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1. 发明授权

US4529788A Process for preparing novel graft polymer 失效
标题翻译：制备新型接枝聚合物的方法
公开(公告)号：US4529788A
公开(公告)日：1985-07-16
申请号：US550072
申请日：1983-11-08
申请人： Masahiro Asami , Kiyoshi Okitsu , Yoshiaki Okumura , Hajime Namikoshi , Masatoshi Mikumo , Shoji Watanabe
发明人： Masahiro Asami , Kiyoshi Okitsu , Yoshiaki Okumura , Hajime Namikoshi , Masatoshi Mikumo , Shoji Watanabe
IPC分类号： C08L1/00 , C08B15/00 , C08G63/00 , C08G63/08 , C08G63/82 , C08G63/10
CPC分类号： C08G63/00
摘要： A process for preparing a graft polymer by subjecting a cyclic ester to ring-opening polymerization in the presence of a cellulose derivative in the presence of a ring-opening polymerization catalyst for the cyclic ester. The resulting graft polymer has high transparency, good film-formability and high solubility and can be suitably used as a novel polymer material.
摘要翻译：在环酯的开环聚合催化剂存在下，在纤维素衍生物的存在下使环酯进行开环聚合来制备接枝聚合物的方法。所得到的接枝聚合物具有高透明度，良好的成膜性和高溶解性，可适用于新颖的聚合物材料。

2. 发明授权

US4417025A Resin composition emulsion 失效
标题翻译：树脂组合物乳液
公开(公告)号：US4417025A
公开(公告)日：1983-11-22
申请号：US337335
申请日：1982-01-06
申请人： Hirotaka Toba , Masatoshi Mikumo , Masahiro Asami
发明人： Hirotaka Toba , Masatoshi Mikumo , Masahiro Asami
IPC分类号： C08F2/24 , C08F251/02 , C08G59/02 , C08L1/08
CPC分类号： C08F251/02
摘要： A resin composition is prepared by emulsion-polymerizing a cellulose ester and at least one radical-polymerizable unsaturated monomer in the aqueous medium under the presence of a dispersion stabilizer, said cellulose ester having been modified by chemically bonding thereonto a polymeric chain compatible with a polymer obtained from said radical-polymerizable unsaturated monomer.
摘要翻译：通过在分散稳定剂的存在下在水性介质中将纤维素酯和至少一种可自由基聚合的不饱和单体进行乳液聚合来制备树脂组合物，所述纤维素酯已经通过化学键合在与聚合物相容的聚合物链上进行改性由所述可自由基聚合的不饱和单体获得。

3. 发明授权

US4521565A Aqueous dispersion 失效
标题翻译：水分散体
公开(公告)号：US4521565A
公开(公告)日：1985-06-04
申请号：US521866
申请日：1983-08-10
申请人： Hirotaka Toaba , Masatoshi Mikumo , Masahiro Asami
发明人： Hirotaka Toaba , Masatoshi Mikumo , Masahiro Asami
IPC分类号： C08F2/20 , C08F2/24 , C08F2/44 , C08F251/02 , C09D151/02 , C08G59/02
CPC分类号： C08F251/02 , C08F2/20 , C09D151/02
摘要： A cellulose derivative-containing aqueous dispersion which is obtained by polymerizing a mixture of a cellulose derivative, at least one radical-polymerizable unsaturated monomer capable of dissolving the cellulose derivative therein and water under radical polymerization conditions, said aqueous dispersion containing as a dispersion stabilizer a water-soluble or water-dispersible polymer in which polymeric chain group compatible with the polymer obtained said radical-polymerizable unsaturated monomer is chemically bonded onto a hydrophilic polymeric chain group.
摘要翻译：一种含纤维素衍生物的水性分散体，其通过在自由基聚合条件下使纤维素衍生物，能够溶解纤维素衍生物的至少一种可自由基聚合的不饱和单体和水的混合物聚合而获得，所述水分散体含有分散稳定剂a 水溶性或水分散性聚合物，其中与获得的所述可自由基聚合的不饱和单体相容的聚合物链基团化学键合到亲水性聚合物链基团上。

