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    • 2. 发明授权
    • Cyan coupler dispersion with increased activity
    • 青色成色剂分散体具有增加的活性
    • US06680165B1
    • 2004-01-20
    • US10279892
    • 2002-10-24
    • Jerrold N. PoslusnyPaul B. MerkelDavid A. SteeleDrake M. MichnoDavid S. RossRichard K. RothrockPaul L. Zengerle
    • Jerrold N. PoslusnyPaul B. MerkelDavid A. SteeleDrake M. MichnoDavid S. RossRichard K. RothrockPaul L. Zengerle
    • G03C108
    • G03C7/3006G03C7/342G03C7/346G03C7/3885G03C7/39216
    • The invention provides a color negative photographic element comprising a light sensitive silver halide emulsion imaging layer having associated therewith a cyan dye-forming coupler dispersion comprising a first 2-ureido-5-acylamino substituted phenolic cyan dye-forming coupler [P], a second phenolic cyan dye-forming coupler [AP] where the 2-substituent is other than an ureido group, a substantially non-color-developable phenolic activator compound [ACT], and a non-phenolic organic coupler solvent having a boiling point of at least 150C; wherein compounds represented by [P], [AP], and [ACT] are present in the coupler dispersion in relative weight fractions of from 0.30 to 0.65 for [P], from 0.15 to 0.35 for [AP], and from 0.15 to 0.35 for [ACT], provided the sum of the relative weight fractions for [P]+[AP]+[ACT]=1, and the weight ratio of the non-phenolic coupler solvent in the coupler dispersion is from 0.30 to 2.0 relative to the sum of [P]+[AP]+[ACT]. Photographic elements incorporating the dispersion formulation of this invention provide good activity, a cyan dye of high density and acceptable absorption maximum for color negative films. In addition, partial substitution of less expensive cyan auxiliary phenolic coupler [AP] and activator [ACT] for cyan phenolic coupler [P] advantageously allows cost savings.
    • 本发明提供了一种彩色底片照相材料,其包含光敏卤化银乳剂成像层,其具有与其形成青色染料的成色剂分散体,其包含第一个2-脲基-5-酰基氨基取代的苯酚青色染料成色剂[P],第二个 酚类青色染料形成成色剂[AP],其中2-取代基不是脲基,基本上不显色的酚类活化剂化合物[ACT]和至少具有沸点的非酚类有机成色剂溶剂 150C; 其中由[P],[AP]和[ACT]表示的化合物在[P]为0.30〜0.65,[AP]为0.15〜0.35,0.15〜0.35的相对重量分数存在于成色剂分散体中 对于[ACT],只要[P] + [AP] + [ACT] = 1的相对重量分数之和,耦合剂分散体中非酚类成色剂溶剂的重量比相对于 [P] + [AP] + [ACT]的总和。 结合本发明的分散体制剂的摄影元件提供了良好的活性,对于彩色底片,高密度和可接受的吸收最大值的青色染料。 另外,青色酚类偶联剂[P]的较便宜的青色辅助酚醛偶合剂[AP]和活化剂[ACT]的部分取代有利于节约成本。
    • 4. 发明授权
    • Photographic elements containing blend of cyan dye-forming couplers
    • 含有青色染料成色剂的混合物的照相元件
    • US06261755B1
    • 2001-07-17
    • US09514632
    • 2000-02-28
    • Danuta GibsonJames S. HonanThomas A. Rosiek
    • Danuta GibsonJames S. HonanThomas A. Rosiek
    • G03C108
    • G03C7/342G03C1/34G03C1/815G03C7/3006G03C7/3212G03C7/34G03C7/3885G03C7/39216G03C7/39256
    • The invention provides a photographic element comprising at least one light-sensitive silver halide emulsion layer having associated therewith: (A) a phenolic cyan dye-forming narrow bandwidth “NB coupler”; (B) a phenolic cyan dye-forming coupler of formula (II): wherein: R3 is an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; R4 is an unsubstituted or substituted alkyl group; R5 is hydrogen, halogen or an unsubstituted or substituted alkyl or aryl group or a 5-10 membered heterocyclic ring which contains one or more heteroatoms selected from nitrogen, oxygen and sulfur, which ring is unsubstituted or substituted; and Z is a hydrogen atom or a group which can be split off by the reaction of the coupler with an oxidized color-developing agent; and (C) a stabilizer of formula (III) wherein: each Y is an independently selected substituent and m is 0 to 4; and each T is an independently selected substituent and p is 0 to 4. Preferably the element has associated therewith one or more high-boiling solvents of formula (IV) wherein: R1 is an unsubstituted or substituted alkyl or aryl group; and G is an unsubstituted or substituted alkyl group.
