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    • 7. 发明申请
    • Azo Dyes
    • 偶氮染料
    • US20140304926A1
    • 2014-10-16
    • US14362931
    • 2012-11-26
    • Huntsman International LLC
    • Alexander MuellerRainer HildebrandSiro Dalle-Nogare
    • D06P1/06C09B33/06
    • D06P1/06C09B33/06C09B67/0041C09B67/0046D06P1/0096D06P1/02
    • The present invention relates to dyes of formula (1), wherein each of the residues D1 and D2 represents a radical of formula (2), wherein Ar1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R1, R2 and R3 are each independently of the other hydrogen, C1-C12alkyl, C1-C12alkoxy, halogen, —OH, —CN, —NO2, —CF3, —SO3H, —NHCOR4, —COOR5, —CONR6R7, —SO2NR8R9, —NR10SO2R11, —SO2R13— or —ZCH2CH2Q, wherein Z is —O—, —SO2—, —NR12—, —CONH— or —NHCO—, Q represents —OH, C1-C12alkyl, —SO2R13—, —NHR14—, —OCH2CH2OH, —SO2CH2CH2OH or —NHCH2CH2OH, R4 is C1-C12alkyl, R5, R6, R7, R8, R9, R10, R12, R13 and R14 are each independently of the others hydrogen or C1-C12alkyl, and R11 is C1-C122alkyl, with the proviso that at least one of the residues D1 and D2 is a radical of formula (2) wherein R3 is —COOR5, —SO2NR8R9, —SO2R13— or —ZCH2CH2Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibre materials.
    • 本发明涉及式(1)的染料,其中残基D1和D2各自表示式(2)的基团,其中Ar1表示碳环或杂环芳族化合物的四价基团,R 1,R 2和R 3各自为 独立于其它氢,C1-C12烷基,C1-C12烷氧基,卤素,-OH,-CN,-NO2,-CF3,-SO3H,-NHCOR4,-COOR5,-CONR6R7,-SO2NR8R9,-NR10SO2R11,-SO2R13-或 -ZCH 2 CH 2 Q,其中Z是-O - , - SO 2 - , - NR 12 - , - CONH-或-NHCO-,Q表示-OH,C 1 -C 12烷基,-SO 2 R 13 - , - NHR 14 - , - OCH 2 CH 2 OH,-SO 2 CH 2 CH 2 OH或 - NHCH2CH2OH,R4是C1-C12烷基,R5,R6,R7,R8,R9,R10,R12,R13和R14各自独立地是氢或C1-C12烷基,R11是C1-C12-2烷基,条件是至少 残基D1和D2之一是式(2)的基团,其中R3是-COOR5,-SO2NR8R9,-SO2R13-或-ZCH2CH2Q,含有这些染料的二色和三色混合物 e使用这些染料染色或印刷含羟基或含氮纤维材料。