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1. 发明授权

US5476945A Water-soluble methine derivatives of thiazole 失效
标题翻译：噻唑的水溶性次甲基衍生物
公开(公告)号：US5476945A
公开(公告)日：1995-12-19
申请号：US138061
申请日：1993-10-19
申请人： Akihiko Ikegawa , Toshinao Ukai , Masayuki Kawakami
发明人： Akihiko Ikegawa , Toshinao Ukai , Masayuki Kawakami
IPC分类号： C07D277/64 , C07D417/14 , C09B23/01 , C09B23/16 , G03C1/22 , C07D413/14
CPC分类号： C07D417/14 , C07D277/64 , C09B23/0083 , C09B23/164 , G03C1/22
摘要： A methine compound represented by the following formula (I): ##STR1## wherein Z.sub.1 and Z.sub.2 each represent a non-metallic atomic group necessitated for forming a five-membered or six-membered, nitrogen-containing heterocyclic ring, R.sub.1 and R.sub.2 each represent an alkyl group, X represents an inorganic anion, k represents a number necessitated for adjusting the electric charge of the molecule to zero, and n represents 0 or 1; with the proviso that when n is 1, the five-membered or six-membered, nitrogen-containing heterocyclic ring formed by Z.sub.2 is cationic, k is not zero and X represents chloride ion. The compound is useful as a spectral sensitizing dye and an antitumor agent.
摘要翻译：由下式（I）表示的次甲基化合物：其中Z1和Z2各自表示形成五元或六元含氮杂环所必需的非金属原子团，R1和 R2各自表示烷基，X表示无机阴离子，k表示将分子的电荷调整为零所需的数，n表示0或1; 条件是当n为1时，由Z2形成的五元或六元含氮杂环是阳离子的，k不为零，X表示氯离子。该化合物可用作光谱增感染料和抗肿瘤剂。

2. 发明授权

US2535992A Thiazolone cyanine dye intermediates 失效
标题翻译：噻唑蓝染料中间体
公开(公告)号：US2535992A
公开(公告)日：1950-12-26
申请号：US6657148
申请日：1948-12-21
申请人： GEN ANILINE & FILM CORP
发明人： THOMPSON THOMAS R
IPC分类号： C09B23/01 , C09B23/04
CPC分类号： C09B23/04 , C09B23/0083

3. 发明授权

US2518730A Process of preparing trinuclear cyanine dyes containing a terminal 5-membered nitrogenous heterocyclic ring system 失效
标题翻译：制备含有末端5元含氮杂环系的三核花青染料的方法
公开(公告)号：US2518730A
公开(公告)日：1950-08-15
申请号：US6657448
申请日：1948-12-21
申请人： GEN ANILINE & FILM CORP
发明人： THOMPSON THOMAS R
IPC分类号： C09B23/01
CPC分类号： C09B23/0083

4. 发明授权

US09040722B2 Photoelectric conversion device and photoelectric conversion device dye, and compound 有权
标题翻译：光电转换装置和光电转换装置染料，复合
公开(公告)号：US09040722B2
公开(公告)日：2015-05-26
申请号：US13876618
申请日：2011-09-27
申请人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Yohei Aoyama , Kensaku Akimoto , Tatsuya Ishida , Toru Yano
发明人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Yohei Aoyama , Kensaku Akimoto , Tatsuya Ishida , Toru Yano
IPC分类号： C07D405/12 , C07D209/08 , C07D417/14 , C07D409/14 , C07D403/06 , C07D413/14 , H01L51/00 , C09B23/12 , C09B23/01 , C07D209/60 , C07D405/14 , C09B23/04 , C09B23/06 , C09B23/08 , C09B23/10 , C09B23/16 , H01G9/20
CPC分类号： H01L51/0032 , C07D209/08 , C07D209/60 , C07D403/06 , C07D405/12 , C07D405/14 , C07D409/14 , C07D413/14 , C07D417/14 , C09B23/0016 , C09B23/0058 , C09B23/0066 , C09B23/0075 , C09B23/0083 , C09B23/04 , C09B23/06 , C09B23/083 , C09B23/105 , C09B23/107 , C09B23/12 , C09B23/164 , H01G9/2031 , H01G9/204 , H01G9/2059 , H01G9/2063 , H01L51/0064 , Y02E10/542
摘要： The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要翻译：本文所述的光电转换装置包括具有染料负载的金属氧化物电极的工作电极，其中染料负载在金属氧化物层上。染料包括由通式（I）表示的结构，其中A是在甲醇溶液中具有350至500nm的最大吸收波长λmax的结构; B是在甲醇溶液中具有500〜700nm的最大吸收波长λmax的花青骨架; Z1是选自-CONR-，-NRCO-，-SO2NR-和-NRSO2-的任何一个二价连接基团; Z1中的R是氢原子，碳原子数1〜8的烷基或碳原子数7〜20的芳烷基， Y1和Y2各自独立地为具有1至8个碳原子的亚烷基或单键，并且可以相同或不同; r为1或2; m和n各自独立地为0〜2的整数。（m + n）为1以上。

