopentadiene compounds having the formula (II) wherein the various substituents and symbols R1, R2, R3, R4, R5, R6, R7, Z and Z and "n" have the meaning specified in the description. These compounds can form metallocene complexes with transition metals, which have shown unusual properties in the (co)polymerization of ethylene and alpha-olefins in general.
摘要翻译：具有式（II）的新的多环戊二烯化合物，其中各种取代基和符号R 1，R 2，R 3，R 4，R 5，R 6，R 7，Z 1和Z 2和“n”具有在说明书中指定的含义。这些化合物可以与过渡金属形成茂金属络合物，这在一般的乙烯和α-烯烃的（共）聚合中显示出不寻常的性质。

6. 发明申请

WO00008036A1 mu -OXOBISMETALLOCENE COMPLEXES, CATALYST FOR OLEFIN POLYMERIZATION CONTAINING THE SAME, AND POLYMERIZATION METHOD 审中-公开
标题翻译： mu-多异氰酸酯复合物，含烯烃聚合的催化剂和聚合方法
公开(公告)号：WO00008036A1
公开(公告)日：2000-02-17
申请号：PCT/JP1999/004147
申请日：1999-08-02
IPC分类号： B01J31/22 , C07F17/00 , C08F4/642 , C08F4/643 , C08F4/659 , C08F10/00 , C08F110/06 , C08F4/64
CPC分类号： B01J31/143 , B01J31/1608 , B01J31/2286 , B01J31/2295 , B01J2531/30 , B01J2531/40 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F2500/17
摘要： Novel mu -oxobismetallocene complexes which have good crystallizability and can be easily separated; a catalyst for olefin polymerization which comprises as essential ingredients at least one of the mu -oxobismetallocene complexes and at least one promoter selected among an aluminoxane, ionic compound, and Lewis acid; and a method of polymerizing an olefin using the catalyst. An example of the mu -oxobismetallocene complexes is a compound represented by formula (1), wherein M is a transition metal belonging to any of the Groups 3, 4, 5, and 6 of the Periodic Table and the lanthanide and actinide elements; n is an integer of 1 or 2; Y is carbon, silicon, germanium, or tin; each X is halogeno, a pseudohalogen group, a hydrocarbon group, etc.; and R1 to R10 each is any of various substituents.
摘要翻译：具有良好结晶性和易于分离的新型多氧基双茂金属络合物; 一种用于烯烃聚合的催化剂，其包含作为必需成分的至少一种三氧化双茂金属络合物和至少一种选自铝氧烷，离子化合物和路易斯酸的助催化剂; 以及使用该催化剂聚合烯烃的方法。该茂氧基硫杂茂合物的一个实例是由式（1）表示的化合物，其中M是属于周期表第3,4,5和6族中的任何一种的过渡金属和镧系元素和锕系元素; n为1或2的整数; Y是碳，硅，锗或锡; 各X为卤素，假卤素基，烃基等; R 1〜R 10各自为各种取代基。

