会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 5. 发明授权
    • Method for producing phosphabenzene compounds
    • 膦酸化合物的制备方法
    • US06255532B1
    • 2001-07-03
    • US09509672
    • 2000-03-30
    • Rocco PacielloEdgar ZellerBernhard BreitMichael Röper
    • Rocco PacielloEdgar ZellerBernhard BreitMichael Röper
    • C07F950
    • C07F9/6568B01J31/2419B01J31/2461B01J2231/321B01J2531/822B01J2531/845
    • A process for the preparation of phosphabenzene compounds of the formulae I and II where R1 to R6, independently of one another, are hydrogen, COOM SO3M, NR3X, NR2, OR, COOR or SR, where M is hydrogen, NH4 or an alkali metal, X is an anion, R is hydrogen, C1-6-alkyl, or C1-12-alkyl, C6-12-aryl, C7-12-aralkyl or C3-6-heterocycloalkyl having 1 to 3 heteroatoms which may be substituted by the above radicals or linked to form fused rings, and —W— is a bridge comprising a covalent bond, an oxo group, a sulfur group, an amino group, a di-C1-6-alkylsilicon group or a C1-16-radial, which may be part of one or more linked cyclic or aromatic rings and may be interrupted by 1 to 3 heteroatoms, where the phosphabenzene ring o- or m-position not bonded to the bridge may carry one of the radicals R1 to R6, with the exception of bis-3,3′-(2,4,6-triphenyl-3-phosphabenzene)-1,1-biphenyl, by reacting corresponding pyrilium salts with PH3 in the presence of a catalytic amount of acid and in the presence or absence of a solvent or diluent, where the pyrilium salts are mixed with PH3 at above 0° C. and reacted at from 0° C. to 200° C. and at a pressure greater than 1 bar.
    • 制备式I和II的膦酸化合物的方法,其中R 1至R 6彼此独立地为氢,COOM SO 3 M,NR 3 X,NR 2,OR,COOR或SR,其中M为氢,NH 4或碱金属, X是阴离子,R是氢,C 1-6 - 烷基或C 1-12 - 烷基,C 6-12 - 芳基,C 7-12 - 芳烷基或具有1至3个杂原子的C 3-6 - 杂环烷基,其可以被 并且-W-是包含共价键,氧代基团,硫基团,氨基基团,二-C1-6烷基硅基团或C1-16-放射状核团的桥, 其可以是一个或多个连接的环状或芳香环的一部分,并且可以被1至3个杂原子中断,其中未键合到桥的膦酰基环或 - 位置可以携带基团R1至R6中的一个,其中 通过使相应的吡啶鎓盐与PH 3在催化量的酸的存在下反应,并在存在或不存在下,将双-3'' - (2,4,6-三苯基-3-苯基苯基) 没有溶剂或稀释剂,其中吡啶鎓盐在0℃下与PH3混合,并在0℃至200℃和大于1巴的压力下反应。
    • 8. 发明授权
    • Method for the production of aldehydes
    • 醛的生产方法
    • US06310261B1
    • 2001-10-30
    • US09582780
    • 2000-07-03
    • Bernhard GeisslerMichael RöperEdgar ZellerRocco PacielloJürgen DeckerHartwig VossNorbert Mahr
    • Bernhard GeisslerMichael RöperEdgar ZellerRocco PacielloJürgen DeckerHartwig VossNorbert Mahr
    • C07C4550
    • C08G73/0206B01J31/1658B01J31/1805B01J2231/321B01J2531/80B01J2531/822C07C45/50Y02P20/584C07C47/02
    • The invention relates to a method for the production of aldehydes or aldehydes and alcohols by hydroformylation of olefins in the presence of a complexing catalyst homogeneously dissolved in a reaction mixture, containing a metal of Group VIIIa of the periodic table of the elements and a phosphorus-free, polydentate nitrogen compound suitable for complex formation as ligand at temperatures ranging from 50 to 100° C. and pressures from 20 to 1,000 bar and recirculating the catalyst complex in the hydroformylation reaction, wherein a) derivatized polyamines are used that are substantially non-water soluble and suitable for complex formation and have a mean molecular weight of more than 1,000 Dalton and at least 10 nitrogen atoms; b) the catalyst complex remaining in the bottom of the distillation column and the excess ligands obtained from the reaction mixture are recirculated totally or partially in the hydroformylation once the hydroformylation reaction and the separation or partial separation by distillation of the aldehydes and the alcohols has been completed; c) continues or at least batchwise evacuation of at least part of the high boiler from the bottom of the distillation of the reaction mixture is then carried out.
    • 本发明涉及通过在均匀溶解在含有元素周期表第Ⅷa族金属的反应混合物的络合催化剂存在下烯烃的加氢甲酰化生产醛或醛和醇的方法, 在50至100℃的温度和20至1,000巴的压力下适合于络合物形成配位体的多余的多齿氮化合物,并且在加氢甲酰基化反应中再循环催化剂配合物,其中a)使用基本上不相容的衍生的多胺, 水溶性且适合于络合物形成,并且具有大于1,000道尔顿和至少10个氮原子的平均分子量; b)一旦加氢甲酰化反应和通过蒸馏醛和醇的分离或部分分离已经被残留在蒸馏塔底部的催化剂络合物和从反应混合物中得到的过量配体在加氢甲酰化反应中被全部或部分再循环 完成 c)然后执行从反应混合物的蒸馏底部继续或至少间歇抽出高锅炉的至少一部分。
    • 9. 发明授权
    • Method of preparing aldehydes by hydroformylation with a rhodium catalyst and recovery of the rhodium catalyst by extraction
    • 通过用铑催化剂加氢甲酰化制备醛的方法,并通过萃取回收铑催化剂
    • US06225507B1
    • 2001-05-01
    • US09117662
    • 1998-08-04
    • Bernhard GiesslerHeinz-Josef KneuperMichael RöperRocco PacielloKnut OppenländerWolfgang Günther
    • Bernhard GiesslerHeinz-Josef KneuperMichael RöperRocco PacielloKnut OppenländerWolfgang Günther
    • C07C4550
    • B01J31/20B01J31/1658B01J31/4046B01J2231/321B01J2531/822C07C45/50C07F9/3817C08G73/0206Y02P20/584C07C47/02
    • A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.
    • 一种通过加氢甲酰化含有多于3个碳原子的烯烃制备醛或醛和醇的方法,包括加氢甲酰化阶段,其中烯烃在50至1000巴的压力和50℃的温度下加氢甲酰化 通过溶解在均匀的反应介质中的铑催化剂和催化剂回收阶段,包括用螯合剂的水溶液萃取铑催化剂,从提取的加氢甲酰化产物蒸汽中分离出醇和/或醛, 在50至1000巴的压力和50至180℃的温度下,在一氧化碳,合成气或含有一氧化碳的气体混合物存在下,含铑水溶液提取物的预羰基化,分离 的预羰化阶段的流出物进入含有主要部分铑的有机相和含有螯合剂的水相 并将有机相再循环到加氢甲酰化阶段,其中使用不含磺酸基团的能够螯合铑的水溶性聚合物的水溶液从加氢甲酰化阶段的流出物中提取铑催化剂。