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    • 4. 发明申请
    • Asymmetric cyanine dye
    • 不对称花青染料
    • US20050119490A1
    • 2005-06-02
    • US10491036
    • 2002-09-27
    • Masayuki Kawakami
    • Masayuki Kawakami
    • C09B23/01C09B23/08G03C1/12G03C1/14G03C1/20C07D43/02
    • C09B23/0066C09B23/086G03C1/127G03C1/14G03C1/20
    • A compound represented by the general formula (I) or a salt thereof [wherein R1, R2, R4, and R5 represent an alkyl group or an aryl group, and R1 and R2 and/or R4 and R5 may bind to each other to form a ring; R3 represents hydrogen atom or sulfo group; R6, R7, R8, and R9 represent hydrogen atom, a halogen atom, an alkyl group, an alkoxyl group, an amino group, nitro group or cyano group; X1 and X2 represent an alkyl group or an aryl group; m1 to m3 represents 0 or 1; L1 to L7 represent a methine group, and when two or more of methine groups among the aforementioned methine groups have a substituent, the substituents may bind to each other to form a ring; M represents hydrogen atom, a metal or a quaternary ammonium salt; and n represents an integer of 1 to 7 required to neutralize a charge]. The compound can be utilized as a novel cyanine dye useful as an infrared photosensitive dye that give no bad influence on photographic characteristics of a photographic emulsion and gives reduced residual color after development.
    • 由通式(I)表示的化合物或其盐[其中R 1,R 2,R 4,R 4和R 4 > 5表示烷基或芳基,R 1和R 2和/或R 4和R 4独立地表示烷基或芳基, SUP> 5 可以彼此结合形成环; R 3表示氢原子或磺基; R 6,R 7,R 8和R 9代表氢原子,卤素原子,烷基 烷氧基,氨基,硝基或氰基; X 1和X 2代表烷基或芳基; m 1至m 3表示0或1; L 1至L 7表示次甲基,并且当上述次甲基中的次甲基中的两个或更多个具有取代基时,取代基可以彼此结合形成 戒指; M表示氢原子,金属或季铵盐; n表示中和电荷所需的1〜7的整数]。 该化合物可以用作可用作红外光敏染料的新颖的花青染料,其对照相乳剂的照相特性没有不利影响,并且显影后残留颜色降低。
    • 6. 发明授权
    • Methine dyes, manufacturing methods thereof, and silver halide photographic materials containing same dyes
    • 甲基染料,其制造方法和含有相同染料的卤化银照相材料
    • US06884891B2
    • 2005-04-26
    • US10192590
    • 2002-07-11
    • Katsumi Kobayashi
    • Katsumi Kobayashi
    • C07D263/56C07D277/64C07D417/14C09B23/00C09B23/01C09B23/02C09B23/10G03C1/12
    • C07D263/56C07D277/64C07D417/14C09B23/0066C09B23/0083C09B23/02C09B23/10G03C1/12
    • Methine dye compounds represented by formula (1) and highly sensitive silver halide photographic materials containing these compounds: Dye1-(L1-(Dye2)m1)m2 (CI1)y1  (1) wherein L1 represents a linkage group represented by formula (2), m1 represents an integer of 1 to 5, m2 represents an integer of 1 to 5, Dye1 represents a first chromophore, Dye 2 represents a second chromophore, CI1 represents an ion for neutralization of electric charge, and y1 represents a number of the ions required for neutralization of electric charges; -G1-A1-Y1-G2-Y2-A2-G3-  (2) wherein A1 and A2 each individually represent a carbonyl group or a sulfonyl group, Y1 and Y2 each individually represent —O—, —S— or —NR1—, R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group, and G1, G2 and G3 each individually represent a divalent linkage group.
    • 由式(1)表示的甲基染料化合物和含有这些化合物的高灵敏度卤化银照相材料:<?in-line-formula description =“In-line Formulas”end =“lead”→Dye1-(L 1 (1)(1)&lt;&lt; 1&gt;(1)&lt; -line-formula description =“In-line Formulas”end =“tail”?>其中L 1表示由式(2)表示的连接基团,m1表示1〜5的整数,m 2 表示1〜5的整数,染料1表示第一发色团,染料2表示第二发色团,CI 1表示用于中和电荷的离子,y1表示中和所需的离子数 的电费; <?in-line-formula description =“In-line Formulas”end =“lead”?> - G <1> 1 - (2)<α-2 2 line-formula description =“In-line Formulas”end =“tail”?>其中A 1和A 2各自各自表示羰基或磺酰基,Y 1个和Y 2个各自各自独立地表示-O - , - S-或-NR 1 - , - R 1, 表示氢原子,烷基,烯基,芳基或杂环基,G 1,G 2和G 3 >各自独立地表示二价连接基团。
    • 10. 发明授权
    • Photosensitive element containing a silver halide emulsion chemically
sensitized with a chalcogenic compound
    • 含有用硫代钼化合物化学致敏的卤化银乳剂的感光元件
    • US6063558A
    • 2000-05-16
    • US317626
    • 1999-05-25
    • Johan LoccufierRene De KeyzerAntonius Rutges
    • Johan LoccufierRene De KeyzerAntonius Rutges
    • G03C1/015G03C1/09G03C1/12
    • G03C1/09G03C1/015G03C1/12
    • A photosensitive element which comprises on a support at least one photosensitive silver halide emulsion layer and at least a non-light sensitive layer, wherein the silver halide emulsion layer comprises a chalcogenic compound satisfying formula (1): ##STR1## wherein: X represents Se or Te, forming a double bond with its neighbouring C-atom,Nu represents a nucleophilic group which brings an electron pair in heterolytic bond formation; Nu has a pK.sub.a -value of at least 2.0 if Nu is an acidic group,L represents a divalent linking group representing each group which can position an electron donating atom in any of the 5th to the 8th position vis-a-vis the carbon atom of the carbon-chalcogen double bond,AQB represents the necessary atoms to form a heterocyclic 5- or 6-membered ring, provided that when A is a Nitrogen-atom, B is an atom selected from the group consisting of NR.sup.1, O, S, Se and Te,R.sup.1 can represent a hydrogen, an alkyl group, an acyl-group, an aryl group, an aralkyl group or a heteroaryl group;and a method wherein said chalcogenic compound is used during the step of chemically sensitizing at least one of the said silver halide emulsions at a pH-value situated between 3 and 10, a pAg-value situated between 6 and 11 and a temperature in the range of from 40.degree. C. up to 95.degree. C.
    • 一种感光元件,其在载体上包含至少一个感光卤化银乳剂层和至少一种不敏感层,其中所述卤化银乳剂层包含满足式(1)的硫代化合物:其中:X表示Se或Te, 与其相邻的C原子形成双键,Nu表示亲电基团,其使电子对在杂解键形成中; 如果Nu是酸性基团,则Nu的pKa值至少为2.0,L表示可以相对于碳原子在5至8位任一位置给电子给体原子的每个基团的二价连接基团 的碳 - 硫属元素双键,AQB表示形成杂环的5或6元环的必要原子,条件是当A为氮原子时,B为选自NR 1,O,S ,Se和Te,R 1可以表示氢,烷基,酰基,芳基,芳烷基或杂芳基; 以及一种方法,其中在化学增感至少一种所述卤化银乳剂的步骤中使用所述硫代化合物,其pH值为3至10,pAg值为6至11,温度范围为 为40℃至95℃