5. 发明申请

US20130199613A1 INK FOR ACTIVE LAYER OF ORGANIC SOLAR CELL, ORGANIC SOLAR CELL, AND PROCESS FOR MANUFACTURE OF ORGANIC SOLAR CELL 审中-公开
标题翻译：有机太阳能电池，有机太阳能电池活性层的吸入和有机太阳能电池的制造工艺
公开(公告)号：US20130199613A1
公开(公告)日：2013-08-08
申请号：US13823202
申请日：2011-11-15
申请人： Akinobu Hayakawa , Kazushi Ito , Taku Sasaki
发明人： Akinobu Hayakawa , Kazushi Ito , Taku Sasaki
IPC分类号： H01L51/42
CPC分类号： H01L51/4213 , B82Y10/00 , C09B23/0058 , C09B23/0083 , C09B23/105 , C09B69/008 , C09D11/52 , H01L51/0003 , H01L51/0007 , H01L51/0036 , H01L51/0037 , H01L51/0047 , H01L51/4233 , H01L2251/308 , H01L2251/552 , Y02E10/549 , Y02P70/521
摘要： The present invention aims to provide an ink for an active layer of an organic solar cell, wherein an active layer having high energy conversion efficiency can be stably and easily formed from the ink; an organic solar cell having high energy conversion efficiency; and a method for producing the organic solar cell. A first aspect of the present invention is an ink for an active layer of an organic solar cell, the ink comprising: an organic semiconductor compound; an inorganic semiconductor compound; an organic solvent; and a dispersant; wherein the dispersant is a compound having a structure with an aromatic ring and/or heterocyclic ring and a polar group asymmetrically bonded to the structure, and fulfills all of the following requirements (1) to (3): (1) the dispersant has a lower LUMO level than the organic semiconductor compound; (2) solubility of the dispersant in the organic solvent is equal to or higher than solubility of the organic semiconductor compound in the organic solvent; and (3) the dispersant has a higher HOMO level than the inorganic semiconductor compound.
摘要翻译：本发明的目的在于提供一种有机太阳能电池的有源层的油墨，其中能够从油墨稳定且容易地形成具有高能量转换效率的活性层; 具有高能量转换效率的有机太阳能电池; 和有机太阳能电池的制造方法。本发明的第一方面是一种有机太阳能电池的活性层用油墨，其特征在于，含有有机半导体化合物; 无机半导体化合物; 有机溶剂; 和分散剂; 其中分散剂是具有芳环和/或杂环结构的化合物和与结构不对称结合的极性基团，并且满足以下所有要求（1）至（3）：（1）分散剂具有低于有机半导体化合物的LUMO水平; （2）分散剂在有机溶剂中的溶解度等于或高于有机半导体化合物在有机溶剂中的溶解度; 和（3）分散剂具有比无机半导体化合物更高的HOMO能级。

