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1. 发明申请

US20180237547A1 WHITE POLYMER DISPERSION 审中-公开
公开(公告)号：US20180237547A1
公开(公告)日：2018-08-23
申请号：US15753649
申请日：2016-08-19
申请人： BASF SE
发明人： Nico VELING , Dirk LAWRENZ , Stefan WEBER , Peter WACHTLER
IPC分类号： C08F2/20 , C08F236/10 , C08F220/18 , C08L3/02 , C08L9/06 , C08F8/04
CPC分类号： C08F2/20 , C08F8/04 , C08F220/18 , C08F236/10 , C08F251/02 , C08F2800/20 , C08L3/02 , C08L9/06 , C09D4/00 , C09D103/02 , C09D151/02 , C09J4/00 , C09J103/02 , C09J151/02 , D21H17/28 , D21H19/54 , C08F212/08 , C08F220/06 , C08F222/02 , C08F236/06 , C08F2220/1825
摘要： The present invention refers to a process for the preparation of an aqueous polymer dispersion, an aqueous polymer dispersion obtained by the process, a binder, an adhesive, a size suitable for at least one fiber, a covering, or a paper coating slip, comprising the aqueous polymer dispersion as well as the use of the aqueous polymer dispersion for the preparation of a binder, an adhesive, a size suitable for at least one type of fiber, a paint, a covering, or a paper coating slip.

2. 发明申请

US20180118867A1 ELLIPTICAL, NEEDLE-SHAPED, OR ROD-SHAPED CROSSLINKED POLYMER PARTICLES, AND USE THEREOF 审中-公开
公开(公告)号：US20180118867A1
公开(公告)日：2018-05-03
申请号：US15571907
申请日：2016-05-02
申请人： Nisshinbo Holdings Inc.
发明人： Kazutoshi Hayakawa , Toshifumi Hashiba , Erina Matsuzaka
IPC分类号： C08F220/14 , C09D133/12 , C09D11/107 , A61K8/02 , A61K8/81 , A61Q19/00 , C09J133/12 , C08F212/08 , C09D125/14 , C09D11/108 , C09J125/14
CPC分类号： C08F220/14 , A61K8/0245 , A61K8/8152 , A61Q1/02 , A61Q19/00 , C08F212/08 , C08F2500/24 , C08F2800/20 , C08F2810/20 , C08L2205/025 , C09D11/107 , C09D11/108 , C09D125/14 , C09D129/04 , C09D133/12 , C09J125/14 , C09J133/12 , G02B5/0242 , C08L33/12 , C08F2220/325 , C08F2/26 , C08F2/20 , C08F220/56
摘要： Provided are elliptical, needle-shaped, or rod-shaped crosslinked polymer particles in which 5-100 mol % of all repeating units are repeating units derived from an unsaturated monomer having a functional group selected from an epoxy group, a carboxyl group, an amide group, a hydroxy group an amino group, and a thiol group, wherein (1) the average (LAV) length (L) in a two-dimensional projection diagram obtained by irradiating the particles with light from a direction orthogonal to the longitudinal direction is 0.1-80 μm, (2) the average (DAV) breadth (D) in the two-dimensional projection diagram obtained by irradiating, the particles with light from the direction orthogonal to the longitudinal direction is 0.05-40 μm, and (3) the average (PAV) aspect ratio (L/D) calculated from the length (L) and the breadth (D) is 1.5-30.

3. 发明授权

US09957407B2 Use of a polymer dispersion for cold sealing 有权
公开(公告)号：US09957407B2
公开(公告)日：2018-05-01
申请号：US14766807
申请日：2014-03-17
申请人： BASF SE
发明人： Andrea Kuntz , Karl-Heinz Schumacher , Christoph Kiener
IPC分类号： C09D133/14 , B05D3/00 , C08F2/20 , C08F2/24 , C09J133/14 , C09J7/02
CPC分类号： C09D133/14 , B05D3/007 , C08F2/20 , C08F2/24 , C09J7/20 , C09J133/14 , C08F2220/1808 , C08F218/08 , C08F220/14 , C08F220/36
摘要： A description is given of the use of a polymer dispersion for cold sealing, the polymer dispersion comprising a polymer in dispersion in water and having a glass transition temperature in the range from −20 to +10° C., said polymer being preparable by emulsion polymerization of radically polymerizable monomers in the presence of at least one polymeric protective colloid, and the polymer being formed to an extent of 0.05 to less than 1 wt % of a monomer M, selected from the group consisting of (meth)acrylate monomers having a substituent of the formula where X is CH2, O, NH or NR, and R is a C1 to C4 alkyl group. Descriptions are also given of a method for producing cold-sealed packaging, and of the packaging obtainable by said method.

