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1. 发明授权

US4399211A Photopolymerizable compositions 失效
标题翻译：光聚合组合物
公开(公告)号：US4399211A
公开(公告)日：1983-08-16
申请号：US203756
申请日：1980-11-03
申请人： Syunichi Kondo , Akihiro Matsufuji , Akira Umehara , Toshinao Ukai , Akira Sato
发明人： Syunichi Kondo , Akihiro Matsufuji , Akira Umehara , Toshinao Ukai , Akira Sato
IPC分类号： C08F2/00 , C08F2/50 , C08F2/54 , G03F7/031 , G03C1/68
CPC分类号： G03F7/031 , C08F2/50 , Y10S430/108 , Y10S430/116 , Y10S430/117 , Y10S430/121 , Y10S430/146
摘要： In a photopolymerizable composition comprising, as essential components, (A) a compound having at least one ethylenically unsaturated double bond capable of undergoing addition polymerization and (B) a photopolymerization initiator, the improvement which comprises that the photopolymerization initiator comprising a combination of (a) a 5-[(arenooxazol-2-ylidene)ethylidene]-2-thiohydantoin compound represented by the general formula (I) (a 5-[(substituted benzoxazol-2'-ylidene)ethylidene]-2-thiohydantoin compound) or (II) (a 5-[substituted naphthol(1,2-D)oxazol-2-ylidene)ethylidene]-2-thiohydantoin compound) and (b) a 2,4,6-substituted-1,3,5-triazine compound represented by the formula (III): ##STR1## wherein X represents a hydrogen atom, an alkyl group, a substituted alkyl group, an alkoxy group, an aryl group, a substituted aryl group, an aryloxy group, an aralkyl group or a halogen atom; R.sup.1, R.sup.2 and R.sup.3 each represents an alkyl group, a substituted alkyl group, an alkenyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different; and R.sup.4, R.sup.5 and R.sup.6 each represents an alkyl group, a substituted alkyl group, an aryl group, a substituted aryl group or an aralkyl group, which may be the same or different but at least one of which represents a mono-, di- or trihalogenomethyl group.
摘要翻译：在包含作为必要成分的（A）具有至少一个可进行加成聚合的烯属不饱和双键的化合物和（B）光聚合引发剂）的光聚合组合物中，包括光聚合引发剂包括（a ）由通式（I）表示的5 - [（异恶唑-2-亚基）亚乙基] -2-硫代乙内酰脲化合物（5 - [（取代的苯并恶唑-2'-亚基）亚乙基] -2-硫代乙内酰脲化合物）或（II）（5- [取代萘酚（1,2-D）恶唑-2-亚基）亚乙基] -2-硫代乙内酰脲化合物）和（b）2,4,6-取代的1,3,5- （III）表示的三嗪化合物：其中X表示氢原子，烷基，取代的烷基，烷氧基，芳基基团，取代的芳基，芳氧基，芳烷基或卤素原子; R1，R2和R3各自表示可以相同或不同的烷基，取代的烷基，烯基，芳基，取代的芳基或芳烷基; 并且R 4，R 5和R 6各自表示烷基，取代的烷基，芳基，取代的芳基或芳烷基，其可以相同或不同，但其中至少一个表示单 - ，二 - 或三卤代甲基。

