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1. 发明授权

US4678611A Novel dyestuff intermediates and use thereof for the manufacture of novel azo dyes 失效
标题翻译：新型染料中间体及其用于制造新型偶氮染料的用途
公开(公告)号：US4678611A
公开(公告)日：1987-07-07
申请号：US820751
申请日：1986-01-17
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C301/00 , C07C303/06 , C07C309/47 , C09B29/01 , C09B29/095 , C09B43/12 , C09B62/006 , C09B62/008 , C09B62/04 , C09B62/085 , C09B62/095 , C09B62/24 , C09B62/245 , C09B62/28 , C09B62/47 , C09B62/473 , C09B62/477 , C09B62/51 , C09B62/515 , C07C143/56
CPC分类号： C09B62/006 , C09B29/0014 , C09B29/0955 , C09B62/043
摘要： Dyestuff intermediates of the formula ##STR1## wherein R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, R.sub.2 represents hydrogen or an acyl radical and Z represents hydrogen or a sulfo group, and the use thereof for the manufacture of azo dyes of the formula ##STR2## wherein D represents the radical of a coupling component, R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, and R.sub.2 represents hydrogen or an acyl radical, or of azo dyes of the formula ##STR3## wherein K is the radical of a coupling component, Z represents hydrogen or the sulfo group, and R.sub.2 represents hydrogen or an acyl radical.
摘要翻译：其中R 1表示氢，1〜8个碳原子的烷基或苯基，R 2表示氢或酰基，Z表示氢或磺基，其制备方法的用途其中D表示偶联组分的基团，R 1表示氢，1至8个碳原子的烷基或苯基，R 2表示氢或酰基，或偶氮染料其中K是偶合组分的基团，Z表示氢或磺基，R2表示氢或酰基。

2. 发明授权

US4602084A Monoazo dyes containing a 4-substituted-2-azo-1,1'-diphenylsulfone component 失效
标题翻译：含有4-取代-2-偶氮-1,1'-二苯砜组分的单偶氮染料
公开(公告)号：US4602084A
公开(公告)日：1986-07-22
申请号：US512089
申请日：1983-07-08
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C313/00 , C07C315/00 , C07C315/04 , C07C317/36 , C07C317/40 , C07C317/48 , C07D209/40 , C07D213/77 , C07D215/38 , C07D231/38 , C07D231/46 , C07D235/02 , C07D239/50 , C07D487/04 , C09B29/01 , C09B29/06 , C09B29/08 , C09B29/15 , C09B29/32 , C09B29/36 , C09B62/028 , C09B62/473 , C09B29/033 , C09B29/036 , C09B62/006
CPC分类号： C07D213/77 , C07D209/40 , C07D215/38 , C07D231/38 , C07D231/46 , C07D235/02 , C07D239/50 , C07D487/04 , C09B29/0007 , C09B29/065 , C09B29/10 , C09B29/322 , C09B29/36 , C09B62/028 , C09B62/473
摘要： Monoazo dyes of the formula ##STR1## in which K is the radical of a coupling component of the benzene or naphthalene series or of the heterocyclic series, and R is a ##STR2## --CO--R.sub.2 or --SO.sub.2 --O--R.sub.2 group in which R.sub.1 is hydrogen or C.sub.1-4 -alkyl and R.sub.2 is a substituted or unsubstituted monosulfo-C.sub.1-12 -alkyl radical, a substituted or unsubstituted monosulfophenyl, disulfophenyl, monosulfonaphthyl or disulfonaphthyl radical, and X and Y, independently of each other, are hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, halogen, C.sub.2-6 -alkanoylamino, C.sub.1-5 -alkylsulfonylamino or a substituted or unsubstituted phenyl or phenoxy radical, produce dyeings on polyamide material which have good light and wet fastness properties.
摘要翻译：式（1）的单偶氮染料其中K是苯或萘系列或杂环系列的偶联组分的基团，R是-CO-R 2或-SO 2 -O- R 2基团，其中R 1是氢或C 1-4 - 烷基，R 2是取代或未取代的单磺酰基-C 1-12 - 烷基，取代或未取代的单磺酰基苯基，二磺基苯基，单磺酰基萘基或二磺基萘基，X和Y各自独立地另一个是氢，C 1-4 - 烷基，C 1-4 - 烷氧基，卤素，C 2-6 - 烷酰基氨基，C 1-5 - 烷基磺酰基氨基或取代或未取代的苯基或苯氧基，在具有良好光线的聚酰胺材料上产生染色，湿牢度特性。

