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1. 发明授权

US06974497B2 Monoazo dyes 失效
标题翻译：单偶氮染料
公开(公告)号：US06974497B2
公开(公告)日：2005-12-13
申请号：US10398557
申请日：2001-09-27
申请人： Rainer Nusser
发明人： Rainer Nusser
IPC分类号： B41M5/00 , C09B62/095 , C09B62/255 , C09B62/44 , C09B62/515 , C09D11/328 , D06P1/382 , D06P1/384 , D06P3/10 , D06P3/66 , D06P5/00 , C09D11/02 , C09B45/18
CPC分类号： C09D11/328 , C09B62/095 , C09B62/255 , C09B62/4416
摘要： Claimed are compounds of formula (I) where the substituents are each as defined in the claims, their preparation, their use as dyes and as a ingredients of an ink-jet printing ink and also substrates dyed with such compounds.
摘要翻译：要求的是式（I）的化合物，其中取代基各自如权利要求书中所定义，它们的制备，它们作为染料的用途和喷墨印刷油墨的成分以及用这些化合物染色的底物。

2. 发明授权

US06852135B2 Water-soluble fiber-reactive colorants, method for the production thereof, and use their use 有权
标题翻译：水溶性纤维反应性着色剂，其制造方法及其用途
公开(公告)号：US06852135B2
公开(公告)日：2005-02-08
申请号：US10312900
申请日：2001-07-14
申请人： Joachim Steckelberg , Hermann Henk
发明人： Joachim Steckelberg , Hermann Henk
IPC分类号： C09B62/095 , C09B62/44 , C09B62/515 , D06P1/382 , D06P1/384 , D06P1/673 , D06P3/10 , D06P3/66 , D06P5/20
CPC分类号： C09B62/095 , C09B62/4416 , C09B62/515
摘要： Dyes of the general formula (1): where M is hydrogen, alkali, ammonium or the equivalent of an alkaline earth metal ion, X is halogen, alkoxy or an N-containing heterocycle, Q is a grouping of the formula (e) where Y is vinyl or an alkali-eliminable grouping and W is alkyl which may be interrupted by an O or an NR group and the radicals R1 and R2 represent alkyl, alkoxy, alkylcarbonylamino, arylcarbonylamino, and also the radicals R3 and R4 are alkyl or hydrogen, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing material, preferably fiber material.
摘要翻译：通式（1）的染料：其中M是氢，碱金属，铵或碱土金属离子当量，X是卤素，烷氧基或含氮杂环，Q是式（e）的组，其中 Y是乙烯基或可碱除去的基团，W是可被O或NR基团中断的烷基，基团R 1和R 2代表烷基，烷氧基，烷基羰基氨基，芳基羰基氨基， 3>和R 4是烷基或氢，它们的制备及其用于染色和印刷含羟基和/或甲酰氨基的材料，优选纤维材料的用途。

3. 发明授权

US5717078A Reactive dyes, containing two triazinyl radicals which are bridged via an aliphatic or aromatic bridge member 失效
标题翻译：含有两个通过脂族或芳族桥连桥桥连的三嗪基的活性染料
公开(公告)号：US5717078A
公开(公告)日：1998-02-10
申请号：US704425
申请日：1996-08-22
申请人： Athanassios Tzikas , Peter Aeschlimann
发明人： Athanassios Tzikas , Peter Aeschlimann
IPC分类号： C07D251/50 , C09B62/44 , C09B62/503 , C09B62/513 , C09B62/515 , C09B62/09 , C09B62/08 , C09B62/507 , D06P1/38
CPC分类号： C09B62/4403
摘要： Reactive dyes of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, X.sub.1 and X.sub.2 are halogen, B.sub.1 is an aromatic or aliphatic bridge member, or the radical of the formula --N(R.sub.2)--B.sub.1 --N(R.sub.3)-- is a piperazine radical, A.sub.1 is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore and, A.sub.2 is a radical of the formula ##STR2## in which D.sub.1 is substituted or unsubstituted phenyl or naphthyl, R.sub.5 and R.sub.6 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, alk is substituted or unsubstituted C.sub.2 -C.sub.6 alkylene and Z is vinyl or a radical --CH.sub.2 --CH.sub.2 --U.sub.1, and U.sub.1 is a leaving group, and the radicals A.sub.1 and A.sub.2 differ from one another, are particularly suitable for dyeing or printing fibre materials containing hydroxyl groups or containing nitrogen. Dyeings with good fastness properties are obtained with a high tinctorial yield.
摘要翻译：其中R 1，R 2，R 3和R 4彼此独立地是氢或取代或未取代的C 1 -C 4烷基，X 1和X 2的式（I）的反应性染料是卤素，B1是芳族或脂族桥连构件，或式-N（R2）-B1-N（R3） - 的基团是哌嗪基，A1是单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an或二恶嗪发色团的基团，A2是其中D1是取代或未取代的苯基或萘基，R 5和R 6彼此独立的式（II）的基团是氢或取代或未取代的C 1 -C 4烷基，烷基是取代或未取代的C 2 -C 6亚烷基，Z是乙烯基或基团-CH 2 -CH 2 -U 1，并且U1是离去基团，基团A1和A2彼此不同，特别适用于染色或印刷含有羟基或含氮的纤维材料。获得具有良好牢度性能的染色，具有高的着色收率。