6. 发明申请

US20130186468A1 PHOTOELECTRIC CONVERSION DEVICE AND PHOTOELECTRIC CONVERSION DEVICE DYE, AND COMPOUND 有权
标题翻译：光电转换装置和光电转换装置染料及其化合物
公开(公告)号：US20130186468A1
公开(公告)日：2013-07-25
申请号：US13876618
申请日：2011-09-27
申请人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Yohei Aoyama , Kensaku Akimoto , Tatsuya Ishida , Toru Yano
发明人： Junji Tanabe , Atsushi Monden , Masahiro Shinkai , Yohei Aoyama , Kensaku Akimoto , Tatsuya Ishida , Toru Yano
IPC分类号： H01L51/00 , H01G9/20
CPC分类号： H01L51/0032 , C07D209/08 , C07D209/60 , C07D403/06 , C07D405/12 , C07D405/14 , C07D409/14 , C07D413/14 , C07D417/14 , C09B23/0016 , C09B23/0058 , C09B23/0066 , C09B23/0075 , C09B23/0083 , C09B23/04 , C09B23/06 , C09B23/083 , C09B23/105 , C09B23/107 , C09B23/12 , C09B23/164 , H01G9/2031 , H01G9/204 , H01G9/2059 , H01G9/2063 , H01L51/0064 , Y02E10/542
摘要： The photoelectric conversion device described herein includes a working electrode having a dye-supported metal oxide electrode in which a dye is supported on a metal oxide layer. The dye includes a structure represented by general formula (I) wherein A is a structure having a maximum absorption wavelength λmax of 350 to 500 nm in a methanol solution; B is a cyanine skeleton having a maximum absorption wavelength λmax of 500 to 700 nm in a methanol solution; Z1 is any one divalent linking group selected from —CONR—, —NRCO—, —SO2NR—, and —NRSO2—; R in Z1 is a hydrogen atom, an alkyl group having 1 to 8 carbon atoms, or an arylalkyl group having 7 to 20 carbon atoms; Y1 and Y2 are each independently an alkylene group having 1 to 8 carbon atoms, or a single bond, and may be the same or different; r is 1 or 2; m and n are each independently an integer of 0 to 2; and (m+n) is 1 or more.
摘要翻译：本文所述的光电转换装置包括具有染料负载的金属氧化物电极的工作电极，其中染料负载在金属氧化物层上。染料包括由通式（I）表示的结构，其中A是在甲醇溶液中具有350-500nm的最大吸收波长的结构; B是在甲醇溶液中具有500-700nm最大吸收波长的花青骨架; Z1是选自-CONR-，-NRCO-，-SO2NR-和-NRSO2-的任何一个二价连接基团; Z1中的R是氢原子，碳原子数1〜8的烷基或碳原子数7〜20的芳烷基， Y1和Y2各自独立地为具有1至8个碳原子的亚烷基或单键，并且可以相同或不同; r为1或2; m和n各自独立地为0〜2的整数。（m + n）为1以上。

7. 发明申请

US20020072019A1 Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US20020072019A1
公开(公告)日：2002-06-13
申请号：US09960981
申请日：2001-09-25
申请人： FUJI PHOTO FILM CO., LTD.
发明人： Katsuhisa Ohzeki , Tetsuo Nakamura
IPC分类号： G03C001/16 , G03C001/18 , G03C001/20
CPC分类号： G03C1/14 , C09B23/0066 , C09B23/0083 , C09B23/08 , C09B69/008 , C09B69/04 , C09B69/06 , G03C1/035 , G03C1/08 , G03C1/09 , G03C1/102 , G03C1/127 , G03C1/16 , G03C1/18 , G03C1/20 , G03C1/22 , G03C5/26 , G03C2001/03517 , G03C2001/03535 , G03C2001/093 , G03C2200/52 , Y10S430/146 , Y10S430/164
摘要： A silver halide photographic light-sensitive material is disclosed, comprising at least one silver halide emulsion layer, wherein the silver halide grain contained in said emulsion layer is silver chloroiodide or silver chloroiodobromide having a silver chloride content of 90 mol % or more and a silver iodide content of 0.01 to 1.0 mol %, at least one hexacyano complex is doped in an amount of at least 1null10null7 mol % based on the total silver amount, and said emulsion layer contains a methine dye represented by the following formula (I): 1 wherein Y represents an atomic group necessary for forming a heterocyclic ring or an atomic group necessary for forming a benzene ring condensed with a heterocyclic ring, which may further be condensed with another carbon ring or heterocyclic ring or may have a substituent, Z1 and Z2 each represents a single bond or an atomic group necessary for forming a nitrogen-containing heterocyclic ring which may further be condensed with another carbon ring or heterocyclic ring or may have a substituent, R represents an alkyl group, an aryl group or a heterocyclic group, D represents a group necessary for forming a methine dye, L1 and L2 each represents a methine group, p represents 0 or 1, M represents a counter ion, and m represents a number of 0 or more necessary for neutralizing the electric charge within the molecule.
摘要翻译：公开了一种卤化银照相感光材料，其包含至少一种卤化银乳剂层，其中所述乳剂层中所含的卤化银颗粒为氯化银银或氯化银含量为90摩尔％以上的氯碘溴化银和银碘化物含量为0.01〜1.0摩尔％，至少一种六氰基络合物的掺杂量相对于总银量为至少1×10 -7摩尔％，所述乳剂层含有下式（I）表示的次甲基染料，：其中Y表示形成杂环所需的原子团或形成与杂环稠合的苯环所需的原子团，其可以进一步与另一碳环或杂环稠合或可以具有取代基Z1和Z2 各自表示形成含氮杂环所需的单键或原子团，所述含氮杂环可以进一步与另一碳环或稠合或可以具有取代基，R表示烷基，芳基或杂环基，D表示形成次甲基染料所需的基团，L1和L2各自表示次甲基，p表示0或1，M表示反离子，m表示中和分子内的电荷所需的0以上的数。