3. 发明授权

US5371201A Azo dyes and preparation and use thereof 失效
标题翻译：偶氮染料及其制备及应用
公开(公告)号：US5371201A
公开(公告)日：1994-12-06
申请号：US48081
申请日：1993-04-15
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B31/072 , C07C245/22
CPC分类号： C09B31/072
摘要： The invention relates to azo dyes of formula ##STR1## wherein A, B and R.sub.1 are as defined in claim 1. The azo dyes of formula (1) give dyeings of good fastness properties on nitrogen-containing or hydroxy group-containing fibre materials, paper or leather.
摘要翻译：本发明涉及式（1）的偶氮染料，其中A，B和R 1如权利要求1所定义。式（1）的偶氮染料给含有或含有羟基的染料具有良好的牢度性能纤维材料，纸或皮革。

4. 发明授权

US4906740A Monoazo dyes containing as the azo component A phenylsulfonylphenyl radical 失效
标题翻译：含有偶氮组分苯基磺酰基苯基的单偶氮染料
公开(公告)号：US4906740A
公开(公告)日：1990-03-06
申请号：US886756
申请日：1986-07-15
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/01 , C09B62/245 , C09B62/473 , D06P3/04
CPC分类号： C09B29/0007 , C09B62/245 , C09B62/473
摘要： The present invention relates to monoazo dyes which dye polyamide material with good light- and wet-fastness and which have the formula ##STR1## in which K is the radical of an amino- or alkoxy-benzene, amino- or alkoxy-naphthalene, naphthol, aminonaphthol, pyrazolone, aminopyrazole, indole, naphthimidazole, diphenylamine, tetrahydroquinoline or acetoacetamide and can be further substituted, R is hydrogen, halogen, C.sub.1-6 -alkyl, trifluoromethyl, carboxyl or a --SO.sub.2 --C.sub.1-6 --alkyl, --SO.sub.2 --R.sub.1, ##STR2## --CO--R.sub.4 group, in which R.sub.1 is a substituted or unsubstituted phenyl- or naphthyl-C.sub.1-4 -alkyl radical, R.sub.2 and R.sub.3 independently of one another are hydrogen or a substituted or unsubstituted C.sub.1-6 -alkyl or C.sub.5-7 -cycloalkyl radical and R.sub.4 is a substituted or unsubstituted phenyl radical, and X is hydrogen, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy or halogen, and in which R in formula (1) may not be hydrogen or chlorine if the radical --N.dbd.N--K is bonded to the phenyl ring in the o-position relative to the --SO.sub.2 -- group and K is the radical of an aminonaphthalenesulfonamide or a 2-amino-8-hydroxynaphthalene-6-sulfonic acid.
摘要翻译：本发明涉及染料具有良好耐光牢度和耐湿牢度的聚酰胺材料的单偶氮染料，其具有式（1）其中K是氨基或烷氧基 - 苯，氨基或烷氧基 - 萘，萘酚，氨基萘酚，吡唑啉酮，氨基吡唑，吲哚，萘并咪唑，二苯胺，四氢喹啉或乙酰乙酰胺，并且可以进一步被取代，R是氢，卤素，C 1-6 - 烷基，三氟甲基，羧基或-SO 2 -C 1-6 - 烷基，其中R 1是取代或未取代的苯基或萘基-C 1-4 - 烷基，R 2和R 3彼此独立地是氢或取代或未取代的C 1 -C 4 - 烷基，-SO 2 -R 1， -6-烷基或C 5-7 - 环烷基，R 4是取代或未取代的苯基，X是氢，C 1-4 - 烷基，C 1-4 - 烷氧基或卤素，并且其中式（1）中的R可以如果自由基-N = NK与相对于-SO 2 - 基团的O-位的苯环键合，则不是氢或氯，并且K 是氨基萘磺酰胺或2-氨基-8-羟基萘-6-磺酸的基团。

5. 发明授权

US4360460A Novel azo dyes having a 4-sulfo-5-aminomethyl naphthalene coupling moiety 失效
标题翻译：具有4-磺基-5-氨基甲基萘偶联部分的新型偶氮染料
公开(公告)号：US4360460A
公开(公告)日：1982-11-23
申请号：US217277
申请日：1980-12-16
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C301/00 , C07C303/06 , C07C309/47 , C09B29/01 , C09B29/095 , C09B43/12 , C09B62/006 , C09B62/008 , C09B62/04 , C09B62/085 , C09B62/095 , C09B62/24 , C09B62/245 , C09B62/28 , C09B62/47 , C09B62/473 , C09B62/477 , C09B62/51 , C09B62/515 , C09B63/00
CPC分类号： C09B62/006 , C09B29/0014 , C09B29/0955 , C09B62/043
摘要： Dyestuff intermediates of the formula ##STR1## wherein R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, R.sub.2 represents hydrogen or an acyl radical and Z represents hydrogen or a sulfo group, and the use thereof for the manufacture of azo dyes of the formula ##STR2## wherein D represents the radical of a coupling component, R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, and R.sub.2 represents hydrogen or an acyl radical, or of azo dyes of the formula ##STR3## wherein K is the radical of a coupling component, Z represents hydrogen or the sulfo group, and R.sub.2 represents hydrogen or an acyl radical.
摘要翻译：其中R 1表示氢，1〜8个碳原子的烷基或苯基，R 2表示氢或酰基，Z表示氢或磺基，其制备方法的用途其中D表示偶联组分的基团，R 1表示氢，1至8个碳原子的烷基或苯基，R 2表示氢或酰基，或偶氮染料其中K是偶合组分的基团，Z表示氢或磺基，R2表示氢或酰基。