4. 发明授权

US4925927A Reactive dyes containing a vinylsulfonylaminocarbonyl group bound to bis-(triazenylamino)-benzene as bridging member of two chromophoric systems 失效
公开(公告)号：US4925927A
公开(公告)日：1990-05-15
申请号：US212393
申请日：1988-06-27
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C09B62/505 , C09B62/44 , C09B62/503 , C09B62/51 , C09B62/513 , C09B62/515 , C09B62/517 , D06P1/38
CPC分类号： C09B62/4403
摘要： Reactive dyes which are particularly suitable for dyeing or printing cellulose-containing fiber materials by the exhaust method or by continuous methods having the formula ##STR1## in which D and D' are each independently of the other a radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye, R', R", B.sub.1 and B.sub.2 are independently of each other hydrogen or alkyl which has 1 to 4 carbon atoms and which is unsubstituted or substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato, X and Y are independently of each other fluorine, chlorine, bromine, sulfo, C.sub.1 -C.sub.4 -alkylsulfonyl or phenylsulfonyl, B is a direct bond or a radical --CH.sub.2).sub.n or --O--CH.sub.2).sub.n, n is 1 to 6; R is a radical of the formula ##STR2## Z is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acetoxyethyl, .beta.-haloethyl or vinyl; alk is alkylene having 1 to 6 carbon atoms or a branched isomer thereof; T is hydrogen, chlorine, bromine, fluorine, hydroxyl, sulfato, alkanoyloxy having 2 to 4 carbon atoms, cyano, carboxyl, alkoxycarbonyl having 1 to 5 carbon atoms, carbamoyl or a radical --SO.sub.2 --Z in which Z is as defined above, V is hydrogen or alkyl which has 1 to 4 carbon atoms and can be substituted by carboxyl, sulfo, carbamoyl, N-methylcarbamoyl, N-ethylcarbamoyl, N,N-dimethylcarbamoyl, N,N-diethylcarbamoyl, cyano, acetyl, propionyl, butyryl, methoxycarbonyl, ethoxycarbonyl, propyloxycarbonyl, sulfamoyl, N-methylsulfamoyl, N-ethylsulfonyl, N,N-dimethylsulfamoyl, N,N-diethylsulfamoyl, methylsulfonyl, ethylsulfonyl, propylsulfonyl, alkoxy groups having 1 or 2 carbon atoms, halogen or hydroxyl, or a radical ##STR3## in which Z, alk and T are as defined above, R.sub.1 is hydrogen or C.sub.1 -C.sub.6 -alkyl, each alk' is independently of the other one polymethylene having 2 to 6 carbon atoms or a branched isomer thereof, and m is 1 to 6, p is 1 to 6 and q is 1 to 6.

5. 发明授权

US4678611A Novel dyestuff intermediates and use thereof for the manufacture of novel azo dyes 失效
标题翻译：新型染料中间体及其用于制造新型偶氮染料的用途
公开(公告)号：US4678611A
公开(公告)日：1987-07-07
申请号：US820751
申请日：1986-01-17
申请人： Rudolf Hurter
发明人： Rudolf Hurter
IPC分类号： C09B29/00 , C07C67/00 , C07C301/00 , C07C303/06 , C07C309/47 , C09B29/01 , C09B29/095 , C09B43/12 , C09B62/006 , C09B62/008 , C09B62/04 , C09B62/085 , C09B62/095 , C09B62/24 , C09B62/245 , C09B62/28 , C09B62/47 , C09B62/473 , C09B62/477 , C09B62/51 , C09B62/515 , C07C143/56
CPC分类号： C09B62/006 , C09B29/0014 , C09B29/0955 , C09B62/043
摘要： Dyestuff intermediates of the formula ##STR1## wherein R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, R.sub.2 represents hydrogen or an acyl radical and Z represents hydrogen or a sulfo group, and the use thereof for the manufacture of azo dyes of the formula ##STR2## wherein D represents the radical of a coupling component, R.sub.1 represents hydrogen, an alkyl radical of 1 to 8 carbon atoms or a phenyl radical, and R.sub.2 represents hydrogen or an acyl radical, or of azo dyes of the formula ##STR3## wherein K is the radical of a coupling component, Z represents hydrogen or the sulfo group, and R.sub.2 represents hydrogen or an acyl radical.
摘要翻译：其中R 1表示氢，1〜8个碳原子的烷基或苯基，R 2表示氢或酰基，Z表示氢或磺基，其制备方法的用途其中D表示偶联组分的基团，R 1表示氢，1至8个碳原子的烷基或苯基，R 2表示氢或酰基，或偶氮染料其中K是偶合组分的基团，Z表示氢或磺基，R2表示氢或酰基。