4. 发明授权

US4415703A Aqueous dispersion of a cellulose derivative 失效
标题翻译：纤维素衍生物的水分散体
公开(公告)号：US4415703A
公开(公告)日：1983-11-15
申请号：US337336
申请日：1982-01-06
申请人： Hirotaka Toba , Masatoshi Mikumo , Masahiro Asami
发明人： Hirotaka Toba , Masatoshi Mikumo , Masahiro Asami
IPC分类号： C08F2/20 , C08F2/24 , C08F2/44 , C08F251/02 , C09D151/02 , C08L1/08 , C08G59/02
CPC分类号： C08F251/02 , C08F2/20 , C09D151/02
摘要： A cellulose derivative-containing aqueous dispersion which is obtained by polymerizing a mixture of a cellulose derivative, at least one radical-polymerizable unsaturated monomer capable of dissolving the cellulose derivative therein and water under radical polymerization conditions, said aqueous dispersion containing as a dispersion stabilizer a water-soluble or water-dispersible polymer in which polymeric chain group compatible with the polymer obtained said radical-polymerizable unsaturated monomer is chemically bonded onto a hydrophilic polymeric chain group.
摘要翻译：一种含纤维素衍生物的水性分散体，其通过在自由基聚合条件下使纤维素衍生物，能够溶解纤维素衍生物的至少一种可自由基聚合的不饱和单体和水的混合物聚合而获得，所述水分散体含有分散稳定剂a 水溶性或水分散性聚合物，其中与获得的所述可自由基聚合的不饱和单体相容的聚合物链基团化学键合到亲水性聚合物链基团上。

5. 发明授权

US06890705B2 Silver halide photosensitive material and image-forming method using same 失效
标题翻译：卤化银感光材料和使用它的成像方法
公开(公告)号：US06890705B2
公开(公告)日：2005-05-10
申请号：US10152629
申请日：2002-05-23
申请人： Kiyoteru Miyake , Masahiro Asami
发明人： Kiyoteru Miyake , Masahiro Asami
IPC分类号： G03C7/407 , G03C1/035 , G03C1/09 , G03C1/34 , G03C1/42 , G03C1/498 , G03C7/392 , G03C7/46 , G03C1/00 , G03C5/16
CPC分类号： G03C1/49818 , G03C1/09 , G03C1/49809 , G03C1/49881 , G03C2001/0055 , G03C2001/03517 , G03C2001/03564 , G03C2001/098 , G03C2200/01 , G03C2200/03 , G03C2200/60
摘要： The second silver halide photosensitive material comprises a substrate and at least one photosensitive silver halide emulsion layer formed thereon, the silver halide photosensitive material comprising at least two types of silver halide grains with different projected areas having photosensitivity in the same spectral range; silver halide grains having a larger projected area having a refractive index n1 and an average thickness a, and silver halide grains having a smaller projected area having a refractive index n2 and an average thickness b; and the silver halide grains satisfying the conditions defined by the following equation (1): n2≦n1, and a≦b×(n2/n1) (1).
摘要翻译：第二卤化银感光材料包括基材和在其上形成的至少一种感光卤化银乳剂层，所述卤化银感光材料包含具有相同光谱范围内具有光敏性的不同投影面积的至少两种类型的卤化银颗粒; 具有折射率n1较大的投影面积和平均厚度a的卤化银颗粒和具有折射率n2和平均厚度b的较小投影面积的卤化银颗粒; 并且满足以下等式（1）定义的条件的卤化银颗粒：<？in-line-formula description =“In-line formula”end =“lead”？> n2 <= N1，ANDa <= Bx（n2 / n1）（1）。 <？in-line-formula description =“In-line Formulas”end =“tail”？>

6. 发明授权

US06335154B1 Silver halide photographic emulsion and light-sensitive material containing the same, and image-forming method using the light-sensitive material 失效
标题翻译：卤化银照相乳剂和含有相同的感光材料，以及使用感光材料的成像方法
公开(公告)号：US06335154B1
公开(公告)日：2002-01-01
申请号：US09533326
申请日：2000-03-22
申请人： Masahiro Asami , Makoto Kikuchi , Tadanobu Sato
发明人： Masahiro Asami , Makoto Kikuchi , Tadanobu Sato
IPC分类号： G03C1035
CPC分类号： G03C1/08 , G03C1/0051 , G03C1/42 , G03C8/4013 , G03C8/404 , G03C2001/0056 , G03C2200/43
摘要： There is disclosed a silver halide photographic emulsion comprising silver halide grains, wherein 50% or more of the projected area of the silver halide grains to be contained is occupied by tabular grains having an aspect ratio of 2 or more and a grain thickness of 0.2 &mgr;m or less, with the tabular grains each having a phase with the content of silver bromide being 10% or more, and wherein in the phase, the tabular grains each contain a metal complex dopant in an amount necessary to increase the density of a dislocation. This emulsion produces high contrast and better granularity while it has high sensitivity. Further, there is also disclosed a silver halide photographic emulsion, wherein the average equivalent-circle diameter of the total tabular grains among the silver halide grains contained is 2.0 to 4.0 &mgr;m, and the tabular grains contain at least one metal complex having, as a ligand, a heterocyclic compound in a number more than half of the coordination number of the metal atom. This emulsion has high sensitivity and excellent photographic characteristics exhibiting little change of gradation upon exposure to high-intensity illumination. In addition, the present invention provides a silver halide color photographic light-sensitive material using the emulsion, and a color image forming process that is simple and rapid and places little load on the environment, using the material.
摘要翻译：公开了包含卤化银颗粒的卤化银照相乳剂，其中待包含的卤化银颗粒的投影面积的50％或更多占据纵横比为2以上且颗粒厚度为0.2μm的片状颗粒或更少，其中每个具有相对于溴化银含量为10％以上的相的片状颗粒，并且其中在该相中，片状颗粒各自含有以增加位错密度所需的量的金属络合物掺杂剂。该乳液具有高对比度和更好的粒度，同时具有高灵敏度。此外，还公开了一种卤化银照相乳剂，其中包含的卤化银颗粒中的总片状颗粒的平均当量圆直径为2.0至4.0μm，并且片状颗粒含有至少一种金属络合物，其具有配体，杂环化合物的数目多于金属原子配位数的一半以上。该乳液具有高灵敏度和优异的照相特性，在暴露于高强度照明时表现出很小的灰度变化。此外，本发明提供一种使用该乳液的卤化银彩色摄影感光材料，以及使用该材料，简单快速并且对环境施加极小负荷的彩色图像形成工艺。

