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1. 发明授权

US06835855B2 Metal complex carrying a 2-phospa-tricyclo[3.3.1.1(3.7)]decyl radical as a ligand in hydroformylation 失效
标题翻译：在加氢甲酰化中携带2-磷杂三环[3.3.1.1（3.7）]癸基作为配体的金属络合物
公开(公告)号：US06835855B2
公开(公告)日：2004-12-28
申请号：US10275562
申请日：2002-11-07
申请人： Wolfgang Ahlers
发明人： Wolfgang Ahlers
IPC分类号： C07C4550
CPC分类号： C07F15/008 , B01J31/1845 , B01J31/2485 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C45/50 , C07C47/02
摘要： In a process for the hydroformylation of ethylenically unsaturated compounds, at least one ethylenically unsaturated compound is reacted with carbon monoxide and hydrogen in the presence of a ligand-metal complex of ruthenium, rhodium, palladium, iridium and/or platinum, where the ligand-metal complex comprises a monophosphine, monophosphinite or monophosphinamidite ligand of the formula I where A together with the phosphorus atom to which it is bound forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical in which one or more nonadjacent carbon atoms may be replaced by heteroatoms and which may be substituted, and R′ is hydrogen or an organic radical having a molecular weight of up to 20 000 bound via a carbon atom or oxygen atom or nitrogen atom. The process is particularly useful for the hydroformylation of internal branched olefins and lower pressures and/or temperatures are required in the hydroformylation than when using other phosphorus ligands.

2. 发明授权

US06583324B2 Process for producing aldehyde 有权
公开(公告)号：US06583324B2
公开(公告)日：2003-06-24
申请号：US09954171
申请日：2001-09-18
申请人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
发明人： Masaki Takai , Iwao Nakajima , Tooru Tsukahara , Yoshiyuki Tanaka , Hisao Urata , Akio Nakanishi
IPC分类号： C07C4550
CPC分类号： C07F9/025 , B01J31/185 , B01J2231/321 , B01J2531/822 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for producing an aldehyde, which comprises a reaction step of producing an aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in the presence of a rhodium complex catalyst comprising at least rhodium and an organic phosphite in a reaction zone, a separation step of obtaining a catalyst solution containing the rhodium complex catalyst by separating the aldehyde from a reaction solution taken from the reaction zone, and a recycling step of recycling the catalyst solution into the reaction zone, wherein the aldehyde is separated from the reaction solution in such a manner as to make an aldehyde concentration from 0.5 to 99 wt % in the catalyst solution.

3. 发明授权

US06365783B1 Process for producing alcohols 有权
标题翻译：醇的制备方法
公开(公告)号：US06365783B1
公开(公告)日：2002-04-02
申请号：US09577981
申请日：2000-05-25
申请人： Yorozu Yokomori , Tsukasa Hayashi , Toshiaki Ogata , Junichi Yamada , Seiji Saito
发明人： Yorozu Yokomori , Tsukasa Hayashi , Toshiaki Ogata , Junichi Yamada , Seiji Saito
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C29/16 , C07C31/125 , C07C47/02
摘要： Provided is a process for producing alcohols or aldehydes by reacting monoolefins with carbon monoxide and hydrogen with less formation of by-products. The process comprises the step of reacting a monoolefin with carbon monoxide and hydrogen in the presence of a cobalt carbonyl catalyst until the conversion of monoolefin reaches 50-90% (the first reaction step), the step of separating unreacted monoolefin from the reaction mixture obtained in the first reaction step (the step of separation of unreacted monoolefin) and the step of reacting the separated unreacted monoolefin with carbon monoxide and hydrogen in the presence of a cobalt carbonyl catalyst (the second reaction step), wherein at least one of the first reaction step and the second reaction step is carried out in the presence of water.
摘要翻译：提供了通过使单烯烃与一氧化碳和氢气反应而形成副产物而生产醇或醛的方法。该方法包括在羰基钴催化剂存在下使单烯烃与一氧化碳和氢气反应的步骤，直到单烯烃的转化率达到50-90％（第一反应步骤），从获得的反应混合物中分离未反应的单烯烃的步骤在第一反应步骤（分离未反应的单烯烃的步骤）和在羰基钴催化剂（第二反应步骤）的存在下使分离的未反应的单烯烃与一氧化碳和氢气反应的步骤，其中第一反应步骤和第二反应步骤在水的存在下进行。

