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1. 发明授权

US06509505B1 Phosphabenzene compounds and their use in hydroformylation 失效
标题翻译：膦酸化合物及其在加氢甲酰化中的应用
公开(公告)号：US06509505B1
公开(公告)日：2003-01-21
申请号：US09936346
申请日：2001-09-11
申请人： Rocco Paciello , Thomas Mackewitz , Michael Röper , Bernhard Breit
发明人： Rocco Paciello , Thomas Mackewitz , Michael Röper , Bernhard Breit
IPC分类号： C07F950
CPC分类号： B01J31/2419 , B01J31/2466 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07D309/34 , C07F9/6568 , C07F15/008 , C07C47/02
摘要： Phosphabenzene compounds of the formula (I) where the radicals R1 to R13 are, independently of one another, hydrogen, COOM, SO3M, NR3X, NR2, OR, COOR or SR (where M=hydrogen, NH4 or alkali metal, X=anion, R=hydrogen or C1-C6-alkyl), or C1-C12-alkyl, C6-C12-aryl, C7-C12-aralkyl, C7-C12-alkaryl or C3-C6-heteroaromatics, where the alkyl, aryl, alkaryl and aralkyl radicals may bear the abovementioned radicals as substituents and two or more of the radicals may be joined to form aliphatic or fused-on rings, where at least one of the radicals R4 and R8 and at least one of the radicals R9 and R13 is not hydrogen, can be used for preparing hydroformylation catalysts.
摘要翻译：其中基团R 1至R 13彼此独立地为氢，COOM，SO 3 M，NR 3 X，NR 2，OR，COOR或SR（其中M =氢，NH 4或碱金属，X =阴离子）的式（I）或C 1 -C 12 - 烷基，C 6 -C 12 - 芳基，C 7 -C 12 - 芳烷基，C 7 -C 12烷芳基或C 3 -C 6 - 杂芳族化合物，其中烷基，芳基，烷芳基并且芳烷基可以带有上述基团作为取代基，并且两个或更多个基团可以连接形成脂族或稠合环，其中基团R 4和R 8中的至少一个以及基团R 9和R 13中的至少一个是不是氢，可用于制备加氢甲酰化催化剂。

2. 发明授权

US06255532B1 Method for producing phosphabenzene compounds 失效
标题翻译：膦酸化合物的制备方法
公开(公告)号：US06255532B1
公开(公告)日：2001-07-03
申请号：US09509672
申请日：2000-03-30
申请人： Rocco Paciello , Edgar Zeller , Bernhard Breit , Michael Röper
发明人： Rocco Paciello , Edgar Zeller , Bernhard Breit , Michael Röper
IPC分类号： C07F950
CPC分类号： C07F9/6568 , B01J31/2419 , B01J31/2461 , B01J2231/321 , B01J2531/822 , B01J2531/845
摘要： A process for the preparation of phosphabenzene compounds of the formulae I and II where R1 to R6, independently of one another, are hydrogen, COOM SO3M, NR3X, NR2, OR, COOR or SR, where M is hydrogen, NH4 or an alkali metal, X is an anion, R is hydrogen, C1-6-alkyl, or C1-12-alkyl, C6-12-aryl, C7-12-aralkyl or C3-6-heterocycloalkyl having 1 to 3 heteroatoms which may be substituted by the above radicals or linked to form fused rings, and —W— is a bridge comprising a covalent bond, an oxo group, a sulfur group, an amino group, a di-C1-6-alkylsilicon group or a C1-16-radial, which may be part of one or more linked cyclic or aromatic rings and may be interrupted by 1 to 3 heteroatoms, where the phosphabenzene ring o- or m-position not bonded to the bridge may carry one of the radicals R1 to R6, with the exception of bis-3,3′-(2,4,6-triphenyl-3-phosphabenzene)-1,1-biphenyl, by reacting corresponding pyrilium salts with PH3 in the presence of a catalytic amount of acid and in the presence or absence of a solvent or diluent, where the pyrilium salts are mixed with PH3 at above 0° C. and reacted at from 0° C. to 200° C. and at a pressure greater than 1 bar.
摘要翻译：制备式I和II的膦酸化合物的方法，其中R 1至R 6彼此独立地为氢，COOM SO 3 M，NR 3 X，NR 2，OR，COOR或SR，其中M为氢，NH 4或碱金属， X是阴离子，R是氢，C 1-6 - 烷基或C 1-12 - 烷基，C 6-12 - 芳基，C 7-12 - 芳烷基或具有1至3个杂原子的C 3-6 - 杂环烷基，其可以被并且-W-是包含共价键，氧代基团，硫基团，氨基基团，二-C1-6烷基硅基团或C1-16-放射状核团的桥，其可以是一个或多个连接的环状或芳香环的一部分，并且可以被1至3个杂原子中断，其中未键合到桥的膦酰基环或 - 位置可以携带基团R1至R6中的一个，其中通过使相应的吡啶鎓盐与PH 3在催化量的酸的存在下反应，并在存在或不存在下，将双-3'' - （2,4,6-三苯基-3-苯基苯基）没有溶剂或稀释剂，其中吡啶鎓盐在0℃下与PH3混合，并在0℃至200℃和大于1巴的压力下反应。