7. 发明授权

US5478707A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US5478707A
公开(公告)日：1995-12-26
申请号：US240619
申请日：1994-05-11
申请人： Masahiro Asami
发明人： Masahiro Asami
IPC分类号： G03C1/015 , G03C1/035 , G03C1/07 , G03C7/30 , G03C7/392 , G03C1/815 , G03C1/005 , G03C1/09
CPC分类号： G03C7/39216 , G03C1/035 , G03C1/07 , G03C7/3022 , Y10S430/132
摘要： There is disclosed a silver halide photographic light-sensitive which is capable of providing a rapid processing as well as a high sensitivity and in which a change in an aging time in exposing through processing provides less performance fluctuation and therefore an excellent stability. The silver halide photographic light-sensitive material comprises a support and provided thereon at least one light-sensitive silver halide emulsion layer and at least one non-light-sensitive layer, wherein at least one of the above light-sensitive emulsion layers contains a silver halide emulsion grain which comprises silver bromochloride having a silver chloride content of 90% or more or silver chloride each containing substantially no silver iodide and in which 50% or more of a grain surface consists of a (111) plane; and further, at least one of the non-light-sensitive layers contains a compound represented by the following Formula (I): ##STR1## wherein X represents a hydrogen atom, a hydroxyl group, an amino group, or a sulfonamido group; R.sup.11 and R.sup.12 each represent the same group as that defined for X, an alkyl group, an aryl group, an amido group, a ureido group, an alkylthio group, an arylthio group, an alkoxy group, or an aryloxy group, and R.sup.11 and R.sup.12 may cooperate to form a carbon ring or a heterocyle; when X is a hydrogen atom, R.sup.11 represents a hydroxyl group, an amino group, or a sulfonamido group; R.sup.13 represents a hydrogen atom, a halogen atom, a sulfo group, a carboxyl group, an alkyl group, an acyl group, an oxycarbonyl group, a carbamoyl group, a sulfonyl group, or a sulfamoyl group; and, the compound represented by Formula (I) has a molecular weight of 390 or more.
摘要翻译：公开了一种能够提供快速加工和高灵敏度的卤化银照相感光性，其中通过处理曝光的老化时间的变化提供较少的性能波动并因此具有优异的稳定性。卤化银照相感光材料包括载体并且在其上提供至少一种感光卤化银乳剂层和至少一种非感光层，其中至少一种上述感光乳剂层含有银卤化银乳剂颗粒，其包含氯化银含量为90％以上的溴氯化银或各自基本上不含碘化银的氯化银，其中50％以上的颗粒表面由（111）面组成; 另外，至少一个非感光层含有由下式（I）表示的化合物：其中X表示氢原子，羟基，氨基或亚磺酰氨基组; R 11和R 12各自表示与X，烷基，芳基，酰胺基，脲基，烷硫基，芳硫基，烷氧基或芳氧基所定义的基团相同的基团，R 11和 R12可以配合形成碳环或杂环; 当X是氢原子时，R11表示羟基，氨基或亚磺酰氨基; R 13表示氢原子，卤素原子，磺基，羧基，烷基，酰基，氧羰基，氨基甲酰基，磺酰基或氨磺酰基。式（I）表示的化合物的分子量为390以上。