6. 发明授权

US4248773A Acetoacetamide diazo dyestuffs 失效
标题翻译：乙酰乙酰胺重氮染料
公开(公告)号：US4248773A
公开(公告)日：1981-02-03
申请号：US964548
申请日：1978-11-29
申请人： Rudolf Hurter , Alfred Fasciati
发明人： Rudolf Hurter , Alfred Fasciati
IPC分类号： C07C301/00 , C07C67/00 , C07C229/64 , C07C309/49 , C07C311/37 , C07C311/39 , C07C313/00 , C07C317/32 , C07C317/36 , C07C319/20 , C07C323/41 , C07C323/48 , C07C323/63 , C07C323/65 , C07C323/66 , C07C323/67 , C07F9/38 , C09B29/01 , C09B29/32 , C09B29/33 , C09B31/02 , C09B31/22 , C09B62/006 , C09B62/47 , C09B69/00 , C09B45/30
CPC分类号： C09B62/006 , C07F9/3834 , C09B29/0003 , C09B29/32 , C09B29/332 , C09B31/025 , C09B69/007
摘要： Novel compounds which have the formula I ##STR1## in which D is the residue of a diazo component, K is the residue of a coupling component, A is an unsubstituted or substituted 1,3- or 1,4-phenylene radical or an unsubstituted or substituted 1,4-naphthylene radical, X is an oxygen atom or sulphur atom, R is a group conferring solubility in water and n and m are each the numbers 0 or 1, with the proviso that if A is a 1,3-phenylene radical the symbol X is bonded in the p-position relative to the amino group or azo grouping of the ring B.
摘要翻译：具有式I的化合物（I）其中D是重氮组分的残基，K是偶合组分的残基，A是未取代或取代的1,3-或1,4-亚苯基或未取代或取代的1,4-亚萘基，X为氧原子或硫原子，R为赋予水溶性的基团，n和m各自为数字0或1，条件是如果A为1 ，3-亚苯基，符号X相对于环B的氨基或偶氮基键合在对位。

7. 发明授权

US5928386A Process for trichromatic dyeing or printing 失效
标题翻译：三色染色或印刷方法
公开(公告)号：US5928386A
公开(公告)日：1999-07-27
申请号：US861288
申请日：1997-05-21
申请人： Rudolf Hurter , Jean-Marie Adam , Francine Casi
发明人： Rudolf Hurter , Jean-Marie Adam , Francine Casi
IPC分类号： C09B67/22 , D06P1/06 , D06P3/04 , D06P3/06 , D06P3/10 , D06P3/14 , D06P3/24 , C09B31/22
CPC分类号： D06P3/06 , C09B67/0058 , D06P3/04 , D06P3/10 , Y10S8/917 , Y10S8/918 , Y10S8/924 , Y10S8/925
摘要： A process for dyeing or printing natural or synthetic polyamide fiber material by the trichromatic technique, which comprises using at least one blue-dyeing dye of formula ##STR1## together with at least one red-dyeing dye of formula ##STR2## together with at least one yellow- or orange-dyeing dye of formula ##STR3##
摘要翻译：一种通过三色技术染色或印刷天然或合成聚酰胺纤维材料的方法，其包括使用至少一种式的蓝染染料与至少一种式的红染色剂一起连同至少一种黄色或橙色染色剂，染色剂配方

