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    • 7. 发明申请
    • PASSIVATION LAYER FORMATION BY PLASMA CLEAN PROCESS TO REDUCE NATIVE OXIDE GROWTH
    • 通过等离子清洁工艺形成钝化层以减少氧化物的生长
    • WO2009085958A2
    • 2009-07-09
    • PCT/US2008/087436
    • 2008-12-18
    • APPLIED MATERIALS, INC.YANG, HaichunLU, Xin LiangKAO, Chien-TehCHANG, Mei
    • YANG, HaichunLU, Xin LiangKAO, Chien-TehCHANG, Mei
    • H01L21/302H01L21/30
    • H01L21/02068H01L21/31116H01L21/76224H01L29/665H01L29/6656H01L29/78
    • Embodiments described herein provide methods for removing native oxide surfaces on substrates while simultaneously passivating the underlying substrate surface. In one embodiment, a method is provided which includes positioning a substrate containing an oxide layer within a processing chamber, adjusting a first temperature of the substrate to about 80°C or less, generating a cleaning plasma from a gas mixture within the processing chamber, such that the gas mixture contains ammonia and nitrogen trifluoride having an NH3/NF3 molar ratio of about 10 or greater, and condensing the cleaning plasma onto the substrate. A thin film, containing ammonium hexafluorosilicate, is formed in part, from the native oxide during a plasma clean process. The method further includes heating the substrate to a second temperature of about 100°C or greater within the processing chamber while removing the thin film from the substrate and forming a passivation surface thereon.
    • 这里描述的实施例提供了用于去除衬底上的自然氧化物表面同时钝化下面的衬底表面的方法。 在一个实施例中,提供了一种方法,其包括:将包含氧化物层的衬底定位在处理室内;将衬底的第一温度调节到大约80℃或更低;从处理室内的气体混合物产生清洁等离子体; 使得气体混合物含有具有约10或更大的NH 3 / NF 3摩尔比的氨和三氟化氮,并且将清洁等离子体冷凝到基板上。 含有六氟硅酸铵的薄膜部分由等离子体清洁过程中的自然氧化物形成。 该方法进一步包括在处理室内将基板加热至约100℃或更高的第二温度,同时从基板移除薄膜并在其上形成钝化表面。