    • 本发明提供了一种照相元件,其包含至少一种与之相关的感光卤化银乳剂层:(A)形成苯酚青色染料的窄带宽“NB成色剂”;(B)式(B)的酚青色染料成色剂 II):其中:R3是未取代或取代的烷基或芳基或含有一个或多个选自氮,氧和硫的杂原子的5-10元杂环,该环是未取代或取代的; R4是未取代或取代的 烷基; R5是氢,卤素或未取代或取代的烷基或芳基或含有一个或多个选自氮,氧和硫的杂原子的5-10元杂环,该环是未取代的或被取代的; Z为氢原子或可通过偶合剂与氧化显色剂的反应而分离的基团; 和(C)式(III)的稳定剂,其中:每个Y是独立选择的取代基,m是0-4; 所述T是独立选择的取代基,p是0至4.优选所述元素与一种或多种式(Ⅳ)的高沸点溶剂缔合,其中:R 1为未取代或取代的烷基或芳基; G是未取代或取代的烷基。
    • 5. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US06171774B2
    • 2001-01-09
    • US09189194
    • 1998-11-09
    • Kunimasa HiyamaKazuhiro Murai
    • Kunimasa HiyamaKazuhiro Murai
    • G03C108
    • G03C7/3013G03C1/385G03C7/367G03C7/39216G03C7/396
    • A silver halide photographic light sensitive material is disclosed. The light-sensitive material comprises a support having thereon a yellow dye image-forming emulsion layer, a magenta dye image-forming emulsion layer, and a cyan dye image-forming emulsion layer and optionally a light-insensitive layer, in which said yellow image-forming emulsion layer contains a yellow dye-forming coupler represented by Formula I and an organic solvent-soluble polymer, and a light-sensitive or light-insensitive layer each adjoined to the yellow image forming emulsion layer contains a polymer which have a constituting unit represented by Formula II; wherein RA is an alkyl group or a cycloalkyl group, RB is a halogen atom or an alkoxy group, RC is a group capable of being a substituent of the benzene group, m is an integer of from 0 to 40, and Z is a releasing group;
    • 公开了一种卤化银照相感光材料。 感光材料包括其上具有黄色染料影像形成乳剂层,品红染料影像形成乳剂层和青色染料影像形成乳剂层以及可选的不透光层的支持体,其中所述黄色图像 形成乳剂层含有由式I表示的黄色染料成色剂和有机溶剂可溶性聚合物,并且与黄色图像形成乳剂层相邻的感光或光不敏感层含有具有构成单元的聚合物 由式II表示;其中RA是烷基或环烷基,RB是卤素原子或烷氧基,RC是能够作为苯基的取代基的基团,m是0-40的整数, Z是释放组;
    • 6. 发明授权
    • Color photographic recording material
    • 彩色摄影材料
    • US6015654A
    • 2000-01-18
    • US20610
    • 1998-02-09
    • Jorg HagemannSiegfried Dzwonnek
    • Jorg HagemannSiegfried Dzwonnek
    • C07C271/28C07C275/40G03C7/30G03C7/38G03C7/392G03C7/333
    • C07C271/28C07C275/40G03C7/39236G03C2200/29G03C7/3008G03C7/3825G03C7/39216
    • A color photographic recording material which contains, on a support, at least one blue-sensitive silver halide emulsion layer with which a yellow coupler is associated, at least one green-sensitive silver halide emulsion layer with which a magenta coupler is associated, and at least one red-sensitive silver halide emulsion layer with which a cyan coupler is associated, as well as light-insensitive intermediate layers between the layers of different coloor-sensitivity, characterised in that it contains a pyrazolotriazole coupler as a magenta coupler in at least one green-sensitive silver halide emulsion layer, and in at least one of said layers it contains, as a DOP scavenger, a compound of formula I ##STR1## wherein X.sub.1,X.sub.2 represent a single bond, --O-- or --NR.sub.7 --,R.sub.1 represents hydrogen or a group which can split off under the conditions of chromogenic development,R.sub.2 represents hydrogen or --CO--X.sub.1 --R.sub.4,R.sub.3 represents hydrogen or --CO--X.sub.2 --R.sub.5,R.sub.4, R.sub.5 represent hydrogen, alkyl, alkenyl or a heterocyclic group,R.sub.6 represents alkyl, aryl, acyl, alkoxy, aryloxy, acyloxy, halogen, --OH, --COOM, --SO.sub.3 M, --CN or --NO.sub.2,R.sub.7 represents hydrogen, alkyl, aryl or acyl,M represents hydrogen or a cation, andn represents 0, 1, 2 or 3and wherein at least one R.sub.2 or R.sub.3 substituent is hydrogen,is distinguished by its improved stability under the effect of light.