4. 发明申请

US20180112118A1 Oil-Phase-free Triple-Play Slick Water Concentration System with Effects of Synergistically Reducing Drag, Assisting Drainage and Promoting Clay Stabilization 审中-公开
公开(公告)号：US20180112118A1
公开(公告)日：2018-04-26
申请号：US15792735
申请日：2017-10-24
申请人： Yangtze University
发明人： Jun Wu , Wei-Chu Yu
IPC分类号： C09K8/05 , C09K8/584 , C09K8/88 , C08F2/06 , C11D1/00 , B01F17/00
CPC分类号： C09K8/05 , B01F17/0035 , C08F2/06 , C08F2/20 , C08F2/44 , C09K8/18 , C09K8/584 , C09K8/68 , C09K8/88 , C09K8/882 , C09K2208/12 , C09K2208/28 , C11D1/004 , C08F220/56 , C08F220/06
摘要： An oil-phase-free triple-play slick water concentration system, is characterized by first synthesizing a water-soluble dispersion polymer drag reducer A; and then preparing an inorganic salt solution B, under mechanical agitation, of high-performance water-soluble fluorocarbon surfactant and a water-soluble of high-performance small molecule or macromolecule clay stabilizer containing quaternary ammonium ions; and finally, the aqueous inorganic salt solution B is slowly added to the drag reducer dispersion A, wherein the ratio of the aqueous inorganic salt solution B and the dispersion A is 20-80:80-20.

5. 发明授权

US09944737B2 Suspensions in aqueous media 有权
公开(公告)号：US09944737B2
公开(公告)日：2018-04-17
申请号：US15537441
申请日：2015-12-15
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： Matthew D. Reichert , Alfred K. Schultz , Andrew M. Savo , Steven Rosenberg , Ralph C. Even , Lester H. Mcintosh, III , Robert Johnson , John David Finch , Decai Yu
IPC分类号： C08F2/18 , C08F2/20 , C08F212/08
CPC分类号： C08F212/08 , C08F2/18 , C08F2/20 , C08F12/08 , C08F212/36
摘要： Provided is a method of suspension polymerization comprising (i) providing a suspension of liquid droplets in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble vinyl monomers, and (b) a polyelectrolyte (PED) having a polarity, (c) one or more initiators, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED), (ii) polymerizing said vinyl monomer or allowing said vinyl monomer to polymerize.

6. 发明申请

US20170369600A1 SUSPENSIONS IN AQUEOUS MEDIA 有权
公开(公告)号：US20170369600A1
公开(公告)日：2017-12-28
申请号：US15536735
申请日：2015-12-15
申请人： Rohm and Haas Company , Dow Global Technologies LLC
发明人： Matthew D. Reichert , Alfred K. Schultz , Andrew M. Savo , Steven Rosenberg , Ralph C. Even , Lester H. Mcintosh, III , Robert Johnson , John David Finch , Decai Yu
IPC分类号： C08F2/20 , C08F212/36 , C08F212/08 , C08J3/07 , C08F12/08
CPC分类号： C08F2/20 , C08F2/18 , C08F12/08 , C08F212/08 , C08F212/36 , C08J3/07
摘要： Provided is a suspension comprising liquid droplets dispersed in an aqueous medium, wherein said droplets comprise (a) one or more water-insoluble compounds, and (b) a vinyl polyelectrolyte (PED) having a polarity, and wherein said aqueous medium comprises a polyelectrolyte (PEW) having a polarity that is opposite to the polarity of said polyelectrolyte (PED). Also provided are a method of making such a suspension and a method using such a suspension in a process of suspension polymerization.