2. 发明授权

US5385807A Photopolymerizable composition 失效
标题翻译：可光聚合组合物
公开(公告)号：US5385807A
公开(公告)日：1995-01-31
申请号：US901773
申请日：1992-06-22
申请人： Yasuo Okamoto , Syunichi Kondo , Toshinao Ukai
发明人： Yasuo Okamoto , Syunichi Kondo , Toshinao Ukai
IPC分类号： G03F7/00 , C08F2/50 , G03F7/004 , G03F7/027 , G03F7/028 , G03F7/029 , G03F7/031 , H01L21/027 , G03C1/72
CPC分类号： G03F7/0295 , G03F7/031 , Y10S430/121
摘要： A photopolymerizable composition comprises: (i) a polymerizable compound carrying an addition-polymerizable unsaturated bond; (ii) a methine compound; (iii) at least one compound selected from the group consisting of: (a) compounds having carbon-halogen bonds, (b) aromatic onium salts, (c) organic peroxides, (d) thio compounds, (e) hexaaryl-biimidazoles, (f) ketooxime esters, and (g) compounds represented by the following general formula (III): ##STR1## wherein R.sup.6, R.sup.7, R.sup.8 and R.sup.9 may be the same or different and each represents a substituted or unsubstituted alkyl, aryl, alkenyl, alkynyl or heterocyclic group, provided that at least two of R.sup.6, R.sup.7, R.sup.8 and R.sup.9 may be bonded together to form a ring structure and that at least one of them represents an alkyl group; and Z.sup.+ represents an alkali metal cation or a quaternary ammonium cation. The composition has a high sensitivity to a wide range of actinic light rays extending from ultraviolet to visible light.
摘要翻译：光聚合性组合物包含：（i）带有可加聚的不饱和键的聚合性化合物; （ii）次甲基化合物; （iii）至少一种选自以下的化合物：（a）具有碳 - 卤键的化合物，（b）芳族鎓盐，（c）有机过氧化物，（d）硫代化合物，（e）六芳基 - （f）酮肟酯，和（g）由以下通式（III）表示的化合物：相同或不同，各自表示取代或未取代的烷基，芳基，烯基，炔基或杂环基，条件是R 6中的至少两个，R 7，R 8和R 9可以结合在一起形成环结构，并且它们中的至少一个表示烷基; Z +表示碱金属阳离子或季铵阳离子。该组合物对从紫外线到可见光延伸的宽范围的光化光线具有高灵敏度。

3. 发明授权

US4820625A Direct positive silver halide photographic material 失效
标题翻译：直接正卤化银照相材料
公开(公告)号：US4820625A
公开(公告)日：1989-04-11
申请号：US98660
申请日：1987-09-21
申请人： Naomi Saeki , Nobuaki Inoue , Toshinao Ukai , Yuji Mihara
发明人： Naomi Saeki , Nobuaki Inoue , Toshinao Ukai , Yuji Mihara
IPC分类号： G03C1/06 , G03C1/485
CPC分类号： G03C1/48523 , Y10S430/141
摘要： A direct positive silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer comprising a prefogged direct-positive silver halide emulsion, preferably one having a chloride content of at least 70 mol%, said emulsion layer or a hydrophilic colloid layer adjacent to said emulsion layer containing at least one compound represented by the following general formula (I) and, optionally, a specified organic desensitizer, ##STR1## wherein Z.sub.1 represents a group of nonmetallic atoms necessary to complete a nitrogen-containing hetero ring; T represents an alkyl group, a cycloalkyl group, an alkenyl group, a halogen atom, a cyano group, a trifluoromethyl group, an alkoxy group, an aryloxy group, a hydroxy group, an alkoxycarbonyl group, a carboxyl group, a carbamoyl group, a sulfamoyl group, an aryl group, an acylamino group, a sulfonamido group, a sulfo group, or a benzo-condensed ring, each of which is or is not substituted; q represents 1, 2, or 3; and r represents 0, 1 or 2.
摘要翻译：一种直接正性卤化银照相材料，其包括其上具有至少一个卤化银乳剂层的载体，所述卤化银乳剂层包含预成型的直接正性卤化银乳剂，优选氯化物含量为至少70mol％的卤化银乳剂层，所述乳剂层或亲水胶体层邻近所述乳剂层，其含有至少一种由以下通式（I）表示的化合物和任选的特定的有机脱敏剂，其中Z1表示完成含氮杂原子所必需的一组非金属原子环; T表示烷基，环烷基，烯基，卤素原子，氰基，三氟甲基，烷氧基，芳氧基，羟基，烷氧基羰基，羧基，氨基甲酰基，各自为或不被取代的氨磺酰基，芳基，酰氨基，亚磺酰氨基，磺基或苯并稠合环; q表示1,2或3; r表示0,1或2。

