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41. 发明授权

US4973736A Diethers of m- or p-hydroxyphenol 失效
标题翻译：对 - 对羟基苯酚的降解
公开(公告)号：US4973736A
公开(公告)日：1990-11-27
申请号：US395192
申请日：1989-08-15
申请人： Rainer Becker , Werner Hoffmann , Heinz-Guenter Oeser , Wolfgang Rohr , Juergen Varwig
发明人： Rainer Becker , Werner Hoffmann , Heinz-Guenter Oeser , Wolfgang Rohr , Juergen Varwig
IPC分类号： C07C69/66 , B01J23/00 , B01J27/00 , C07B61/00 , C07C41/00 , C07C41/01 , C07C41/16 , C07C41/26 , C07C43/205 , C07C43/225 , C07C43/23 , C07C43/29 , C07C43/295 , C07C51/00 , C07C59/125 , C07C59/64 , C07C67/00 , C07C201/00 , C07C205/38 , C07C253/00 , C07C255/54 , C07D213/64 , C07D241/44 , C07D277/68
CPC分类号： C07D277/68 , C07C205/38 , C07C41/16 , C07C41/26 , C07C43/225 , C07C43/23 , C07C43/29 , C07C59/64 , C07D213/64 , C07D241/44
摘要： Diethers of m- or p-hydroxyphenol, as well as the monoethers, are prepared by reacting m- or p-tert.-butoxyphenol of the formula II ##STR1## with a halogen compound in the presence of a hydroxide, carbonate and/or bicarbonate of an alkali metal or alkaline earth metal and an organic solvent which is inert under the reaction conditions, at from 20.degree. C. to 150.degree. C., and, if desired, reacting the resulting diether with a dilute aqueous inorganic acid at from 30.degree. to 100.degree. C. to give the monoether.The end products which can be prepared by the process according to the invention are useful starting materials for the preparation of dyes, drugs and crop protection agents.
摘要翻译：通过使式II II的m-或p-叔丁氧基苯酚与卤素化合物在氢氧化物，碳酸盐和/或其盐的存在下反应来制备间 - 或对羟基苯酚以及单醚，或碱性金属或碱土金属的碳酸氢盐和在反应条件下为惰性的有机溶剂，在20℃至150℃，如果需要，将所得二醚与稀无机酸水溶液反应从30℃至100℃，得到单醚。可通过本发明方法制备的最终产物是用于制备染料，药物和作物保护剂的有用起始材料。

42. 发明授权

US4654167A p-Alkoxycyclohexylalkanols and p-alkoxycyclohexylalkyl esters and their use as scents 失效
标题翻译：对 - 烷氧基环己基链烷醇和对 - 烷氧基环己基烷基酯及其作为香料的用途
公开(公告)号：US4654167A
公开(公告)日：1987-03-31
申请号：US794795
申请日：1985-11-04
申请人： Dieter Degner , Walter Gramlich , Werner Hoffmann , Ludwig Schuster
发明人： Dieter Degner , Walter Gramlich , Werner Hoffmann , Ludwig Schuster
IPC分类号： A61K8/00 , A61K8/34 , A61K8/37 , A61Q13/00 , C07C41/00 , C07C43/196 , C07C67/00 , C07C69/02 , C11B9/00 , C07C43/18
CPC分类号： C11B9/0034 , C07C43/196
摘要： p-Alkoxycyclohexylalkanols and their esters of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.7 -alkyl, in particular tert.-butyl, or is cyclohexyl, R.sup.2 is C.sub.1 -C.sub.3 -alkyl, in particular methyl or ethyl, and R.sup.3 is hydrogen, acetyl, propionyl or butyryl, and scent compositions containing these compounds I and processes for their preparation. The novel compounds have fine woody or sandalwood notes and can be used as scents and as components of scent compositions.
摘要翻译：对烷氧基环己基链烷醇及其通式Ⅰ的酯其中R 1是C 1 -C 7 - 烷基，特别是叔丁基，或是环己基，R 2是C 1 -C 3烷基，特别是甲基或乙基，R 3 是氢，乙酰基，丙酰基或丁酰基，以及含有这些化合物I的香味组合物及其制备方法。这些新颖的化合物具有优良的木质或檀木香料，可用作气味和作为香味组合物的组分。

