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    • 1. 发明授权
    • Fine polymer particles having heterogeneous phase structure
    • 具有异质相结构的聚合物微粒
    • US6027805A
    • 2000-02-22
    • US103936
    • 1998-06-25
    • Junichi YamanouchiHidetoshi WatanabeKunio IshigakiSeiichi YamamotoKouta Fukui
    • Junichi YamanouchiHidetoshi WatanabeKunio IshigakiSeiichi YamamotoKouta Fukui
    • C08F279/02C08L51/00C08L51/04C08L51/06C08L53/00C08L53/02G03C1/053G03C1/95G03C5/26G03C5/30G03C5/305G03C5/31C08F279/00
    • G03C5/30C08F279/02C08L51/00C08L51/04C08L51/06C08L53/00C08L53/02G03C1/053G03C1/95G03C5/26G03C5/265G03C5/3021G03C5/3035G03C5/305G03C5/31Y10T428/2984Y10T428/2987Y10T428/2989
    • Latex polymer of fine particles having a heterogeneous phase structure which comprises a core of a polymer having repeating units derived from a conjugated diene monomer and a shell of a polymer having repeating units derived from at least one ethylenically unsaturated monomer carrying an active methylene group; a silver halide photographic light-sensitive material comprises a core/shell latex polymer whose shell consists of a polymer having repeating units of an ethylenically unsaturated monomer represented by the formula: CH.sub.2 .dbd.C(R.sup.1)--L--X (wherein R.sup.1 represents H, alkyl or halogen, L represents a single bond or a bivalent coupling group, X represents an active methylene group, provided that L is bonded to X in the form of alkylene; and a method for forming images on a silver halide light-sensitive material which comprises exposing the material which comprises at least one light-sensitive silver halide emulsion layer and at least one hydrophilic colloidal layer either of which comprises a latex polymer having active methylene groups and developing the exposed material with a developer which comprises a dihydroxybenzene developing agent and an auxiliary developing agent showing superadditivity, the pH increase observed when adding 0.1 mole/l developer of NaOH to the developer .ltoreq.0.25; 9.5.ltoreq. initial pH of the developer .ltoreq.11.0; the amount of the developer supplemented .ltoreq.225 ml/ml.sup.2.
    • 具有非均相结构的细颗粒的乳胶聚合物,其包含具有衍生自共轭二烯单体的重复单元的聚合物芯和具有衍生自至少一种带有活性亚甲基的烯属不饱和单体的重复单元的聚合物的壳; 卤化银照相感光材料包括核/壳胶乳聚合物,其壳由具有由式:CH 2 = C(R 1)-LX(其中R 1表示H的烷基或烷基)的烯属不饱和单体的重复单元的聚合物组成, 卤素,L表示单键或二价偶联基团,X表示活性亚甲基,条件是L以亚烷基的形式键合到X;以及在卤化银感光材料上形成图像的方法,其包括曝光 所述材料包含至少一种感光卤化银乳剂层和至少一种亲水性胶体层,其中任一种包含具有活性亚甲基的胶乳聚合物,并用显影剂显影所述外露材料,所述显影剂包含二羟基苯显影剂和辅助显影剂 显示超加性剂,当向显影剂添加0.1mol / l NaOH显影剂时观察到的pH增加
    • 4. 发明授权
    • Process of treating a silver halide photographic element
    • 处理卤化银照相元件的方法
    • US5238801A
    • 1993-08-24
    • US965050
    • 1992-10-22
    • Kunio IshigakiKen-ichi KuwabaraAkira Hatakeyama
    • Kunio IshigakiKen-ichi KuwabaraAkira Hatakeyama
    • G03C1/005G03C1/74
    • G03C1/005G03C1/74
    • A silver halide photographic material which has at least one silver halide emulsion layer on a support, wherein there is incorporated at least one electrically conductive layer of which the surface resistance is not more than 10.sup.12 .OMEGA. under conditions of 25.degree. C., 25% RH, which photographic material has been dried out at a relative humidity of not more than 50% when the water content is not more than 300 wt% with respect to the total dry weight of the binder included in the silver halide emulsion layers and other hydrophilic layers on the support, which was subjected, after drying, to a heat treatment of duration at least 6 hours at a temperature of at least 30.degree. C. in an atmosphere of absolute humidity not more than 0.01, and which has been stored under conditions of absolute humidity not more than 0.01.
    • 一种卤化银照相材料,其在载体上具有至少一个卤化银乳剂层,其中在25℃,25%RH的条件下并入至少一个导电层,其表面电阻不超过1012欧姆 当相对于卤化银乳剂层和其它亲水层中包含的粘合剂的总干重,当含水量不超过300重量%时,照相材料已经在相对湿度不超过50%的条件下干燥 在干燥后在绝对湿度不大于0.01的气氛中在至少30℃的温度下进行至少6小时的热处理的载体上,并且在 绝对湿度不大于0.01。
    • 7. 发明授权
    • Method of hardening gelatin and photographic materials produced thereby
    • 硬化明胶和由此生产的照相材料的方法
    • US4444926A
    • 1984-04-24
    • US320028
    • 1981-11-10
    • Masasi OgawaKunio IshigakiKiyotaka Hori
    • Masasi OgawaKunio IshigakiKiyotaka Hori
    • C08L89/00C09H7/00G03C1/053G03C1/30B01J13/02
    • G03C1/053G03C1/307
    • A method of hardening gelatin is described which uses (1) a polymer containing at least 0.01 mol % of a repeating unit represented by formula (I) ##STR1## wherein R represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, or a halogen atom, M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, or an organic base, X represents an alkyl group having from 1 to 6 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, an alkylamino group having from 1 to 6 carbon atoms, or a halogen atom, m represents 0, 1 or 2, and n represents 1 or 2, (2) a polyvalent alcohol having at least two hydroxy groups, and (3) a hardener having an active vinyl group.The method has advantages in that the rate of hardening the gelatin is fast, the so-called post hardening property is small, and the gelatin composition is hardely influenced by the conditions of temperature and humidity during storage.
    • 描述了一种硬化明胶的方法,其使用(1)含有至少0.01mol%由式(I)表示的重复单元的聚合物其中R表示氢原子,具有1〜 6个碳原子或卤素原子,M表示氢原子,碱金属原子,碱土金属原子或有机碱,X表示碳原子数1〜6的烷基,烷氧基含1个 至6个碳原子,具有1至6个碳原子的烷基氨基或卤素原子,m表示0,1或2,n表示1或2,(2)具有至少两个羟基的多元醇,以及 (3)具有活性乙烯基的固化剂。 该方法的优点在于明胶硬化速度快,所谓的后固化性能小,明胶组合物在储存期间受温度和湿度条件的影响很大。