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    • 8. 发明授权
    • Methine dyes, manufacturing methods thereof, and silver halide photographic materials containing same dyes
    • 甲基染料,其制造方法和含有相同染料的卤化银照相材料
    • US06884891B2
    • 2005-04-26
    • US10192590
    • 2002-07-11
    • Katsumi Kobayashi
    • Katsumi Kobayashi
    • C07D263/56C07D277/64C07D417/14C09B23/00C09B23/01C09B23/02C09B23/10G03C1/12
    • C07D263/56C07D277/64C07D417/14C09B23/0066C09B23/0083C09B23/02C09B23/10G03C1/12
    • Methine dye compounds represented by formula (1) and highly sensitive silver halide photographic materials containing these compounds: Dye1-(L1-(Dye2)m1)m2 (CI1)y1  (1) wherein L1 represents a linkage group represented by formula (2), m1 represents an integer of 1 to 5, m2 represents an integer of 1 to 5, Dye1 represents a first chromophore, Dye 2 represents a second chromophore, CI1 represents an ion for neutralization of electric charge, and y1 represents a number of the ions required for neutralization of electric charges; -G1-A1-Y1-G2-Y2-A2-G3-  (2) wherein A1 and A2 each individually represent a carbonyl group or a sulfonyl group, Y1 and Y2 each individually represent —O—, —S— or —NR1—, R1 represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group, and G1, G2 and G3 each individually represent a divalent linkage group.
    • 由式(1)表示的甲基染料化合物和含有这些化合物的高灵敏度卤化银照相材料:<?in-line-formula description =“In-line Formulas”end =“lead”→Dye1-(L 1 (1)(1)&lt;&lt; 1&gt;(1)&lt; -line-formula description =“In-line Formulas”end =“tail”?>其中L 1表示由式(2)表示的连接基团,m1表示1〜5的整数,m 2 表示1〜5的整数,染料1表示第一发色团,染料2表示第二发色团,CI 1表示用于中和电荷的离子,y1表示中和所需的离子数 的电费; <?in-line-formula description =“In-line Formulas”end =“lead”?> - G <1> 1 - (2)<α-2 2 line-formula description =“In-line Formulas”end =“tail”?>其中A 1和A 2各自各自表示羰基或磺酰基,Y 1个和Y 2个各自各自独立地表示-O - , - S-或-NR 1 - , - R 1, 表示氢原子,烷基,烯基,芳基或杂环基,G 1,G 2和G 3 >各自独立地表示二价连接基团。
    • 10. 发明申请
    • Silver halide photographic material
    • 卤化银照相材料
    • US20040038159A1
    • 2004-02-26
    • US10251841
    • 2002-09-23
    • FUJI PHOTO FILM CO., LTD.
    • Tetsuo Nakamura
    • G03C001/16G03C001/18G03C007/32
    • G03C7/301G03C1/12G03C7/38
    • A silver halide photographic material comprising at least one methine dye of formula (I) and at least one coupler of formula (X): 1 wherein X1 and X2 each represents O, S, Se, Te, N or C; Y1 represents a furan, pyrrole or thiophene ring which may be condensed and substituted with the specific ring; Y2 represents an atomic group necessary for forming a benzene ring or a 5- or 6-membered unsaturated heterocycle; R1 and R2 each represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; L1, L2 and L3 each represents a methine group; n1 represents 0 or 1; M1 represents a counter ion; and m1 represents a number of 0 or more necessary for neutralizing a charge in a molecule; 2 wherein Z1 and Z2 each represents nullC(Q3)null or nullNnull; Q1 and Q3 each represents a hydrogen atom or a monovalent substituent group; Q2 represents a hydrogen atom or a coupling release group.
    • 一种卤化银照相材料,其包含至少一种式(I)的次甲基染料和至少一种式(X)的成色剂:其中X 1和X 2各自表示O,S,Se,Te,N或C ; Y 1表示呋喃,吡咯或噻吩环,其可被稠合并用特定的环取代; Y 2表示形成苯环或5-或6-元不饱和杂环所必需的原子团; R 1和R 2各自表示取代或未取代的烷基,芳基或杂环基; L 1,L 2和L 3各自表示次甲基; n 1表示0或1; M 1表示抗衡离子; m 1表示中和分子中的电荷所需的0以上的数; 其中Z 1和Z 2各自表示-C(Q 3)=或-N =; Q 1和Q 3各自表示氢原子或一价取代基; Q 2表示氢原子或偶联离解基团。