3. 发明授权

US07012162B2 Phosphacyclohexanes and the use thereof in the hydroformylation of olefins 失效
标题翻译：磷杂环己烷及其在烯烃加氢甲酰化中的应用
公开(公告)号：US07012162B2
公开(公告)日：2006-03-14
申请号：US10311584
申请日：2001-06-25
申请人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
发明人： Thomas Mackewitz , Wolfgang Ahlers , Edgar Zeller , Michael Röper , Rocco Paciello , Rainer Papp , Konrad Knoll , Hartwig Voss
IPC分类号： C07C45/50 , C07F9/02 , B01J31/00
CPC分类号： B01J31/2466 , B01J31/20 , B01J31/2423 , B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F15/0026 , C07F15/0053 , C07F15/0066 , C07F15/008 , C07F15/045 , C07F15/065 , C07C47/21 , C07C47/02
摘要： The invention relates to phosphacyclohexanes of general formulae I and II, wherein the following designations, among others, apply: R can represent hydrogen, C1-100-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: R1 to R10 can independently represent hydrogen, C1-20-alkyl, C7-20-aralkyl, C7-20-alkaryl, and C6-12-aryl: W, W′ can independently represent single bonds or bridges comprising 1 to 20 carbon atoms, which can form part of a cyclic or aromatic group and can be interrupted by heteroatoms. Said phosphacyclohexanes are used as ligands in transition metal complexes of transition metals belonging to groups VIII to X of the periodic table.
摘要翻译：本发明涉及通式I和II的磷杂环己烷，其中应用以下名称：R可以表示氢，C 1-100 - 烷基，C 7-20〜 C 1 -C 6烷基，C 7-20芳烷基和C 6-12 - 芳基：R 1至R 10， / SUP>可以独立地表示氢，C 1-20 - 烷基，C 7-20-20芳烷基，C 7-20 - 烷芳基，和C 6-12 - 芳基：W，W'可以独立地表示单键或包含1至20个碳原子的桥，其可以形成环状或芳族基团的一部分并且可以被杂原子中断。所述磷杂环己烷用作属于周期表第VIII至X族过渡金属的过渡金属络合物中的配体。

4. 发明授权

US07145042B2 Method for producing dialdehydes and or ethylenically unsaturated monoaldehydes by hydroformylating ethylenically unsaturated compounds 失效
公开(公告)号：US07145042B2
公开(公告)日：2006-12-05
申请号：US10527635
申请日：2003-09-12
申请人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Röper , Thomas Mackewitz , Volker Böhm , Xavier Sava , Oliver Löber , Oliver Bey , Jürgen Stephan , Frank Haese
发明人： Martin Volland , Wolfgang Ahlers , Klaus Ebel , Rocco Paciello , Michael Röper , Thomas Mackewitz , Volker Böhm , Xavier Sava , Oliver Löber , Oliver Bey , Jürgen Stephan , Frank Haese
IPC分类号： C07C45/50
CPC分类号： C07F9/6596 , C07C45/50 , C07F9/572 , C07F9/5728 , C07F9/65522 , C07F9/65586 , C07F9/65842 , C07F9/65848 , C07C47/12 , C07C47/21
摘要： The invention relates to a method for producing dialdehydes and/or ethylenically unsaturated monoaldehydes by reacting at least one compound with at least two ethylenically unsaturated double bonds with carbon monoxide and hydrogen in the presence of a hydroformylating catalyst with at least one complex of a metal of subgroup VIII. The subgroup comprises at least pnicogen chelate ligands.