4. 发明授权

US06274773B1 Process for the continuous preparation of alkyl 5-formylvalerate compounds using homogeneous rhodium hydroformylation catalysts 失效
标题翻译：使用均相铑加氢甲酰化催化剂连续制备5-甲酰基戊酸烷基酯化合物的方法
公开(公告)号：US06274773B1
公开(公告)日：2001-08-14
申请号：US09304668
申请日：1999-05-04
申请人： Onko J. Gelling , Peter C. Borman
发明人： Onko J. Gelling , Peter C. Borman
IPC分类号： C07C4550
CPC分类号： C07C67/347 , C07C69/716
摘要： Process for the continuous preparation of an alkyl 5-formylvalerate by reacting an alkyl-3-pentenoate with carbon monoxide and hydrogen by hydroformylation using a catalyst system comprising rhodium or iridium and a multidentate organic phosphite ligand according to the general formula: in which n is 2-6, X is an n-valent organic bridging group, and in which the end groups R1-R2 are monovalent aryl groups, wherein the process is carried out in the presence of an acid compound having a pKa between 1 and 12 measured in water at 18° C.
摘要翻译：通过使用包含铑或铱的催化剂体系和根据通式的多齿有机亚磷酸酯配体通过加氢甲酰化反应使3-戊烯酸烷基酯与一氧化碳和氢气反应来连续制备5-甲酰基烷基烷基的方法：其中n是 2-6，X是n价有机桥连基团，其中端基R1-R2是一价芳基，其中该方法在pKa在1和12之间的酸化合物存在下进行，其在 18°C水

5. 发明授权

US06252121B1 Metal-ligand complex catalyzed processes 有权
标题翻译：金属 - 配体络合物催化方法
公开(公告)号：US06252121B1
公开(公告)日：2001-06-26
申请号：US09361907
申请日：1999-07-27
申请人： John Nicholas Argyropoulos , David Robert Bryant , Michael Leo Tulchinsky , Jeffrey Scott Kanel , Paul Foley , Barry Brent Fish
发明人： John Nicholas Argyropoulos , David Robert Bryant , Michael Leo Tulchinsky , Jeffrey Scott Kanel , Paul Foley , Barry Brent Fish
IPC分类号： C07C4550
CPC分类号： C07B63/00 , B33Y40/00 , B33Y70/00 , C07B2200/09 , C07C29/141 , C07C45/49 , C07C45/50 , C07C45/78 , C07C45/80 , C07C47/32 , C07C209/26 , C07C253/30 , C07C2601/14 , Y02P20/582 , C07C47/347 , C07C47/36 , C07C31/276
摘要： This invention relates to a process for separating one or more cyclic products from a reaction product fluid comprising one or more cyclic reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, a non-polar solvent and said one or more cyclic products, wherein said process comprises: (1) reacting said one or more cyclic reactants in the presence of said metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and non-polar solvent to form a multiphase reaction product fluid; and (2) separating said multiphase reaction product fluid to obtain a non-polar phase comprising said one or more cyclic reactants, metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand and non-polar solvent and a polar phase comprising said one or more cyclic products.
摘要翻译：本发明涉及从包含一种或多种环状反应物，金属 - 有机磷配位体配合物催化剂，任选的游离有机磷配体，非极性溶剂和所述一种或多种环状产物的反应产物流体中分离一种或多种环状产物的方法其中所述方法包括：（1）在所述金属 - 有机磷配体配合物催化剂，任选的游离有机磷配体和非极性溶剂的存在下使所述一种或多种环状反应物反应以形成多相反应产物流体; 和（2）分离所述多相反应产物流体以获得包含所述一种或多种环状反应物，金属 - 有机磷配体络合物催化剂，任选的游离有机磷配体和非极性溶剂的非极性相和包含所述一种或多种循环产品。