6. 发明授权

US4564672A Water-soluble monoazo and disazo compounds containing a fibre-reactive 2-alkoxy-5-chloro-aniline diazo component and copper complexes thereof, useful as dyestuffs 失效
标题翻译：含有纤维反应性2-烷氧基-5-氯 - 苯胺重氮组分的水溶性单偶氮和双偶氮化合物及其铜配合物，可用作染料
公开(公告)号：US4564672A
公开(公告)日：1986-01-14
申请号：US517806
申请日：1983-07-27
申请人： Ludwig Schlafer
发明人： Ludwig Schlafer
IPC分类号： C09B62/507 , C09B62/51 , C09B62/515 , D06P1/384 , C09B62/513
CPC分类号： C09B62/515
摘要： New water-soluble azo compounds which have the general formula (1) ##STR1## in which K is the radical of a water-soluble coupling component which can couple at one or two positions in the molecule and which belongs to the series comprising aminobenzenes, phenols, naphthols, aminonaphthols, acylaminonaphthols, dihydroxynaphthalenesulfonic acids, phenylazoaminonaphtholsulfonic and naphthylazoaminonaphtholsulfonic acids, 5-pyrazolones and 5-aminopyrazoles and 2-hydroxy-6-pyridones, R represents an alkoxy group of 1 to 4 C-atoms and X a group of the formula --SO.sub.2 --CH.dbd.CH.sub.2 or --SO.sub.2 --CH.sub.2 --CH.sub.2 --Z in which Z is a group which can be eliminated under alkaline conditions, furthermore, the copper complex compounds of the above-mentioned metal-free compounds of the general formula (1). The novel metal-free compounds as well as the copper complex compounds have valuable dyestuff properties and are particularly suitable as fiber-reactive dyestuffs for dyeing and printing materials containing hydroxy or carbonamide groups, preferably fiber materials. The compounds of the invention produce deep dyeings which have very good fastness to nitrogen oxide and excellent fastness to wet processing such as fastness to boiling with sodium carbonate, fastness to washing at 60.degree. to 95.degree. C. and/or with peroxides, fastness to alkaline and acid perspiration, to water (under severe conditions), to alkalis and acids such as tartaric acid, to cross-dyeing, to bleaching with hypochlorite and to chlorinated water. The copper-complex compounds yield dyeings which are especially fast to light.
摘要翻译：具有通式（1）的新的水溶性偶氮化合物（1）其中K是水溶性偶联组分的基团，其可以在分子的一个或两个位置偶联并且属于该系列包括氨基苯，酚，萘酚，氨基萘酚，酰氨基萘酚，二羟基萘磺酸，苯偶氮基萘酚磺酸和萘基氨基萘酚磺酸，5-吡唑啉酮和5-氨基吡唑和2-羟基-6-吡啶酮，R表示1-4个C原子的烷氧基，X a 式-SO2-CH = CH2或-SO2-CH2-CH2-Z的基团，其中Z是在碱性条件下可以除去的基团，此外，上述不含金属的化合物的铜络合物通式（1）。新型无金属化合物以及铜络合物具有有价值的染料性能，特别适用于用于染色和印刷含有羟基或碳酰胺基团的材料的纤维活性染料，优选纤维材料。本发明的化合物产生对氮氧化物具有非常好的牢度和对湿法加工具有优异的耐湿牢度的深染色，例如用碳酸钠进行耐烫牢度，在60℃至95℃下耐洗牢度和/或用过氧化物，耐牢度碱性和酸性汗液，水（在苛刻条件下），碱和酸如酒石酸，交叉染色，用次氯酸盐和氯化水漂白。铜络合物产生特别快的染色。

7. 发明授权

US3637645A Water-soluble pyrazaline disazo dyestuffs and metal complex compounds thereof 失效
标题翻译：水溶性吡咯烷酮衍生物及其金属复合化合物
公开(公告)号：US3637645A
公开(公告)日：1972-01-25
申请号：US3637645D
申请日：1968-09-06
申请人： HOECHST AG
发明人： MEININGER FRITZ , FUCHS HERMANN
IPC分类号： C09B62/515 , C09B31/14 , C09B45/24 , D06P1/10
CPC分类号： C09B62/515
摘要： WATER-SOLUBLE DISAZO-DYESTUFFS HAVING IN FORM OF THE FREE ACID THE FORMULA