7. 发明申请

WO1995017962A1 CATALYST FOR CONVERSION OF METHANE TO ETHYLENE, PREPARATION THEREOF, AND PROCESS FOR MANUFACTURING ETHYLENE USING SAID CATALYST 审中-公开
标题翻译：用于将甲苯转化成乙烯的催化剂，其制备方法以及使用合适的催化剂制备乙烯的方法
公开(公告)号：WO1995017962A1
公开(公告)日：1995-07-06
申请号：PCT/KR1994000186
申请日：1994-12-30
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , PARK, Dae, Chul , AHN, Pyung, Kwon
发明人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
IPC分类号： B01J31/16
CPC分类号： B01J31/0267 , B01J21/04 , B01J31/0259 , B01J31/04 , B01J31/1616 , B01J31/20 , B01J31/2404 , B01J31/28 , B01J31/30 , B01J37/0203 , B01J2531/0211 , B01J2531/60 , B01J2531/70 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , C07C2/76 , C07C2527/128 , C07C2531/20 , C07C2531/24 , Y02P20/52 , Y10S585/943 , C07C11/04
摘要： The present invention relates to a new catalyst for converting methane into ethylene preparation thereof, and process for manufacturing ethylene using said catalyst. The conversion reaction catalyst in the present invention is employed in converting directly methane or methane-containing gas in the presence of the above catalyst with the general formula (1): Ma.Pc.D/S.........., where M is a metal cluster or metal complex compound selected from the group of VIII, VII and VI series; S is an inorganic carrier; P is a promoter of phosphorus compound; D is a cobalt compound, and "a" is weight percentage of metal cluster or metal complex compound in catalyst, having a value of 0,01 to 10, "c" is weight percentage of promoter in catalyst, ranging from 1,0 to 35,0.
摘要翻译：本发明涉及用于将甲烷转化为乙烯制备的新型催化剂，以及使用所述催化剂制备乙烯的方法。本发明中的转化反应催化剂用于在上述催化剂存在下直接甲烷或含甲烷的气体转化为通式（1）：Ma.Pc.D / S ......... 其中M是选自VIII，VII和VI系列的金属簇或金属络合物; S是无机载体; P是磷化合物的促进剂; D是钴化合物，“a”是金属簇或金属络合物在催化剂中的重量百分数，其值为0.01至10，“c”是催化剂中助催化剂的重量百分比，范围为1.0至 35,0。

8. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

9. 发明申请

WO2004037838A1 PREPARATION OF PARTIALLY HYDROGENATED RAC-ANSA-METALLOCENE COMPLEXES 审中-公开
标题翻译：部分加氢仲胺 - 金属茂复合物的制备
公开(公告)号：WO2004037838A1
公开(公告)日：2004-05-06
申请号：PCT/EP2003/011679
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , DUCHIRON, Stéphanie , LELONG, Jean-François
发明人： DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , DUCHIRON, Stéphanie , LELONG, Jean-François
IPC分类号： C07F17/00
CPC分类号： B01J31/2234 , B01J31/2295 , B01J2531/30 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/58 , B01J2531/60 , C07B53/00 , C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing hydrogenated or partially hydrogenated, racemic ansa-metallocene complexes by reacting bridged or unbridged transition metal complexes with alkali metal compounds or alkaline earth metal compounds, heating the resulting reaction mixture to a temperature in the range from -78 to 250°C and at least partially hydrogenating the reaction products in the presence of a suitable catalyst, to the corresponding hydrogenated or partially hydrogenated metallocenes and to their use as catalysts or as a constituent of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及通过使桥联或未桥连的过渡金属配合物与碱金属化合物或碱土金属化合物反应制备氢化或部分氢化的外消旋的仲茂金属络合物的方法，将得到的反应混合物加热至-78℃ 至250℃，并在合适的催化剂存在下将反应产物至少部分氢化至相应的氢化或部分氢化的金属茂，并将其用作催化剂或用作烯属不饱和化合物或试剂的聚合催化剂的用途或立体选择性合成中的催化剂。

