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    • 10. 发明授权
    • Silver halide emulsion
    • 卤化银乳剂
    • US5807665A
    • 1998-09-15
    • US630335
    • 1996-04-10
    • Mitsuo Saitou
    • Mitsuo Saitou
    • G03C1/005G03C1/015G03C1/04G03C1/07G03C1/053G03C1/035
    • G03C1/0051G03C1/015G03C1/04G03C1/07
    • A silver halide emulsion is disclosed, comprising at least a dispersing medium and silver halide grains, wherein at least 60% of the total projected area of silver halide grains is occupied by tabular grains having a crystal defect for anisotropic growth which have a {100} face as a main plane and an aspect ratio (diameter/thickness ratio) of not less than 2.0, and the right-angled parallelogram enclosed with {100} faces at the edges of the tabular grains or a right-angled parallelogram formed by extending the {100} faces at the edges having a slenderness side ratio (a ratio of the length of the long side to that of the short side) of 1 to 6; and said silver halide emulsion is prepared in the presence of a compound A.sup.0 and/or a compound B.sup.0, wherein the compound A.sup.0 represents an organic compound having covalently bonded to an individual molecule thereof at least two molecules of an adsorbable agent which accelerates formation of a {100} face of silver bromide grains, and the compound B.sup.0 represents an organic compound except gelatin having at least four alcoholic groups per molecule, both the compounds A.sup.0 and B.sup.0 are organic compounds except gelatin and other proteins. The emulsion is excellent in sensitivity, image quality and preservability.
    • 公开了一种卤化银乳剂,其包含至少一种分散介质和卤化银颗粒,其中卤化银颗粒的总投影面积的至少60%由具有{100}的各向异性生长的晶体缺陷的片状颗粒占据, 作为主平面和纵横比(直径/厚度比)不小于2.0,并且由{100}包围的直角平行四边形面在片状颗粒的边缘或通过延伸形成的直角平行四边形 {100}在具有长径比(长边与短边的长度的比)的边缘处面对1至6; 并且所述卤化银乳剂在化合物A0和/或化合物B0的存在下制备,其中化合物A0表示与其各自分子共价键合的至少两个分子的可吸附剂的分解,其加速形成 {100}表面的溴化银颗粒,化合物B0表示除了每分子具有至少四个醇基的明胶之外的有机化合物,化合物A0和B0都是除明胶和其他蛋白质之外的有机化合物。 该乳液的灵敏度,图像质量和保存性都很好。