7. 发明申请

US20170349680A1 Method for Preparing Polyvinyl Chloride by Suspension and Polymerization, and Feeding Device 审中-公开
公开(公告)号：US20170349680A1
公开(公告)日：2017-12-07
申请号：US15533605
申请日：2015-02-11
申请人： Qingdao Amos Resource and Technology Co., Ltd.
发明人： Yuhai GAO , Xianzhen ZHUO
IPC分类号： C08F114/06 , B01J4/00
CPC分类号： C08F114/06 , B01J4/00 , B01J4/001 , C08F2/01 , C08F2/20 , C08F14/06
摘要： The present invention provides a production method of polyvinyl chloride by suspension polymerization and a feeding apparatus. This method comprises: Step 1: injecting a vinyl chloride monomer and water at 25-98° C. into a reaction vessel to obtain a water suspension, closing the reaction kettle, repeatedly and cyclically performing vacuum-pumping and cleansing with nitrogen, stirring and evacuating oxygen in the reaction kettle; Step 2: adding a first suspension agent and a second suspension agent into the reaction kettle, and then adding a nanopowder and an initiator composite, to carry out the polymerization reaction; Step 3: adding cold water to terminate the polymerization reaction upon the pressure in the reaction kettle is reduced to 3.5 bar or less; Step 4: evacuating and vacuumizing the reaction kettle, and then filtering, washing and drying the resulted polymer, to obtain polyvinyl chloride. The present invention also provides a feeding apparatus used for the above production method. Polyvinyl chloride produced by the method of this invention has good performance and can meet the requirements of physical and chemical properties and applicability for most applications.

8. 发明授权

US09650455B2 Dispersion stabilizer for suspension polymerization and method for producing vinyl resin 有权
公开(公告)号：US09650455B2
公开(公告)日：2017-05-16
申请号：US14910582
申请日：2014-08-06
申请人： KURARAY CO., LTD.
发明人： Tadahito Fukuhara , Yosuke Kumaki
IPC分类号： C08F116/06 , C08F2/20 , C08F8/12 , C08F2/30 , C08F216/06 , C08F218/08
CPC分类号： C08F116/06 , C08F2/20 , C08F2/30 , C08F8/12 , C08F216/06 , C08F218/08 , C08L2201/54 , C08F222/16 , C08F220/06 , C08F222/02 , C08F2220/585 , C08F2216/1441 , C08F220/34
摘要： The present invention provides a highly water-soluble and easy-to-handle dispersion stabilizer for suspension polymerization that meets the following requirements: even if the amount of the dispersion stabilizer for suspension polymerization used for suspension polymerization of a vinyl compound is small, the resulting vinyl resin has high plasticizer absorptivity and is easy to work with; it is easy to remove residual monomer components from the resulting vinyl resin; and the resulting vinyl resin contains fewer coarse particles. The present invention relates to a dispersion stabilizer for suspension polymerization of a vinyl compound. This dispersion stabilizer contains a vinyl alcohol polymer (A) having a degree of saponification of 20 mol % or more and less than 65 mol %, a viscosity average degree of polymerization (P) of 100 or more and less than 600, an aliphatic hydrocarbon group having 6 to 18 carbon atoms at its terminal, and an anionic group in its side chain.

9. 发明授权

US09593256B2 Low-solvent polyacrylate copolymer dispersions 有权
标题翻译：低溶剂聚丙烯酸酯共聚物分散体
公开(公告)号：US09593256B2
公开(公告)日：2017-03-14
申请号：US14365195
申请日：2012-12-17
申请人： Bayer Intellectual Property GmbH
发明人： Marc Claudius Schrinner , Heinz-Dietmar Gewiss , Nusret Yuva , Martin Melchiors
IPC分类号： C09D133/10 , C08F220/18 , C08F265/06 , C08F8/44 , C09D151/00 , C08G18/62 , C08G18/79 , C08G18/08 , C09D175/04 , C08F285/00 , C08F2/20 , C09D133/06
CPC分类号： C09D133/10 , C08F2/20 , C08F8/44 , C08F220/18 , C08F265/06 , C08F285/00 , C08F2800/20 , C08F2810/50 , C08G18/0866 , C08G18/6225 , C08G18/792 , C09D133/066 , C09D151/00 , C09D175/04 , C08F218/04 , C08F216/02 , C08F220/06 , C08F220/20 , C08F220/14 , C08F2220/1825 , C08F218/10 , C08F212/08 , C08F220/02 , C08F2220/1875 , C08F2220/1858 , C08K5/1515 , C08L51/003
摘要： The present invention relates to an aqueous secondary copolymer dispersion comprising a copolymer (P) synthesized from a mixture of free-radically polymerizable monomers (M) comprising (M1) cycloaliphatic esters of acrylic and/or methylacrylic acid; (M2) vinyl esters of aliphatic carboxylic acids; (M3) hydroxy-functional, free-radically polymerizable monomers; (M4) carboxyl-functional, free-radically polymerizable monomers and (M5) hydroxyl- and carboxyl-free (meth)acrylic esters having C1 to C12 hydrocarbon radicals in the alcohol moiety and/or vinylaromatics. The mixture further comprises glycidyl esters of aliphatic carboxylic acids. The invention also relates to a method for the production of such a dispersion, to the use of the dispersion as a coating and as a binder in 2K polyurethane coatings.
摘要翻译：本发明涉及包含由可自由基聚合的单体（M）由丙烯酸和/或甲基丙烯酸的（M1）脂环族酯组成的混合物合成的共聚物（P）的水性二次共聚物分散体; （M2）脂肪族羧酸的乙烯基酯; （M3）羟基官能的可自由基聚合的单体; （M4）羧基官能的可自由基聚合的单体和（M5）羟基和无羧基的（甲基）丙烯酸酯，其在醇部分和/或乙烯基芳族化合物中具有C1-C12烃基。该混合物还包含脂族羧酸的缩水甘油酯。本发明还涉及生产这种分散体的方法，以分散体作为涂料和作为粘合剂在2K聚氨酯涂料中的用途。