    • 一种彩色照相记录材料,其在载体上含有与黄色成色剂结合的至少一个感蓝卤化银乳剂层,至少一种与品红成色剂相关的感绿卤化银乳剂层和 至少一个红色感光卤化银乳剂层,青色成色剂与其相关联,以及不同感光度敏感层之间的不透光中间层,其特征在于,它含有至少一种作为品红色成色剂的吡唑并三唑成色剂 绿敏感的卤化银乳剂层,并且在至少一个所述层中,它含有作为DOP清除剂的式I化合物,其中X 1,X 2表示单键,-O-或-NR 7 - ,R 1表示氢或 在显色条件下可以分离的基团,R 2表示氢或-CO-X 1 -R 4,R 3表示氢或-CO-X 2 -R 5,R 4,R 5表示氢,烷基,烯基或杂环 基团,R 6表示烷基,芳基,酰基,烷氧基,芳氧基,酰氧基,卤素,-OH,-COOM,-SO 3 M,-CN或-NO 2,R 7表示氢,烷基,芳基或酰基,M表示氢或阳离子, 并且n表示0,1,2或3,并且其中至少一个R 2或R 3取代基是氢,其特征在于其在光的作用下的改进的稳定性。
    • 8. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5538842A
    • 1996-07-23
    • US268976
    • 1994-06-30
    • Osamu TakahashiTakehiko Sato
    • Osamu TakahashiTakehiko Sato
    • G03C7/38G03C7/30G03C7/392G03C1/08G03C7/26G03C7/32
    • G03C7/301G03C7/3008G03C7/3022G03C7/39216Y10S430/132
    • There is disclosed a silver halide color photographic light-sensitive material which excels in a color reproduction and a light fastness at a low density part through a high density part and which is improved in a Y-stain at a background part. The silver halide color photographic light-sensitive material comprises a support and provided thereon at least one photographic constitutional layer, wherein at least one layer of the above photographic constitutional layers contains at least one of the compounds represented by the following Formula (I) and a compound represented by the following Formula (II) in the same layer: ##STR1## wherein R represents a hydrogen atom or a substituent; Z.sub.a, Z.sub.b, and Z.sub.c each represent any group of methine, substituted methine, .dbd.N--, or --NH--; Y represents a hydrogen atom or a group capable of splitting off upon a coupling reaction with an oxidation product of a developing agent; provided that a dimer or a polymer may be formed via R, Y, or Z.sub.a, Z.sub.b or Z.sub.c when each is a substituted methine: ##STR2## wherein X and Y each represent a hydrogen atom, an alkyl group, an alkoxy group, or an acyl group; Z represents --CO-- or --COO--; and m, l and p each represent an integer of 1 to 4.
    • 公开了一种卤化银彩色摄影感光材料,其通过高密度部分在低密度部分的色彩再现性和耐光性优异,并且在背景部分的Y染色改善。 卤化银彩色摄影感光材料包括一个支撑体,并在其上提供至少一个照相构成层,其中至少一层上述照相构成层含有至少一种由下式(I)表示的化合物和 在同一层中由下式(II)表示的化合物:其中R表示氢原子或取代基的式(I) Za,Zb和Zc各自表示任何次甲基,取代的次甲基,= N-或-NH-的任一组; Y表示氢原子或能够与显影剂的氧化产物偶联反应时分解的基团; 条件是当各自为取代的次甲基时,可以通过R,Y或Za,Zb或Zc形成二聚体或聚合物:其中X和Y各自表示氢原子,烷基, 烷氧基或酰基; Z表示-CO-或-COO-; m,l和p分别表示1〜4的整数。
    • 10. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US5380631A
    • 1995-01-10
    • US2465
    • 1993-01-08
    • Yasushi NozawaNobuo SetoNobutaka OhkiMasayoshi Toyoda
    • Yasushi NozawaNobuo SetoNobutaka OhkiMasayoshi Toyoda
    • G03C1/035G03C1/18G03C1/34G03C7/305G03C7/333G03C7/392G03C1/46
    • G03C7/3335G03C7/305G03C7/39216Y10S430/158
    • A silver halide color photographic light-sensitive material having at least one negative silver halide emulsion layer on a support, wherein the silver halide color photographic light-sensitive material contains at least one type of a compound which reacts with the oxidized form of a developing agent to release a development inhibitor or a precursor of a development inhibitor and/or at least one type of a compound which cleaves after reacting with the oxidized form of a color developing agent, the cleaved compound of which in turn reacts with another molecule of the oxidized form of a color developing agent to cleave a development inhibitor, and contains at least one type of a compound selected from Formulas (A) and (B) below. In Formulas (A) and (B), each of R.sub.a1 to R.sub.a5 and R.sub.b1 to R.sub.b5 represents a hydrogen atom, an alkyl group or other groups. R.sub.a1 to R.sub.a5 are not simultaneously hydrogen atoms, and one or two of R.sub.b2 to R.sub.b5 are hydroxyl groups. ##STR1##
    • 一种卤化银彩色照相感光材料,其在载体上具有至少一个负卤化银乳剂层,其中所述卤化银彩色照相感光材料含有至少一种与氧化形式的显影剂反应的化合物 释放开发抑制剂或显影抑制剂的前体和/或至少一种类型的化合物,其与氧化形式的显色剂反应后裂解,其中切割的化合物又与另一分子的氧化的 形成显色剂以切割显影抑制剂,并含有至少一种选自下式(A)和(B)的化合物。 在式(A)和(B)中,Ra1〜Ra5和Rb1〜Rb5各自表示氢原子,烷基或其它基团。 Ra1〜Ra5不同时为氢原子,Rb2〜Rb5中的一个或两个为羟基。 公式(A)公式(B)