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    • 1. 发明授权
    • Direct positive silver halide photographic material
    • 直接正卤化银照相材料
    • US4820625A
    • 1989-04-11
    • US98660
    • 1987-09-21
    • Naomi SaekiNobuaki InoueToshinao UkaiYuji Mihara
    • Naomi SaekiNobuaki InoueToshinao UkaiYuji Mihara
    • G03C1/06G03C1/485
    • G03C1/48523Y10S430/141
    • A direct positive silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer comprising a prefogged direct-positive silver halide emulsion, preferably one having a chloride content of at least 70 mol%, said emulsion layer or a hydrophilic colloid layer adjacent to said emulsion layer containing at least one compound represented by the following general formula (I) and, optionally, a specified organic desensitizer, ##STR1## wherein Z.sub.1 represents a group of nonmetallic atoms necessary to complete a nitrogen-containing hetero ring; T represents an alkyl group, a cycloalkyl group, an alkenyl group, a halogen atom, a cyano group, a trifluoromethyl group, an alkoxy group, an aryloxy group, a hydroxy group, an alkoxycarbonyl group, a carboxyl group, a carbamoyl group, a sulfamoyl group, an aryl group, an acylamino group, a sulfonamido group, a sulfo group, or a benzo-condensed ring, each of which is or is not substituted; q represents 1, 2, or 3; and r represents 0, 1 or 2.
    • 一种直接正性卤化银照相材料,其包括其上具有至少一个卤化银乳剂层的载体,所述卤化银乳剂层包含预成型的直接正性卤化银乳剂,优选氯化物含量为至少70mol%的卤化银乳剂层,所述乳剂层或亲水胶体层 邻近所述乳剂层,其含有至少一种由以下通式(I)表示的化合物和任选的特定的有机脱敏剂,其中Z1表示完成含氮杂原子所必需的一组非金属原子 环; T表示烷基,环烷基,烯基,卤素原子,氰基,三氟甲基,烷氧基,芳氧基,羟基,烷氧基羰基,羧基,氨基甲酰基, 各自为或不被取代的氨磺酰基,芳基,酰氨基,亚磺酰氨基,磺基或苯并稠合环; q表示1,2或3; r表示0,1或2。
    • 4. 发明授权
    • Heat-developable photosensitive material
    • 热显影感光材料
    • US06344313B1
    • 2002-02-05
    • US09538727
    • 2000-03-30
    • Takahiro GotoToshihide EzoeHiroyuki SuzukiMinoru SakaiHideki MaetaNobuaki InoueMasaru Takasaki
    • Takahiro GotoToshihide EzoeHiroyuki SuzukiMinoru SakaiHideki MaetaNobuaki InoueMasaru Takasaki
    • G03C1498
    • G03C1/49845
    • An object of the present invention is to provide a heat-developable photosensitive material of improved fluctuation of photographic performance (sensitivity, Dmin) arisen from fluctuation of development temperature condition (temperature, time) and storage time after heat development. According to the present invention, there is provided a heat-developable photosensitive material, wherein the photosensitive material comprises, on a support, an image-forming layer containing at least (a) non-photosensitive organic silver salt, (b) photosensitive silver halide, (c) a reducing agent, and (d) a binder, and a protective layer on the image-forming layer, polymer latexes are used as binders of the image-forming layer and the protective layer, and the photosensitive material further comprises, on the image-forming layer side, (e) a nucleating agent and (f) one or more compounds represented by the following formula (1): wherein, in the formula (1), Z1 and Z2 each independently represent a halogen atom, X1 represents a hydrogen atom or an electron withdrawing group, Y1 represents —CO— group or —SO2— group, Q represents an arylene group which may have a substituent or a divalent heterocyclic group which may have a substituent, L represents a linking group, W represents carboxyl group or a salt thereof, slufo group or a salt thereof, phosphoric acid group, hydroxyl group, a quaternary ammonium group, or a polyethyleneoxy group, and n represents 0 or 1.
    • 本发明的目的是提供一种由显影温度条件(温度,时间)的波动和热显影后的储存时间引起的照相性能(灵敏度,Dmin)变动波动的热显影感光材料。 根据本发明,提供了一种热显影感光材料,其中感光材料在载体上包含至少含有(a)非光敏有机银盐的图像形成层,(b)感光卤化银 ,(c)还原剂,和(d)粘合剂和图像形成层上的保护层,聚合物胶乳用作图像形成层和保护层的粘合剂,并且感光材料还包含, 在成像层侧,(e)成核剂和(f)一种或多种由下式(1)表示的化合物:其中,在式(1)中,Z1和Z2各自独立地表示卤素原子, X1表示氢原子或吸电子基,Y1表示-CO-基或-SO2-基,Q表示可具有取代基的亚芳基或可具有取代基的2价杂环基,L表示连接基, W代表羧基 基团或其盐,slufo基团或其盐,磷酸基,羟基,季铵基或聚乙烯氧基,n表示0或1。
    • 9. 发明授权
    • Method of forming image providing a change in sensitivity by altering
the pH of the developer
    • US4873173A
    • 1989-10-10
    • US110981
    • 1987-10-21
    • Senzo SasaokaTetsuo YoshidaNobuaki Inoue
    • Senzo SasaokaTetsuo YoshidaNobuaki Inoue
    • G03C5/29G03C1/06G03C5/30
    • G03C1/061G03C5/30
    • A method of forming an image is provided. The method comprises the steps of (a) imagewise exposing a photographic material which comprises a support having provided thereon at least one light-sensitive silver halide emulsion layer and which contains a hydrazine compound represented by the following general formula (I) in the emulsion layer or a hydrophilic colloid layer adjacent thereto, the photographic material being designed so that a difference in sensitivity (sensitivity being defined as log E corresponding to the density of fog+2.0) between (1) the photographic material is development-processed with a developing solution having a sulfite ion concentration of 0.15 mole/l or more, a potassium ion concentration of 0.2 mole/l or more and a pH value ranging from 10.5 to 12.3 and (2) the photographic material is development-processed with the same developing solution as described above, except that the pH value was lowered by 1.0, (.DELTA.log E), is 0.7 or less, and moreover, the gamma value obtained in (1) is 10 or more and the gamma value obtained in (2) is 5 or more: ##STR1## wherein A represents an aliphatic group, or an aromatic group; B represents a formyl group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, a carbamoyl group, an alkoxycarbonyl group, an aryloxcarbonyl group, a sulfinamoyl group, an alkoxysulfonyl group, a thioacyl group, a thiocarbamoyl group, a sulfamoyl group, or a heterocyclic group; both R.sub.0 and R.sub.1 represent a hydrogen atom, or one of them represents a hydrogen atom and the other represents an alkysulfonyl group, an arylsulfonyl group, or an acyl group; and B, R.sub.1 and the nitrogen atom attached thereto may form a partial structure of hydrazone, and (b) developing the exposed material with a developer. The method realizes superhigh contrast and high resolution images.