4. 发明授权

US4596767A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4596767A
公开(公告)日：1986-06-24
申请号：US599904
申请日：1984-04-13
申请人： Yuji Mihara , Toshinao Ukai , Shoji Ishiguro
发明人： Yuji Mihara , Toshinao Ukai , Shoji Ishiguro
IPC分类号： G03C1/28
CPC分类号： G03C1/28
摘要： A silver halide photographic light-sensitive material spectrally sensitized in an infrared region is described. The silver halide photographic light-sensitive material has at least one silver halide photographic emulsion layer containing at least one infrared-sensitizing dye represented by the following general Formula (I): ##STR1## wherein R.sub.1, R.sub.2, R, D, Z, Z.sub.1, X, and n are as described in the specification; and at least one compound represented by the following general Formula (II): ##STR2## wherein Z.sub.2, R.sub.6, R.sub.7 and X.sub.1 are described in the specification.The silver halide photographic light-sensitive material has improved sensitivity in an infrared spectral region and improved preservability.
摘要翻译：描述了在红外区域光谱敏化的卤化银照相感光材料。卤化银摄影感光材料具有至少一种含有至少一种由以下通式（I）表示的红外线增感染料的卤化银照相乳剂层：其中R1，R2，R，D，Z，Z1 ，X和n如说明书中所述; 和由以下通式（II）表示的至少一种化合物：其中Z2，R6，R7和X1在说明书中描述。卤化银照相感光材料在红外光谱区域具有改进的灵敏度和改进的保存性。

5. 发明授权

US5424442A Water-soluble methine compounds useful in photographic silver halide emulsion containing the same 失效
标题翻译：水溶性次甲基化合物可用于含有相同的照相卤化银乳剂
公开(公告)号：US5424442A
公开(公告)日：1995-06-13
申请号：US078110
申请日：1993-06-18
申请人： Keizo Koya , Toshinao Ukai , Haruo Takei
发明人： Keizo Koya , Toshinao Ukai , Haruo Takei
IPC分类号： G03C1/12 , C09B23/00 , C09B23/01 , C09B69/06 , G03C1/26 , G03C1/40 , C07D277/62
CPC分类号： C09B69/06 , C09B23/0075 , G03C1/26
摘要： A water-soluble methine compound represented by the following general formula (I): ##STR1## wherein Z.sub.1 and Z.sub.2, which may be the same or different, each represents a non-metallic atomic group required for forming a 5-membered or 6-membered nitrogen-containing heterocyclic ring; R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group; Q.sub.1 and Q.sub.2 each represents an atomic group required, in combination, for forming a 4-thiazolidinone ring, a 5-thiazolidinone ring, a 4-imidazolidinone ring, a 4-oxazolidinone ring, a 5-oxazolidinone ring, a 5-imidazolidinone ring or a 4-dithiolanone ring; L.sub.1, L.sub.2, L.sub.3, L.sub.4 and L.sub.5, which may be the same or different, each represents a methine group; R represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group; m represents 1 or 2; i and h each represents 0 or 1; l represents 1 or 2; and j and k each represents 0, 1, 2 or 3.A photographic silver halide emulsion containing said methine compound added in the form of an aqueous solution is also disclosed.
摘要翻译：由以下通式（I）表示的水溶性次甲基化合物：其中Z1和Z2可以相同或不同，分别表示形成一个或多个所需的非金属原子团 5元或6元含氮杂环; R 1和R 2可以相同或不同，各自表示烷基; Q1和Q2各自表示组合形成4-噻唑烷酮环，5-噻唑烷酮环，4-咪唑啉酮环，4-恶唑烷酮环，5-恶唑烷酮环，5-咪唑啉酮环所需的原子团或4-二硫戊环酮环; L1，L2，L3，L4和L5可以相同或不同，表示次甲基; R表示氢原子，烷基，芳基或杂环基; m表示1或2; i和h各自表示0或1; l表示1或2; 并且j和k各自表示0,1,2或3.还公开了含有以水溶液形式加入的次甲基化合物的照相卤化银乳剂。

6. 发明授权

US4030931A Heat developable light-sensitive material 失效
标题翻译：热可显影的感光材料
公开(公告)号：US4030931A
公开(公告)日：1977-06-21
申请号：US578833
申请日：1975-05-19
申请人： Yasuhiro Noguchi , Toshinao Ukai , Kenji Sashihara , Takao Masuda
发明人： Yasuhiro Noguchi , Toshinao Ukai , Kenji Sashihara , Takao Masuda
IPC分类号： G03C1/498 , G03C1/02
CPC分类号： G03C1/49845
摘要： A heat developable light-sensitive material comprising a support having thereon or therein at least (a) an organic silver salt, (b) a light-sensitive silver halide or a light-sensitive silver halide-forming component and (c) as a reducing agent at least one ester selected from the group consisting of (1) esters of carboxylic acids derived from phenol derivatives in which at least one of the o-positions thereof is substituted, preferably substituted with a bulky group, and mono- or poly-hydric alcohols, and (2) esters of alcohols derived from polyhydric phenols in which at least one of the o-positions thereof is substituted, preferably substituted with a bulky group, and mono- or polycarboxylic acids, to reduce the thermal fog produced at the background after heat development processing, and to increase the whiteness of the unexposed areas and the stability to normal room illumination.
摘要翻译：一种可热显影的感光材料，其包含至少（a）有机银盐，（b）感光卤化银或感光卤化银形成组分的载体，（c）作为还原剂至少一种酯选自（1）衍生自其中至少一个位置被取代的苯酚衍生物的羧酸酯，优选被大体积取代的单体或多元醇醇和（2）衍生自其中其至少一个位置被取代的多元酚的醇，优选被大体积取代的醇和单羧酸或多元羧酸的酯，以减少在背景下产生的热雾在显影处理之后，并且增加未曝光区域的白度和对正常室内照明的稳定性。