8. 发明授权

US5958665A Sultone compound, quaternary salt compound and methine compound, production process thereof, and silver halide photographic light-sensitive material containing the quaternary salt compound and/or methine compound 失效
标题翻译：磺内酯化合物，季盐化合物和次甲基化合物，其制备方法和含有季盐化合物和/或次甲基化合物的卤化银照相感光材料
公开(公告)号：US5958665A
公开(公告)日：1999-09-28
申请号：US943157
申请日：1997-10-03
申请人： Takanori Hioki , Tetsuya Watanabe
发明人： Takanori Hioki , Tetsuya Watanabe
IPC分类号： C09B23/01 , C09B23/02 , C09B23/10 , G03C1/005 , G03C1/12 , G03C1/16 , G03C1/18 , G03C1/20 , G03C1/22 , G03C1/26 , G03C1/485 , G03C8/08
CPC分类号： C09B23/10 , C09B23/0066 , C09B23/0083 , C09B23/02 , G03C1/12 , G03C1/0051 , G03C1/127 , G03C1/16 , G03C1/18 , G03C1/20 , G03C1/22 , G03C1/26 , G03C1/48576 , G03C8/08
摘要： A sultone compound represented by formula (I) or (I'), a quaternary salt compound represented by formula (II) or (II'), a methine compound represented by formula (III) or (III'), production processes thereof and a silver halide photographic light-sensitive material comprising a quaternary salt compound represented by formula (II) or (II') and/or a methine compound represented by formula (III) or (III') are disclosed.
摘要翻译：由式（I）或（I'）表示的磺内酯化合物，由式（II）或（II'）表示的季盐化合物，由式（III）或（III'）表示的次甲基化合物，其制备方法和公开了包含由式（II）或（II'）表示的季盐化合物和/或由式（III）或（III'）表示的次甲基化合物的卤化银照相感光材料。

9. 发明授权

US3909274A Silver halide emulsion containing trinuclear rhodanine nucleus dyes soluble in low-molecular weight alcohols 失效
标题翻译：含有可溶于低分子量醇的三核绕丹宁核染料的卤化银乳剂
公开(公告)号：US3909274A
公开(公告)日：1975-09-30
申请号：US32057573
申请日：1973-01-02
申请人： MINNESOTA MINING & MFG
发明人： BERETTA PAOLO , MAGNANI LUIGI
IPC分类号： C09B23/00 , C09B23/01 , C09B67/34 , C09B67/44 , G03C1/26 , G03C1/10
CPC分类号： G03C1/26 , C09B23/0083
摘要： Trinuclear dyes derived from the rhodanine nucleus are made soluble in low-molecular weight alcohols by the addition of a substituent to the nitrogen atom of the rhodanine central nucleus.
摘要翻译：衍生自绕丹宁核的三核染料通过向绕丹宁中央核的氮原子加成取代基而使其溶于低分子量醇。

10. 发明授权

US2556515A Methine dyes containing a 3-aryl-4-thiazolidone nucleus 失效
标题翻译：含有3-芳基-4-噻唑烷酮核的甲基染料
公开(公告)号：US2556515A
公开(公告)日：1951-06-12
申请号：US36748
申请日：1948-01-02
申请人： EASTMAN KODAK CO
发明人： BROOKER LESLIE G S , WHITE FRANK L
IPC分类号： C09B23/01 , C09B23/04 , G03C1/16
CPC分类号： C09B23/0091 , C09B23/0083 , C09B23/04 , G03C1/16

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