8. 发明授权

US5230995A Method of manufacturing silver halide emulsion and a color photographic material having the emulsion manufactured by the method 失效
标题翻译：制备卤化银乳剂的方法和具有通过该方法制造的乳液的彩色照相材料
公开(公告)号：US5230995A
公开(公告)日：1993-07-27
申请号：US691277
申请日：1991-04-25
申请人： Masahiro Asami
发明人： Masahiro Asami
IPC分类号： G03C1/015 , G03C1/12 , G03C1/29
CPC分类号： G03C1/015 , G03C1/12 , G03C1/29
摘要： In a method of manufacturing a silver halide emulsion which comprises a silver chlorobromide having a silver chloride content of 90 mol% or more or silver chloride and said silver halide containing substantially no silver iodide, the improvement which comprises the steps of,(i) adding to a reactor a compound capable of spectrally sensitizing the silver halide emulsion in a wavelength range between 590 nm and 720 nm, and(ii) then adding to the reactor a compound capable of spectrally sensitizing the silver halide emulsion in a wavelength range between 390 nm and 590 nm,prior to the completion of chemical sensitization of the silver halide emulsion, and color photographic material having the emulsion manufactured by the method.
摘要翻译：在制备卤化银乳剂的方法中，其包含氯化银氯化物含量为90摩尔％以上的氯化银或氯化银，所述卤化银基本上不含碘化银，其改进包括以下步骤：（i）加入向反应器提供能够在590nm至720nm波长范围内对卤化银乳剂进行光谱增感的化合物，和（ii）然后向反应器中加入能够在390nm波长范围内对卤化银乳剂进行光谱增感的化合物在完成卤化银乳剂的化学增感之前和590nm，以及具有通过该方法制造的乳液的彩色照相材料。

9. 发明授权

US4865962A Photographic light-sensitive material and method of developing the same 失效
标题翻译：摄影感光材料及其开发方法
公开(公告)号：US4865962A
公开(公告)日：1989-09-12
申请号：US138162
申请日：1987-12-28
申请人： Kazunori Hasebe , Masahiro Asami , Naoto Ohshima , Keisuke Shiba , Toshihiro Nishikawa , Kei Sakanoue , Akira Abe
发明人： Kazunori Hasebe , Masahiro Asami , Naoto Ohshima , Keisuke Shiba , Toshihiro Nishikawa , Kei Sakanoue , Akira Abe
IPC分类号： G03C1/08 , G03C1/015 , G03C1/035 , G03C1/07 , G03C1/09 , G03C1/12 , G03C1/22 , G03C5/29 , G03C7/30
CPC分类号： G03C1/015 , G03C1/035 , G03C1/09 , G03C5/29 , G03C7/3022 , G03C1/07 , G03C1/12 , G03C2001/0153 , G03C2001/03517 , G03C2001/03523 , G03C2001/03576 , G03C2001/091 , G03C2001/095 , G03C2001/348 , G03C2200/38
摘要： A photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, characterized in that the emulsion layer contains silver chlorobromide prepared in such a manner that silver halide regular crystal grains, having no twinning crystal plane and containing 50 mol % or more of silver chloride, are used as host grains, an organic compound is adsorbed on a surface of each of the host grains, and sulfur-plus-gold sensitization is performed, either during or after halide conversion in the presence of a bromide.

10. 发明授权

US4555468A Photosensitive diazonium material with precoat of graft polymer prepared by grafting cellulose derivation with radical polymerizable monomer 失效
标题翻译：通过用自由基聚合单体接枝纤维素衍生物制备的具有接枝聚合物预涂层的光敏重氮材料
公开(公告)号：US4555468A
公开(公告)日：1985-11-26
申请号：US605727
申请日：1984-05-01
申请人： Takashi Yano , Masahiro Asami
发明人： Takashi Yano , Masahiro Asami
IPC分类号： C08F251/02 , G03C1/60 , G03C1/80 , G03C1/76
CPC分类号： G03C1/60 , C08F251/02
摘要： A photosensitive material of the diazonium type which comprises a support, a precoat layer thereon and a photosensitive layer of a diazonium compound is improved by using a graft copolymer on a cellulose derivative as the precoat layer. A hydrophilic epoxy compound may be used in the precoat layer and a coupler and a benzenediazonium hexafluorophosphate derivative may be used in the photosensitive layer.
摘要翻译：通过在纤维素衍生物上使用接枝共聚物作为预涂层，改善了包含载体，其上的预涂层和重氮化合物的感光层的重氮型感光材料。可以在预涂层中使用亲水性环氧化合物，并且可以在感光层中使用偶联剂和苯二氮六氟磷酸盐衍生物。

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