10. 发明申请

US20170029534A1 DISPERSION STABILIZER FOR SUSPENSION POLYMERIZATION, AND METHOD FOR PRODUCING VINYL RESIN 审中-公开
标题翻译：用于悬浮聚合的分散稳定剂，以及生产乙烯基树脂的方法
公开(公告)号：US20170029534A1
公开(公告)日：2017-02-02
申请号：US15302307
申请日：2015-04-08
申请人： KURARAY CO., LTD. , KURARAY EUROPE GMBH
发明人： Tadahito FUKUHARA , Yosuke KUMAKI , Samuel MICHEL , Dirk HARTMANN
IPC分类号： C08F2/20 , C08F2/18 , C08F2/24
CPC分类号： C08F2/20 , C08F2/18 , C08F2/24 , C08F2/30 , C08F14/06 , C08F18/04 , C08F18/08 , C08F283/06 , C08L29/04 , C08L51/00 , C08L31/04 , C08L71/02 , C08L31/02 , C08L51/08 , C08L27/06
摘要： Provided is a dispersion stabilizer for suspension polymerization comprising an aqueous emulsion containing a dispersant (A), a dispersoid (B), a graft polymer (C), and an aqueous medium, wherein the dispersant (A) contains a surfactant, the dispersoid (B) contains a polymer having an ethylenically unsaturated monomer unit, the graft polymer (C) is obtained by graft polymerization of the ethylenically unsaturated monomer with the dispersant (A), a mass ratio [A/(A+B+C)] is 0.001 or more and less than 0.18, a mass ratio [C/(A+B+C)] is 0 or more and less than 0.04, and the total content of the dispersant (A), the dispersoid (B), and the graft polymer (C) is 35 to 70 mass %. A vinyl polymer to be obtained by suspension polymerization of a vinyl compound using the dispersion stabilizer has good plasticizer absorption. Further, the number of fish-eyes that occur when the vinyl polymer is formed is small, and the hue deterioration is also suppressed. Further, the dispersion stabilizer also has excellent handleability.
摘要翻译：提供一种悬浮聚合用分散稳定剂，其包含含有分散剂（A），分散质（B），接枝聚合物（C）和水性介质的水性乳液，其中分散剂（A）含有表面活性剂，分散质（ B）含有具有烯键式不饱和单体单元的聚合物，接枝聚合物（C）通过烯属不饱和单体与分散剂（A）的接枝聚合得到，质量比[A /（A + B + C）]为 0.001以上且小于0.18，质量比[C /（A + B + C）]为0以上且小于0.04，分散剂（A），分散质（B）和接枝聚合物（C）为35〜70质量％。通过使用分散稳定剂的乙烯基化合物的悬浮聚合获得的乙烯基聚合物具有良好的增塑剂吸收。此外，形成乙烯基聚合物时发生的鱼眼数量小，并且还抑制了色调劣化。此外，分散稳定剂也具有优异的可操作性。

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