6. 发明授权

US06777579B2 Hydroformylation process 有权
标题翻译：加氢甲酰化过程
公开(公告)号：US06777579B2
公开(公告)日：2004-08-17
申请号：US10294320
申请日：2002-11-14
申请人： Peter Arnoldy , Robert Hardy Ellison , Herman Pieter Charles Eduard Kuipers , Robert Moene , Frederik Hendrik Van Der Steen
发明人： Peter Arnoldy , Robert Hardy Ellison , Herman Pieter Charles Eduard Kuipers , Robert Moene , Frederik Hendrik Van Der Steen
IPC分类号： C07C4550
CPC分类号： C07C45/50 , B01J31/20 , B01J31/24 , B01J2531/845 , C07C29/16 , C07C2601/08 , C07C31/125 , C07C31/36 , C07C31/135 , C07C33/20 , C07C47/02
摘要： A hydroformylation process is provided that involves reacting a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of a cobalt catalyst and a sulfur-containing additive which suppresses the formation of cobalt carbide in the reaction mixture.
摘要翻译：提供加氢甲酰化方法，其包括在钴催化剂和含硫添加剂的存在下使具有至少一个烯烃碳 - 碳键的化合物与氢气和一氧化碳反应，所述添加剂抑制反应混合物中碳化钴的形成。

7. 发明授权

US06753450B2 Process for the preparation of aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US06753450B2
公开(公告)日：2004-06-22
申请号：US10275563
申请日：2002-11-07
申请人： Wolfgang Ahlers , Michael Slany
发明人： Wolfgang Ahlers , Michael Slany
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C47/02
摘要： The invention relates to a process for the preparation of aldehydes in which at least one compound containing a vinyl or vinylidene group is reacted with carbon monoxide and hydrogen in the presence of a source of a metal from sub-group VIII and in the presence of a bidentate diphosphine ligand, where the diphosphine ligand has the general formula I in which A together with the phosphorus atom to which it is bonded, in each case forms a 2-phosphatricyclo[3.3.1.1{3,7}]decyl radical, in which one or more non-adjacent carbon atoms may be replaced by oxygen atoms and which is substituted or unsubstituted, and X is a bridging chain having 1 to 10 carbon atoms, and the molar ratio between the diphosphine ligand and the metal is at least 5. The process gives predominantly n-aldehydes.
摘要翻译：本发明涉及一种制备醛的方法，其中至少一种含有乙烯基或亚乙烯基的化合物与来自第VIII族的金属源存在下的一氧化碳和氢气反应，二膦配体，其中二膦配体具有通式Iin，其中A与其键合的磷原子一起形成2-磷酸三环[3.3.1.1 {3,7}]癸基，其中一个或更多的不相邻的碳原子可以被氧原子取代并且是取代或未被取代的，X是具有1-10个碳原子的桥连链，二膦配体和金属之间的摩尔比至少为5.该方法给出主要是正醛。