7. 发明授权

US5476945A Water-soluble methine derivatives of thiazole 失效
标题翻译：噻唑的水溶性次甲基衍生物
公开(公告)号：US5476945A
公开(公告)日：1995-12-19
申请号：US138061
申请日：1993-10-19
申请人： Akihiko Ikegawa , Toshinao Ukai , Masayuki Kawakami
发明人： Akihiko Ikegawa , Toshinao Ukai , Masayuki Kawakami
IPC分类号： C07D277/64 , C07D417/14 , C09B23/01 , C09B23/16 , G03C1/22 , C07D413/14
CPC分类号： C07D417/14 , C07D277/64 , C09B23/0083 , C09B23/164 , G03C1/22
摘要： A methine compound represented by the following formula (I): ##STR1## wherein Z.sub.1 and Z.sub.2 each represent a non-metallic atomic group necessitated for forming a five-membered or six-membered, nitrogen-containing heterocyclic ring, R.sub.1 and R.sub.2 each represent an alkyl group, X represents an inorganic anion, k represents a number necessitated for adjusting the electric charge of the molecule to zero, and n represents 0 or 1; with the proviso that when n is 1, the five-membered or six-membered, nitrogen-containing heterocyclic ring formed by Z.sub.2 is cationic, k is not zero and X represents chloride ion. The compound is useful as a spectral sensitizing dye and an antitumor agent.
摘要翻译：由下式（I）表示的次甲基化合物：其中Z1和Z2各自表示形成五元或六元含氮杂环所必需的非金属原子团，R1和 R2各自表示烷基，X表示无机阴离子，k表示将分子的电荷调整为零所需的数，n表示0或1; 条件是当n为1时，由Z2形成的五元或六元含氮杂环是阳离子的，k不为零，X表示氯离子。该化合物可用作光谱增感染料和抗肿瘤剂。

8. 发明授权

US4965170A Silver halide photographic material and method for forming super high contrast images therewith 失效
标题翻译：卤化银照相材料和用于形成超高对比度图像的方法
公开(公告)号：US4965170A
公开(公告)日：1990-10-23
申请号：US489872
申请日：1990-03-06
申请人： Toshinao Ukai , Kazuhiro Shirasu , Koki Nakamura , Keizo Koya , Masahiro Okada , Kazunobu Katoh
发明人： Toshinao Ukai , Kazuhiro Shirasu , Koki Nakamura , Keizo Koya , Masahiro Okada , Kazunobu Katoh
IPC分类号： G03C1/06 , G03C1/83 , G03C7/305
CPC分类号： G03C1/83 , G03C1/061 , G03C7/30547 , Y10S430/156 , Y10S430/159
摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer, said emulsion layer or at least one of other hydrophilic colloid layers containing a compound represented by formula (I):PWR--Time--.sub.T LA (I)wherein PWR represents a group which undergoes reduction to release (Time).sub.t LA; Time represents a group which release LA upon reaction following release of (Time).sub.t LA from PWR; t represents an integer of 0 or 1; and LA represents a group having a maximum light absorption in a wavelength range of 310 nm or more. In a preferred embodiment, one of said other hydrophilic colloid layers substantially free of the compound represented by formula (I) is provided between said at least one silver halide emulsion layer in said silver halide photographic material and one of said other hydrophilic colloid layers containing the compound represented by formula (I), and at least one of these hydrophilic colloid layers or at least one other of said other hydrophilic colloid layers contains a hydrazine derivative. A process for the formation of an ultrahigh contrast image, which comprises exposing the above-described silver halide photographic material to light, and then developing the silver halide photographic material with a developing solution having a pH of 11.0 to 12.3 and containing 0.15 mol/l or more of sulfite ions.