8. 发明授权

US4918183A Monoazo dyes, process for their preparation, and the use thereof 失效
标题翻译：单偶氮染料，其制备方法及其用途
公开(公告)号：US4918183A
公开(公告)日：1990-04-17
申请号：US790656
申请日：1985-10-24
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/01 , C09B62/008 , D06P3/04
CPC分类号： C09B62/008 , C09B29/0007
摘要： The invention relates to monoazo dyes of the formula ##STR1## wherein K is the radical of a coupling component of the benzene, naphthalene or heterocyclic series, and R is hydrogen, halogen, carboxy, a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkanoylamino, C.sub.1 -C.sub.6 alkylsulfonylamino, C.sub.1 -C.sub.6 alkylsulfonyl, phenyl(C.sub.1 -C.sub.4)alkylsulfonyl or naphthyl(C.sub.1 -C.sub.4)alkylsulfonyl or benzoyl radical, which radicals may be further substituted, or is a ##STR2## group, wherein each of R.sub.1 and R.sub.2 independently of the other is hydrogen or a C.sub.1 -C.sub.6 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl radical, which radicals may be further substituted, and wherein X is hydrogen, halogen or a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkanoylamino or C.sub.1 -C.sub.6 alkylsulfonylamino radical, which radicals may be further substituted.These dyes give dyeings of good light- and wetfastness properties on polyamide material.
摘要翻译：本发明涉及式（1）的单偶氮染料，其中K是苯，萘或杂环系列的偶联组分的基团，R是氢，卤素，羧基，C 1 -C 6烷基，C 1 -C 6烷氧基，C 2 -C 6烷酰基氨基，C 1 -C 6烷基磺酰基氨基，C 1 -C 6烷基磺酰基，苯基（C 1 -C 4）烷基磺酰基或萘基（C 1 -C 4）烷基磺酰基或苯甲酰基，该基团可以进一步被取代，或者为“ R 1和R 2彼此独立地是氢或C 1 -C 6烷基，C 5 -C 7环烷基，苯基或萘基，该基团可以被进一步取代，并且其中X是氢，卤素或C 1 -C 6烷基，C 1 -C 6烷氧基， C 6烷酰基氨基或C 1 -C 6烷基磺酰基氨基，该基团可以被进一步取代。这些染料在聚酰胺材料上产生良好的耐光性和耐湿性能的染色。

9. 发明授权

US4866164A 3-methyl-1-phenyl-5-pyrozolone-4-azo-1'-(3'-chloro-S-tri azinylamins)-benzene-6'-sulfonic acid compounds 失效
标题翻译： 3-甲基-1-苯基-5-焦唑酮-4-偶氮-1' - （3'-氯-3-三嗪基） - 苯-6'-磺酸化合物
公开(公告)号：US4866164A
公开(公告)日：1989-09-12
申请号：US843441
申请日：1986-03-24
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B62/085 , D06P1/382 , D06P3/14 , D06P3/24
CPC分类号： C09B62/085 , D06P1/382
摘要： The monoazo dyes of the formula ##STR1## wherein R.sub.1 is N-ethylanilino or anilino which is substituted by C.sub.2 -C.sub.5 alkanoylamino, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.3 is halogen or C.sub.1 -C.sub.4 alkyl, produce dyeings and prints of good lightfastness and wetfastness properties on polyamide fibre materials.
摘要翻译：式（1）的单偶氮染料其中R1是被C2-C5烷酰基氨基取代的N-乙基苯胺基或苯胺基，R2是氢或C1-C4烷基，R3是卤素或C1-C4烷基，产生良好的染色和印刷聚酰胺纤维材料的耐光牢度和耐湿性能。

10. 发明授权

US4219472A 5-Aminomethyl-2-amino naphthyl-(1) azo dyes 失效
标题翻译： 5-氨基甲基-2-氨基萘基 - （1）偶氮染料
公开(公告)号：US4219472A
公开(公告)日：1980-08-26
申请号：US908498
申请日：1978-05-22
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/06 , C09B29/095 , C09B43/128 , C09B44/04 , C09B45/14 , C09B62/006 , C09B62/44 , D06P1/02 , D06P1/18 , D06P1/38 , C09B62/08 , C09B62/24 , C09B62/40 , C09B62/50
CPC分类号： D06P1/02 , C09B29/06 , C09B29/095 , C09B43/128 , C09B44/04 , C09B45/14 , C09B62/006 , C09B62/4401 , D06P1/18 , D06P1/38
摘要： The invention relates to novel azo dyes of the formula ##STR1## wherein R.sub.1 represents hydrogen, alkyl of 1 to 8 carbon atoms or the phenyl radical, R.sub.2 represents hydrogen, an acyl radical or a fibre-reactive radical, and D represents the radical of any diazo component, which dyes are useful for dyeing and printing a wide variety of natural and synthetic textile materials and leather; thus the acid dyes, which optionally contain fiber-reactive groups, are used for dyeing and printing materials such as cellulose and natural or synthetic polyamide. The cationic dyes are especially used in dyeing and printing polyacrylonitrile, and the disperse dyes are especially used in dyeing and printing polyester materials.
摘要翻译：本发明涉及新的式（Ⅰ）的偶氮染料，其中R1代表氢，1-8个碳原子的烷基或苯基，R2代表氢，酰基或纤维反应性基团，D代表任何重氮组分，这些染料可用于染色和印刷各种天然和合成纺织材料和皮革; 因此任选地含有纤维反应性基团的酸性染料用于染色和印刷材料如纤维素和天然或合成聚酰胺。阳离子染料特别用于染色和印花聚丙烯腈，分散染料特别用于染色和印花聚酯材料。

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