1-((Z)M-A(-O-R)-N=N-),3-(HO-),4-(HO3S-),6-((Z)N-K-N=N-)

NAPHTHALENE

R REPRESENT HYDROGEN OR LOWER ALKYL, M AND A REPRESENT INTEGERS FROM 0 TO 2, THE SUM OF M AND N BEING AT LEAST 1 AND AT MOST 2, A REPRESENTS THE RADICAL OF A DIZZO COMPONENT FO THE BENZENE AND NAPHTHALENE SERIES, AND K REPRESENTS THE RADICAL OF A COUPLING COMPONENT OF THE MAPHTHALENE, PYRAZOLONE AND ACEO-ACETYLARYLANIDE SERIES, AND THE 1:1 COPPER COMPLEX COMPOUND OR THE 1:2-COBALT-OR 1:2-CHROMIUM COMPLEX COMPOUNDS THEREOF, SAID DYESTUFFS BEING SUITABLE FOR THE DYEING OR PRINTING OF FIBROUS MATERIALS OF NATIVE OR REGENERATED CELLULOSE, WOOL, SILK, POLYAMIDES OR POLYARETHANES, THE DYEINGS AND PRINTS OBTAINED ON CELLULOSE FIBROUS MATERIALS BEING OF INTENSE REDBROWN, DARK BROWN, OLIVE, GREY (BLACK) OR NAVY BLUE SHADES AND BEING DISTINGUISHED BY A VERY GOOD FASTNESS TO LIGHT AND TO WET PROCESSING.

8. 发明申请

US20210002735A1 Process for the Simultaneous Tanning and Dyeing of Collagen Containing Fibrous Material 有权
公开(公告)号：US20210002735A1
公开(公告)日：2021-01-07
申请号：US16969783
申请日：2019-01-25
申请人： HUNTSMAN ADVANCED MATERIALS (SWITZERLAND) GMBH
发明人： Darryl Miles Cassingham , Georg Roentgen , Athanassios Tzikas
IPC分类号： C14C3/08 , D06P1/382 , D06P3/32 , C09B62/515 , C09B62/513
摘要： A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2) wherein A1, A2 and A3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q1, Q2, Q3 and Q4 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, G1 and G2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z1)2-3 is 2 to 3 identical or different fiber reactive radicals, Z2 and Z3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

9. 发明授权

US5583207A Fibre-reactive monoazo copper complexes containing a halo substituted pyrimidine substituent 失效
标题翻译：含有卤素取代的嘧啶取代基的纤维反应性单偶氮铜络合物
公开(公告)号：US5583207A
公开(公告)日：1996-12-10
申请号：US431652
申请日：1995-05-02
申请人： Rainer Nusser , Roland Wald
发明人： Rainer Nusser , Roland Wald
IPC分类号： C09B45/18 , C09B62/032 , C09B62/255 , C09B62/44 , C09B62/515 , C09B62/095 , D06P1/38 , D06P1/382
CPC分类号： C09B62/032 , C09B62/4401
摘要： Fibre-reactive 1:1 copper complexes of the formula ##STR1## which compounds are in free acid or salt form, and mixtures thereof, are useful for dyeing or printing hydroxy group- or nitrogen-containing organic substrates, for example leather and fibre material comprising natural or synthetic polyamides or natural or regenerated cellulose; the most preferred substrate is a textile material comprising cotton.
摘要翻译：具有游离酸或盐形式的化合物“IMAGE”的纤维反应性1：1铜络合物及其混合物可用于染色或印刷含羟基或含氮有机基质，例如皮革和纤维材料包括天然或合成聚酰胺或天然或再生纤维素; 最优选的基材是包含棉的纺织材料。

10. 发明授权

US5463031A Reactive dyestuffs 失效
标题翻译：活性染料
公开(公告)号：US5463031A
公开(公告)日：1995-10-31
申请号：US226435
申请日：1994-04-12
申请人： Horst Jager , Frank-Michael Stohr , Karl K. Schundehutte
发明人： Horst Jager , Frank-Michael Stohr , Karl K. Schundehutte
IPC分类号： C09B62/503 , C09B62/44 , C09B62/505 , C09B62/51 , C09B62/513 , C09B62/515 , C09B62/517 , C09B62/04 , C09B62/20 , D06P1/38
CPC分类号： C09B62/4422
摘要： Reactive dyestuffs of the formula ##STR1## in which the substituents have the meanings given in the description are highly suitable for the dyeing and printing of cellulose materials and nitrogen-containing materials.They produce dyeings and prints having good wet and light fastness properties.
摘要翻译：式（1）的反应性染料其中取代基具有本说明书中给出的含义非常适用于纤维素材料和含氮材料的染色和印花。它们产生具有良好的耐湿和耐光性的染色和印花。

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