9. 发明授权

US4956263A Silver halide photographic material containing a compound capable of releasing a dye 失效
标题翻译：含有能够释放染料的化合物的卤化银照相材料
公开(公告)号：US4956263A
公开(公告)日：1990-09-11
申请号：US238796
申请日：1988-08-31
申请人： Kunio Ishigaki , Kazunobu Katoh , Nobuaki Inoue , Hisashi Okada , Toshinao Ukai , Morio Yagihara , Yoshihiro Takagi , Masakazu Yoneyama
发明人： Kunio Ishigaki , Kazunobu Katoh , Nobuaki Inoue , Hisashi Okada , Toshinao Ukai , Morio Yagihara , Yoshihiro Takagi , Masakazu Yoneyama
IPC分类号： G03C1/06 , G03C1/83
CPC分类号： G03C1/061 , G03C1/83 , Y10S430/156
摘要： A silver halide photographic material capable of providing very high contrast image and having improved safelight safety is described, which comprises a support having thereon at least one silver halide emulsion layer, and containing in the silver halide emulsion layer or another hydrophilic colloid layer (i) a compound represented by formula (I) ##STR1## wherein PWR represents a group capable of releasing ##STR2## upon being reduced; Time represents a group capable of releasing LA after being released from PWR, t is 0 or 1; and LA represents a group having an absorption maximum in the wavelength region longer than 310 nm, (ii) a hydrazine derivative, and (iii) at least one compound represented by formulae (IX) and (X) ##STR3## wherein R.sup.91, R.sup.92, R.sup.93, and R.sup.94, which may be the same or different, each represents hydrogen, an alkyl group, an aryl group, an amino group, a hydroxyl group, an alkoxy group, an alkylthio group, a carbamoyl group, a halogen atom, a cyano group, a carboxyl group, an alkoxycarbonyl group or a heterocyclic group and R.sup.91 and R.sup.92 or R.sup.92 and R.sup.93 may be linked to form a 5- or 6-membered ring; provided that at least one of R.sup.91 and R.sup.93 represents a hydroxyl group.

10. 发明授权

US4731793A Dye laser 失效
标题翻译：染色激光
公开(公告)号：US4731793A
公开(公告)日：1988-03-15
申请号：US883398
申请日：1986-07-08
申请人： Toshinao Ukai , Hisashi Okada
发明人： Toshinao Ukai , Hisashi Okada
IPC分类号： C09B23/02 , H01S3/094 , H01S3/213 , H01S3/20
CPC分类号： H01S3/094034 , C09B23/02 , H01S3/213
摘要： A dye laser is described, comprising a cell containing a laser dye solution and a pumping energy source connected to the cell, wherein the laser dye solution contains a compound represented by formula (I): ##STR1## wherein n represents 0 or 1; m represents 0, 1, 2 or 3; L.sup.1 and L.sup.2 which may be the same or different each represents a methine or substituted methine group; R.sup.1 is a substituted or unsubstituted alkyl group, an alkenyl group or an aralkyl group; R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 which may be the same or different each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkenyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an alkoxycarbonyl group, an acyloxy group, an acyl group, a hydroxy group, a cyano group, or a substituted or unsubstituted amino group; Z represents atoms necessary to form a 5- or 6-membered ring which may have a substituent or may be condensed to another ring, X.crclbar. represents an anion; and r represents 1 or 2, with the compound being an intramolecular salt when r is 1.
摘要翻译：描述了染料激光器，其包含含有激光染料溶液和连接到电池的泵浦能量源的电池，其中激光染料溶液含有由式（I）表示的化合物：其中n表示0或 1; m表示0,1,2或3; L1和L2可以相同或不同，表示次甲基或取代的次甲基; R1是取代或未取代的烷基，烯基或芳烷基; 可以相同或不同的R 2，R 3，R 4，R 5和R 6各自表示氢原子，卤素原子，取代或未取代的烷基，烯基，芳基，芳烷基，烷氧基，芳氧基，烷氧基羰基，酰氧基，酰基，羟基，氰基或取代或未取代的氨基; Z表示形成可以具有取代基或可以与另一个环稠合的5-或6-元环所必需的原子，X（ - ）表示阴离子; r表示1或2，当r为1时，该化合物为分子内盐。

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