43. 发明授权

US4491545A Preparation of 2,3,5-trimethyl-p-benzoquinone 失效
标题翻译：制备2,3,5-三甲基 - 对苯醌
公开(公告)号：US4491545A
公开(公告)日：1985-01-01
申请号：US482416
申请日：1983-04-06
申请人： Frank Thoemel , Werner Hoffmann
发明人： Frank Thoemel , Werner Hoffmann
IPC分类号： C07C46/00 , B01J23/00 , B01J23/72 , B01J27/122 , B01J31/02 , C07B61/00 , C07C45/00 , C07C46/04 , C07C46/06 , C07C46/08 , C07C46/10 , C07C50/02 , C07C67/00 , C07C50/04
CPC分类号： C07C46/08 , C07C46/06 , C07C46/10
摘要： Trimethyl-p-benzoquinone of the formula I ##STR1## is prepared by a process wherein A. 2,5,6-trimethylcyclohex-2-en-1-one or 2,3,6-trimethylcyclohex-2-en-1-one is reacted with air or oxygen at from 0.degree. to 150.degree. C. in a virtually anhydrous low molecular weight alkanol in the presence of a catalytic amount of copper(I) oxide or copper(II) oxide and in the presence of from 1 to 10 moles of a hydrogen halide gas per mole of trimethylcyclohexenone, and thereafterB. the reaction mixture, which essentially contains 2,3,6-trimethylphenol and/or 4-halo-2,3,6-trimethylphenol, is mixed with an alkali metal alcoholate in an amount such that a sample, when moistened with water, has a pH of from 3 to 6, and is then reacted with air, pure oxygen or tert.-butyl hydroperoxide at from 0.degree. to 150.degree. C., or wherein from 1 to 10 mole equivalents of a hydrogen halide gas per mole of substrate to be reacted are passed into a mixture containing a virtually anhydrous low molecular weight alkanol and a catalytic amount of copper(I) oxide or copper(II) oxide at from 0.degree. to 30.degree. C., an alkali metal alcoholate is added in an amount such that a sample, when moistened with water, has a pH of from 3 to 6, about one mole equivalent of 2,3,6-trimethylphenol is added and the mixture is then reacted with air, oxygen or tert.-butyl peroxide at from 0.degree. to 150.degree. C.Trimethyl-p-benzoquinone is an important intermediate for the synthesis of vitamin E.
摘要翻译：式I（I）的三甲基对苯醌通过以下方法制备：其中A.2,5,6-三甲基环己-2-烯-1-酮或2,3,6-三甲基环己-2-烯在催化量的氧化铜（I）或氧化铜（II）的存在下，在几乎无水的低分子量链烷醇中，0-150℃下，-1,1-二氧化物与空气或氧气反应，每摩尔三甲基环己烯酮为1至10摩尔卤化氢气体，然后为B.基本上含有2,3,6-三甲基苯酚和/或4-卤代-2,3,6-三甲基苯酚的反应混合物为与碱金属醇化物混合，其量使得样品在用水润湿时具有3至6的pH，然后与0℃至150℃的空气，纯氧或叔丁基过氧化氢反应。 C，或其中每摩尔待反应的底物1至10摩尔当量的卤化氢气体通入含有几乎无水的低分子量链烷醇和加入催化量的0〜30℃的氧化铜（I）或氧化铜（II），碱金属醇化物的添加量使得当用水润湿时，样品的pH为3 至6，加入约1摩尔当量的2,3,6-三甲基苯酚，然后将混合物与空气，氧气或叔丁基过氧化物在0至150℃下反应。三甲基对苯醌是重要的维生素E合成中间体

44. 发明授权

US4426332A Preparation of resorcinol derivatives 失效
标题翻译：间苯二酚衍生物的制备
公开(公告)号：US4426332A
公开(公告)日：1984-01-17
申请号：US370404
申请日：1982-04-21
申请人： Frank Thoemel , Werner Hoffmann
发明人： Frank Thoemel , Werner Hoffmann
IPC分类号： C07C37/06 , C07C37/07 , C07C39/08 , C07C41/00 , C07C41/01 , C07C43/23 , C07C69/84 , C07C69/88 , C07C69/92 , C07C255/53 , C11B9/00 , C07C121/75 , C07C37/00
CPC分类号： C07C255/00 , C07C37/07 , C07C41/01
摘要： A process for the preparation of resorcinol derivatives of the general formula I ##STR1## where R.sup.1 is carbalkoxy, nitrile, alkyl or H and R.sup.2 to R.sup.5 are H or lower alkyl, by reacting the corresponding cyclohexane-1,3-dione (II) with oxygen or an oxygen-containing gas in the presence of a catalytic amount of a copper compound and of from 1 to 10 moles of a hydrogen halide, or from 0.5 to 5 moles of thionyl chloride per mole of II, in an alkanol having from 1 to 6 carbon atoms, tetrahydrofuran or methyl tert.-butyl ether as the solvent, at from 0.degree. to 150 C., without the addition of a significant amount of water to the reaction mixture. Some of the resorcinol derivatives prepared are useful scents with fragrance notes of the character of the odoriferous substance of natural oak moss.
摘要翻译：制备通式Ⅰ（I）的间苯二酚衍生物的方法，其中R 1是烷氧基，腈，烷基或H和R 2至R 5是H或低级烷基，通过使相应的环己烷-1,3-二酮（II）与氧或含氧气体在催化量的铜化合物和1至10摩尔卤化氢存在下，或每摩尔II的0.5至5摩尔亚硫酰氯，在具有1至6个碳原子的链烷醇，四氢呋喃或甲基叔丁基醚作为溶剂，在0℃至150℃下，不向反应混合物中加入大量水。制备的一些间苯二酚衍生物是具有天然橡木苔的气味物质特征的香味的有用香味。