5. 发明授权

US06252117B1 Preparation of phosphabenzene compounds 失效
标题翻译：膦酸化合物的制备
公开(公告)号：US06252117B1
公开(公告)日：2001-06-26
申请号：US09525064
申请日：2000-03-14
申请人： Thomas Mackewitz , Michael Röper , Bernhard Breit
发明人： Thomas Mackewitz , Michael Röper , Bernhard Breit
IPC分类号： C07F950
CPC分类号： C07F9/6568
摘要： Phosphabenzene compounds of the formulae I and II where R1 to R6 are identical or different and are, for example, hydrogen, are prepared by reacting corresponding pyrylium salts with PH3 in the presence or absence of a solvent or diluent. The pyrylium salts are combined with PH3 at above 0° C. and reacted at a temperature in the range from 0° C. to 200° C. and a pressure above 1 bar without addition of an acid catalyst or a base.
摘要翻译：在存在或不存在溶剂或稀释剂的情况下，通过使相应的吡喃鎓盐与PH 3反应来制备其中R 1至R 6相同或不同且为例如氢的式I和II的亚膦酸化合物。吡喃鎓盐与0℃下的PH 3结合，在0℃至200℃的温度和1巴以上的温度下反应，不加酸催化剂或碱。

6. 发明授权

US06977312B2 Phosphor, arsenic and antimony compounds based upon diaryl-anellated bicyclo[2.2.n] parent substances and catalysts containing same 失效
标题翻译：基于二芳基 - 苯氧基双环[2.2.n]母体物质和含有它们的催化剂的磷光体，砷和锑化合物
公开(公告)号：US06977312B2
公开(公告)日：2005-12-20
申请号：US10203296
申请日：2001-02-09
申请人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
发明人： Wolfgang Ahlers , Michael Röper , Peter Hofmann , Daniel C. M. Warth , Rocco Paciello
IPC分类号： B01J31/16 , B01J31/18 , B01J31/22 , B01J31/24 , C07B37/12 , C07C2/50 , C07C13/44 , C07C13/64 , C07C13/68 , C07C45/50 , C07C51/14 , C07C253/10 , C07F9/46 , C07F9/50 , C07F9/6561 , C07F9/6571 , C07F9/6574 , C07F15/00 , C07F15/04 , C07F15/06 , C08F4/42 , C07F9/02
CPC分类号： C07F9/65746 , B01J31/1658 , B01J31/185 , B01J31/1865 , B01J31/1875 , B01J31/2457 , B01J2231/12 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/543 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/46 , C07F9/5027 , C07F9/6561 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： Novel compounds of phosphorus, of arsenic and of antimony can be used as ligands to form complexes of metals of transition group VIII which can be used in catalysts for hydroformylation, hydrocyanation, carbonylation, hydrogenations, oligomerization and polymerization of olefins and for metathesis.
摘要翻译：可以使用磷，砷和锑的新型化合物作为配体，形成可用于加氢甲酰化，氢化氰化，羰基化，氢化，烯烃低聚和聚合的复合催化剂的过渡基团VIII的金属络合物和复分解。

7. 发明授权

US06486359B1 Catalyst comprising a complex of a metal of subgroup viii based on a phosphinite ligand, and a method for hydroformylation 失效
标题翻译：包含基于磷化物配体的亚基viii金属的络合物的催化剂和加氢甲酰化的方法
公开(公告)号：US06486359B1
公开(公告)日：2002-11-26
申请号：US09719353
申请日：2000-12-12
申请人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
发明人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
IPC分类号： C07C4550
CPC分类号： C07F15/008 , B01J31/1875 , B01J2231/321 , B01J2531/0266 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/657163 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： The invention relates to a catalyst which comprises at least one complex of a metal of group VIII, which comprises at least one uni-, bi- or multidentate phosphinite ligand in which the phosphorus atom and the oxygen atom of the phosphinite group are part of a 5- to 8-membered heterocycle, and to processes for hydroformylation and hydrocyanation of compounds which contain at least one ethylenic double bond in the presence of a catalyst of this type.
摘要翻译：本发明涉及一种催化剂，其包含至少一种第VIII族金属的络合物，其包含至少一种一元，二元或多数的磷化物配位体，其中磷原子和磷酸基团的氧原子是 5至8元杂环，以及在这种催化剂存在下含有至少一个烯属双键的化合物的加氢甲酰化和氢化氰化方法。