10. 发明申请

WO2003045551A1 ORGANOMETALLIC TRANSITION METAL COMPOUND, BISCYCLOPENTADIENYL LIGAND SYSTEM, CATALYST SYSTEM AND PREPARATION OF POLYOLEFINS 审中-公开
标题翻译：有机金属过渡金属化合物，双叉聚苯乙烯配位体系，催化剂体系和聚烯烃的制备
公开(公告)号：WO2003045551A1
公开(公告)日：2003-06-05
申请号：PCT/EP2002/013296
申请日：2002-11-26
申请人： BASELL POLYOLEFINE GMBH , OKUMURA, Yoshikuni , OBERHOFF, Markus , SCHOTTEK, Jörg , SCHULTE, Jörg
发明人： OKUMURA, Yoshikuni , OBERHOFF, Markus , SCHOTTEK, Jörg , SCHULTE, Jörg
IPC分类号： B01J31/16
CPC分类号： B01J31/143 , B01J31/2295 , B01J2531/30 , B01J2531/40 , B01J2531/48 , B01J2531/50 , B01J2531/60 , C07F7/0818 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/06 , C08F210/00 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/03 , C08F210/16
摘要： Organometallic transition metal compounds of the formula (I) where M 1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides; X are identical or different and are each halogen, hydrogen,C 1 -C 20 -alkyl, C 2 -C 20 -alkenyl, C 6 -C 22 -aryl, alkylaryl or arylalkyl having from 1 to 10 carbon atoms in the alkyl part and from 6 to 22 carbon atoms inthe aryl part, -OR 5 or -NR 5 R 6 , where two radicals X may also be joined to one another or two radicals X may together form a substituted or unsubstituted diene ligand, in particular a 1,3-diene ligand; where R 5 and R 6 are each C 1 -C 10 -alkyl, C 6 -C 15 -aryl, alkylaryl, arylalkyl, fluoroalkyl or fluoroaryl each having from 1 to 10 carbon atoms in the alkyl radical and from 6 to 22 carbon atoms in the aryl radical; n is a natural number from 1 to 4 which is equal to the oxidation number of M 1 minus 2; R 1 is a C 2 -C 40 radical which is branched in the α position; R 2 is hydrogen or a C 1 -C 40 radical which may be branched or unbranched in the α position; R 3 , R 3a and R 3b are identical or different and are each hydrogen or a C 1 -C 40 radical, where at least one of the radicals R 3 , R 3a , R 3b is not hydrogen; R 4 is a substituted or unsubstituted C 6 -C 40 -aryl radical or C 2 -C 40 -heteroaromatic radical containing at least one heteroatom selected from the group consisting of O, N, S and P; T is a divalent C 1 -C 40 group which together with the cyclopen tadienyl ring forms a further saturated or unsaturated ring system having a ring size of from 5 to 12 atoms, where T may contain the heteroatoms Si, Ge, N, P, O or S withing the ring system fused onto the cyclopentadienyl ring; and Z is a bridge consisting of a divalent atom or a divalent group, can be used in catalyst systems for preparing polyolefins by polymerization or copolymerization of at least one olefin. Biscyclopentadienyl ligand systems which have such a substitution pattern and can be used for preparing these organometallic transition metal compounds are also provided.
摘要翻译：式（I）的有机金属过渡金属化合物，其中M 1是元素周期表第3,4,5或6族的元素或镧系元素; X是相同或不同的，分别是烷基部分中具有1-10个碳原子的卤素，氢，C 1 -C 20烷基，C 2 -C 20 - 烯基，C 6 -C 22 - 芳基，烷基芳基或芳烷基和6至22碳芳基部分中的原子，-OR 5或-NR 5 R 6，其中两个基团X也可以彼此连接，或两个基团X可以一起形成取代或未取代的二烯配体，特别是 1,3-二烯配体; 其中R 5和R 6各自为C 1 -C 10 - 烷基，C 6 -C 15 - 芳基，烷基芳基，芳基烷基，氟代烷基或氟代芳基，其各自在烷基和碳原子数为6至22的碳原子上具有1至10个碳原子在芳基中; n是1至4的自然数，等于M 1的氧化数减去2; R 1是在α位上分支的C 2 -C 40基团; R 2是氢或在α位上可以是支链或非支链的C1-C40基团; R 3，R 3a和R 3b相同或不同，各自为氢或C 1 -C 40基团，其中R 3，R 3a，R 3b，不是氢; R 4是含有至少一个选自O，N，S和P的杂原子的取代或未取代的C 6 -C 40 - 芳基或C 2 -C 40杂芳族基团; T是二价C1-C40基团，其与环戊二烯基环一起形成具有5至12个原子的环尺寸的另外的饱和或不饱和环体系，其中T可以含有杂原子Si，Ge，N，P，O或将环系统融合到环戊二烯基环上; Z是由二价原子或二价基团构成的桥，可用于通过至少一种烯烃的聚合或共聚合制备聚烯烃的催化剂体系。还提供了具有这种取代模式并可用于制备这些有机金属过渡金属化合物的双环戊二烯基配体体系。

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