45. 发明授权

US4292244A Novel 2,4-disubstituted pyran derivatives, their preparation and their use as scents 失效
标题翻译：新型2,4-二取代吡喃衍生物，其制备及其作为香料的用途
公开(公告)号：US4292244A
公开(公告)日：1981-09-29
申请号：US154900
申请日：1980-05-30
申请人： Werner Hoffmann , Frank Thoemel
发明人： Werner Hoffmann , Frank Thoemel
IPC分类号： C07D309/20 , C07D309/22 , C11B9/00 , C07D309/24 , C07D309/26
CPC分类号： C07D309/20 , C07D309/22 , C11B9/008
摘要： 2-(1-methyl-eth-1-en-1-yl)-,2-(1-methyl-prop-1-en-1-yl)-, 2-(eth-1-en-1-yl)- and 2-(prop-1-en-1-yl)-4-methyl-2,3-dihydro-6H-pyrans substituted in the 2-position of the side chain by hydroxymethyl, acyloxymethyl, alkoxycarbonylmethyl, halomethyl or formyl. The novel 4-methyl-2,3-dihydro-6H-pyrans are obtained by reaction of 3-methyl-but-3-en-1-ol with an appropriately substituted unsaturated aldehyde in the presence of an acid catalyst. The products possess very interesting organoleptic properties.
摘要翻译： 2-（1-甲基 - 乙-1-烯-1-基） - ，2-（1-甲基 - 丙-1-烯-1-基） - ，2-（乙-1-烯-1-基）） - 和2-（丙-1-烯-1-基）-4-甲基-2,3-二氢-6H-吡喃酮在侧链的2-位被羟甲基，酰氧基甲基，烷氧基羰基甲基，卤代甲基或甲酰基。通过在酸催化剂存在下，使3-甲基 - 丁-3-烯-1-醇与适当取代的不饱和醛反应得到新的4-甲基-2,3-二氢-6H-吡喃。该产品具有非常有趣的感官特性。

46. 发明授权

US4250101A Bis-epoxy-dialkoxy-alkanes 失效
标题翻译：双环氧 - 二烷氧基烷烃
公开(公告)号：US4250101A
公开(公告)日：1981-02-10
申请号：US54863
申请日：1979-07-05
申请人： Manfred Baumann , Werner Hoffmann
发明人： Manfred Baumann , Werner Hoffmann
IPC分类号： C07D301/02 , C07D303/48 , C07D307/60 , C07D303/22
CPC分类号： C07D307/60 , C07D301/02 , C07D303/48
摘要： Bis-epoxy-dialkoxy-alkanes are valuable intermediates for the preparation of the sought-after aromatic 2,5-dimethyl-4-hydroxy-2,3-dihydrofuran-3-one. The novel bis-epoxy-dialkoxy-alkanes are obtained by reacting the corresponding .alpha.,.alpha.'-dihalo-1,2-diketones with an alkali metal hydroxide or an alkali metal alkoxide and an alkanol at from -20.degree. to +100.degree. C. To prepare the 2,5-dialkyl-4-hydroxy-2,3-dihydro-furan-3-ones, which are valuable aromatics, the novel bis-epoxy-dialkoxy-alkanes are heated with strong mineral acids or strong organic acids at from 60.degree. to 120.degree. C.
摘要翻译：双环氧 - 二烷氧基烷烃是制备所需的芳族2,5-二甲基-4-羟基-2,3-二氢呋喃-3-酮的有价值的中间体。通过使相应的α，α'-二卤代-1,2-二酮与碱金属氢氧化物或碱金属醇盐和在-20℃至+ 100℃的链烷醇反应获得新的双环氧 - 二烷氧基烷烃为了制备作为有价值芳烃的2,5-二烷基-4-羟基-2,3-二氢呋喃-3-酮，新型双环氧 - 二烷氧基烷烃用强无机酸或强有机酸加热在60〜120℃