8. 发明授权

US06440891B1 Catalyst comprising a complex of a metal of subgroup VIII, on the basis of a phosphonite ligand and method for hydroformylation 有权
标题翻译：基于亚膦酸盐配体和加氢甲酰化方法的含有第VIII族金属络合物的催化剂
公开(公告)号：US06440891B1
公开(公告)日：2002-08-27
申请号：US09623175
申请日：2000-08-29
申请人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer , Wolfgang Siegel
发明人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer , Wolfgang Siegel
IPC分类号： B01J3100
CPC分类号： C07F9/65746 , B01J31/1865 , B01J2231/321 , B01J2531/0266 , B01J2531/80 , B01J2531/821 , B01J2531/822 , B01J2531/845 , C07C45/50 , C07C253/30 , C07F9/65719 , C07C255/17 , C07C47/02
摘要： The catalyst comprises at least one bi- or more highly dentate phosphonite ligand of the general formula I or salts and mixtures thereof and is useful in a process for hydroformylating compounds containing at least one ethylenically unsaturated double bond by reaction with carbon monoxide and hydrogen.
摘要翻译：催化剂包含至少一种具有通式I或其盐及其混合物的高度齿状的亚膦酸酯配体，并且可用于通过与一氧化碳和氢气反应加氢甲酰化含有至少一个烯属不饱和双键的化合物的方法。

9. 发明授权

US06310261B1 Method for the production of aldehydes 失效
标题翻译：醛的生产方法
公开(公告)号：US06310261B1
公开(公告)日：2001-10-30
申请号：US09582780
申请日：2000-07-03
申请人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
发明人： Bernhard Geissler , Michael Röper , Edgar Zeller , Rocco Paciello , Jürgen Decker , Hartwig Voss , Norbert Mahr
IPC分类号： C07C4550
CPC分类号： C08G73/0206 , B01J31/1658 , B01J31/1805 , B01J2231/321 , B01J2531/80 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
摘要翻译：本发明涉及通过在均匀溶解在含有元素周期表第Ⅷa族金属的反应混合物的络合催化剂存在下烯烃的加氢甲酰化生产醛或醛和醇的方法，在50至100℃的温度和20至1,000巴的压力下适合于络合物形成配位体的多余的多齿氮化合物，并且在加氢甲酰基化反应中再循环催化剂配合物，其中a）使用基本上不相容的衍生的多胺，水溶性且适合于络合物形成，并且具有大于1,000道尔顿和至少10个氮原子的平均分子量; b）一旦加氢甲酰化反应和通过蒸馏醛和醇的分离或部分分离已经被残留在蒸馏塔底部的催化剂络合物和从反应混合物中得到的过量配体在加氢甲酰化反应中被全部或部分再循环完成 c）然后执行从反应混合物的蒸馏底部继续或至少间歇抽出高锅炉的至少一部分。

10. 发明授权

US06225507B1 Method of preparing aldehydes by hydroformylation with a rhodium catalyst and recovery of the rhodium catalyst by extraction 失效
标题翻译：通过用铑催化剂加氢甲酰化制备醛的方法，并通过萃取回收铑催化剂
公开(公告)号：US06225507B1
公开(公告)日：2001-05-01
申请号：US09117662
申请日：1998-08-04
申请人： Bernhard Giessler , Heinz-Josef Kneuper , Michael Röper , Rocco Paciello , Knut Oppenländer , Wolfgang Günther
发明人： Bernhard Giessler , Heinz-Josef Kneuper , Michael Röper , Rocco Paciello , Knut Oppenländer , Wolfgang Günther
IPC分类号： C07C4550
CPC分类号： B01J31/20 , B01J31/1658 , B01J31/4046 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07F9/3817 , C08G73/0206 , Y02P20/584 , C07C47/02
摘要： A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.
摘要翻译：一种通过加氢甲酰化含有多于3个碳原子的烯烃制备醛或醛和醇的方法，包括加氢甲酰化阶段，其中烯烃在50至1000巴的压力和50℃的温度下加氢甲酰化通过溶解在均匀的反应介质中的铑催化剂和催化剂回收阶段，包括用螯合剂的水溶液萃取铑催化剂，从提取的加氢甲酰化产物蒸汽中分离出醇和/或醛，在50至1000巴的压力和50至180℃的温度下，在一氧化碳，合成气或含有一氧化碳的气体混合物存在下，含铑水溶液提取物的预羰基化，分离的预羰化阶段的流出物进入含有主要部分铑的有机相和含有螯合剂的水相并将有机相再循环到加氢甲酰化阶段，其中使用不含磺酸基团的能够螯合铑的水溶性聚合物的水溶液从加氢甲酰化阶段的流出物中提取铑催化剂。

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