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    • 4. 发明授权
    • Method of manufacturing a semiconductor capacitor having a hemispherical grain layer using a dry cleaning process
    • 使用干洗方法制造具有半球形晶粒层的半导体电容器的方法
    • US06537876B2
    • 2003-03-25
    • US09799033
    • 2001-03-06
    • Seung-pil ChungKyu-hwan ChangYoung-min KwonSang-lock Hah
    • Seung-pil ChungKyu-hwan ChangYoung-min KwonSang-lock Hah
    • H01L218242
    • H01L28/84H01L21/02046Y10S438/906Y10S438/964
    • A method of manufacturing a semiconductor device having a hemispherical grain (HSG) layer employs a dry cleaning process. A polysilicon layer is formed on a specific material layer on a semiconductor substrate. Next, a polysilicon pattern, at least a portion of which is exposed, is formed by etching the polysilicon layer. The exposed surface of the polysilicon pattern is then dry cleaned by supplying hydrogen in a plasma state and a fluorine-based gas toward the exposed surface. The exposed surface of the polysilicon pattern may also be wet cleaned before being dry cleaned to wash away pollutants which may have been left thereon. An HSG layer is then formed on the cleaned surface of the polysilicon pattern. After the HSG layer is formed, the surface of the HSG layer may be dry cleaned again by supplying hydrogen in a plasma state and a fluorine-based gas toward the surface of the HSG layer. The surface of the HSG layer may also be further wet cleaned before being dry cleaned. Accordingly, the HSG layer is effectively cleaned without damaging or contaminating the HSG layer, thereby improving the reliability of the semiconductor device.
    • 制造具有半球形颗粒(HSG)层的半导体器件的方法采用干法处理。 在半导体衬底上的特定材料层上形成多晶硅层。 接下来,通过蚀刻多晶硅层形成其至少一部分露出的多晶硅图案。 然后通过以等离子体状态供给氢气和将氟基气体朝向暴露的表面进行干式清洗。 多晶硅图案的暴露表面也可以在干燥清洁之前被湿清洗以洗去可能留在其上的污染物。 然后在多晶硅图案的清洁表面上形成HSG层。 在形成HSG层之后,可以通过以等离子体状态供给氢,并将氟基气体朝向HSG层的表面再次干燥HSG层的表面。 HSG层的表面也可以在干洗之前进一步湿清洗。 因此,HSG层被有效地清洁而不损坏或污染HSG层,从而提高半导体器件的可靠性。
    • 9. 发明授权
    • Method of removing oxide layer and semiconductor manufacturing apparatus for removing oxide layer
    • 去除氧化物层的方法和用于去除氧化物层的半导体制造装置
    • US07488688B2
    • 2009-02-10
    • US10997902
    • 2004-11-29
    • Seung-pil ChungKyu-whan ChangSun-jung LeeKun-tack LeeIm-soo ParkKwang-wook LeeMoon-hee Lee
    • Seung-pil ChungKyu-whan ChangSun-jung LeeKun-tack LeeIm-soo ParkKwang-wook LeeMoon-hee Lee
    • H01L21/302
    • H01L21/02057H01L21/31116
    • A method for removing an oxide layer such as a natural oxide layer and a semiconductor manufacturing apparatus which uses the method to remove the oxide layer. A vertically movable susceptor is installed at the lower portion in a processing chamber and a silicon wafer is loaded onto the susceptor when it is at the lower portion of the processing chamber. The air is exhausted from the processing chamber to form a vacuum condition therein. A hydrogen gas in a plasma state and a fluorine-containing gas are supplied into the processing chamber to induce a chemical reaction with the oxide layer on the silicon wafer, resulting in a reaction layer. Then, the susceptor is moved up to the upper portion of the processing chamber, to anneal the silicon wafer on the susceptor with a heater installed at the upper portion of the processing chamber, thus vaporizing the reaction layer. The vaporized reaction layer is exhausted out of the chamber. The oxide layer can be removed with a high selectivity while avoiding damage or contamination of the underlying layer.
    • 用于除去氧化物层的方法,例如天然氧化物层和使用该方法去除氧化物层的半导体制造装置。 垂直移动的基座安装在处理室的下部处,并且当硅晶片位于处理室的下部时,将硅晶片装载到基座上。 空气从处理室排出,在其中形成真空条件。 将等离子体状态的氢气和含氟气体供给到处理室,以引起与硅晶片上的氧化物层的化学反应,产生反应层。 然后,将基座向上移动到处理室的上部,通过安装在处理室上部的加热器对基座上的硅晶片退火,从而使反应层蒸发。 蒸发的反应层被排出室外。 可以以高选择性去除氧化物层,同时避免下层的损坏或污染。