8. 发明授权

US06486359B1 Catalyst comprising a complex of a metal of subgroup viii based on a phosphinite ligand, and a method for hydroformylation 失效
标题翻译：包含基于磷化物配体的亚基viii金属的络合物的催化剂和加氢甲酰化的方法
公开(公告)号：US06486359B1
公开(公告)日：2002-11-26
申请号：US09719353
申请日：2000-12-12
申请人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
发明人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
IPC分类号： C07C4550
CPC分类号： C07F15/008 , B01J31/1875 , B01J2231/321 , B01J2531/0266 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/657163 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： The invention relates to a catalyst which comprises at least one complex of a metal of group VIII, which comprises at least one uni-, bi- or multidentate phosphinite ligand in which the phosphorus atom and the oxygen atom of the phosphinite group are part of a 5- to 8-membered heterocycle, and to processes for hydroformylation and hydrocyanation of compounds which contain at least one ethylenic double bond in the presence of a catalyst of this type.
摘要翻译：本发明涉及一种催化剂，其包含至少一种第VIII族金属的络合物，其包含至少一种一元，二元或多数的磷化物配位体，其中磷原子和磷酸基团的氧原子是 5至8元杂环，以及在这种催化剂存在下含有至少一个烯属双键的化合物的加氢甲酰化和氢化氰化方法。

9. 发明授权

US06420611B1 Composition comprising polymeric phosphite 失效
标题翻译：含有聚亚磷酸盐的组合物
公开(公告)号：US06420611B1
公开(公告)日：2002-07-16
申请号：US09399634
申请日：1999-09-20
申请人： Wilson Tam , Kathryn Eileen Schwierbert
发明人： Wilson Tam , Kathryn Eileen Schwierbert
IPC分类号： C07C4550
CPC分类号： C08G63/6924 , B01J31/06 , B01J31/1658 , B01J31/185 , B01J31/28 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/827 , B01J2531/828 , C07C45/50 , C07C67/347 , C07C253/30 , C07F9/145 , C08G63/692 , C07C69/716 , C07C255/17 , C07C47/02
摘要： A composition comprising a Group VIII metal and a phosphite-containing polymer having repeat units derived from (1) a carbonyl compound, a monomer, and phosphochloridite; (2) phosphorus trichloride, a polyhydric alcohol, and an aromatic diol; or (3) combinations of (1) and (2).
摘要翻译：包含VIII族金属和含有衍生自（1）羰基化合物，单体和磷酸亚铁的重复单元的含亚磷酸酯的聚合物的组合物; （2）三氯化磷，多元醇和芳族二醇; 或（3）（1）和（2）的组合。

10. 发明授权

US06403837B1 Process for the catalytic preparation of aldehydes from olefins using ligand mixtures 失效
标题翻译：使用配体混合物从烯烃催化制备醛的方法
公开(公告)号：US06403837B1
公开(公告)日：2002-06-11
申请号：US09708624
申请日：2000-11-09
申请人： Dieter Hess , Dirk Roettger , Detlef Selent , Armin Boerner
发明人： Dieter Hess , Dirk Roettger , Detlef Selent , Armin Boerner
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C47/02
摘要： A process for preparing aldehydes having from 4 to 25 carbon atoms by catalytic hydroformylation of the corresponding olefins, wherein the catalyst used comprises a metal of transition group 8 of the Periodic Table in the presence of a ligand A of the formula I where X=As, Sb or P and R1,R2,R3: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where two of the radicals R1, R2, R3 can be covalently linked with the proviso that at least one of the hydrocarbon radicals R1, R2, R3 contains a heteroatom selected from the group consisting of O, S, N, F, Cl, Be, I, Se and Te, and a ligand B of the formula II where R4, R5, R6: are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon having from 1 to 50 carbon atoms, where two of the radicals R4, R5 and R6 can be covalently linked.
摘要翻译：通过相应烯烃的催化加氢甲酰化制备具有4至25个碳原子的醛的方法，其中所用的催化剂包括在式I的配体A的存在下的周期表的过渡族8的金属，其中X = As，Sb 或P和R 1，R 2，R 3：各自是具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃基，其中基团R 1，R 2，R 3中的两个可以共价连接，条件是至少一个的烃基R1，R2，R3含有选自O，S，N，F，Cl，Be，I，Se和Te的杂原子和式II的配体B，其中R4，R5，R6：各自为具有1至50个碳原子的取代或未取代的脂族，脂环族或芳族烃，其中基团R 4，R 5和R 6中的两个可以共价连接。

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