47. 发明授权

US4238088A Guide for a thin tape-like recording medium, particularly a magnetic tape 失效
标题翻译：薄带状记录介质，特别是磁带的指导
公开(公告)号：US4238088A
公开(公告)日：1980-12-09
申请号：US52105
申请日：1979-06-26
申请人： Klaus Schoettle , Werner Hoffmann , Eduard Kaemmer
发明人： Klaus Schoettle , Werner Hoffmann , Eduard Kaemmer
IPC分类号： B65H23/16 , B65H23/26 , G11B15/295 , G11B15/60 , G11B15/32 , G11B15/66
CPC分类号： G11B15/605 , G11B15/295
摘要： A tape guide, especially a guide for thin magnetic tapes which are subjected to strong acceleration forces in the longitudinal direction, and a tape transport apparatus with a central capstan, comprising such a tape guide. The tape guide includes one or two rotatable, but fixedly arranged guide rollers having flanges arranged around part of the periphery thereof, which flanges each have an ingress and an egress chamfer for the tape. When one guide roller is used, the magnetic head is positioned between a tape reel and the guide roller and, when two guide rollers are used, it is positioned between the said two rollers, the magnetic head bearing against the unsupported span of tape in each case. The tape guide may be provided with means for producing cushions of air for stabilizing the roller as it rotates.
摘要翻译：带引导件，特别是用于在纵向方向上受到强加力的薄磁带的引导件，以及包括这种带引导件的带有中心绞盘的带传送装置。带引导件包括一个或两个可旋转但固定地布置的导辊，其具有围绕其周边的一部分布置的凸缘，该凸缘各自具有用于带的入口和出口倒角。当使用一个导辊时，磁头位于磁带卷轴和导向辊之间，并且当使用两个导向辊时，它位于所述两个辊之间，磁头轴承抵抗在每个中的带的无支撑跨度案件。带引导件可以设置有用于产生用于在旋转时使辊稳定的空气垫的装置。

48. 发明授权

US4225099A Tape transport mechanism 失效
标题翻译：磁带传输机制
公开(公告)号：US4225099A
公开(公告)日：1980-09-30
申请号：US954636
申请日：1978-10-25
申请人： Klaus Schoettle , Helmut Lewin , Werner Hoffmann , Peter Dobler , Lothar Gliniorz
发明人： Klaus Schoettle , Helmut Lewin , Werner Hoffmann , Peter Dobler , Lothar Gliniorz
IPC分类号： G11B15/295 , G11B15/32
CPC分类号： G11B15/295
摘要： This invention relates to a tape transport mechanism, particularly an improved contact winding tape transport system modified to protect it against tape transport disturbances occasioned by mechanical impacts. A shock-resisting coupling means is provided which is allocated to the reel carriers and which allows slow movements of the carriers toward and away from a drive capstan during normal working of the mechanism but prevents sudden movements of the carriers induced by mechanical shocks for instance. Piston/cylinder assemblies and magnetic rope/drum arrangements are disclosed as such shock-resisting means. The transport mechanism can be used advantageously in portable apparatus, preferably in magnetic tape recorders and especially in video cameras.
摘要翻译：本发明涉及一种带传送机构，特别是一种改进的接触绕带输送系统，其被修改为保护其免受机械冲击引起的带运输干扰。提供了抗冲击的联接装置，其被分配给卷轴托架，并且允许托架在机构的正常加工期间朝向和远离驱动绞盘运动缓慢，但是防止例如由机械冲击引起的载体的突然移动。公开了活塞/气缸组件和磁绳/滚筒装置作为这种抗冲击装置。运输机构可以有利地用在便携式设备中，优选地在磁带录音机中，特别是在摄像机中。

49. 发明授权

US4124451A Closure for a coking chamber of a coking oven 失效
标题翻译：炼焦炉焦化室关闭
公开(公告)号：US4124451A
公开(公告)日：1978-11-07
申请号：US706839
申请日：1976-07-19
申请人： Kurt Dix , Werner Hoffmann
发明人： Kurt Dix , Werner Hoffmann
IPC分类号： C10B25/06 , C10B25/16
CPC分类号： C10B25/16
摘要： The opening for charging a coking chamber of a coking oven is closed by closure means and a lock chamber is arranged outside the closure means for preventing any emissions from the coking chamber seeping past the closure means to pass to the outer atmosphere.
摘要翻译：用于对焦化炉的焦化室充电的开口由封闭装置封闭，并且在封闭装置的外部设置有一个锁室，用于防止焦化室中的任何排放物通过封闭装置渗透到外部大气中。

50. 发明授权

US4069258A Cyclopentene derivatives 失效
标题翻译：环戊烯衍生物
公开(公告)号：US4069258A
公开(公告)日：1978-01-17
申请号：US666630
申请日：1976-03-15
申请人： Werner Hoffmann , Karl VON Fraunberg
发明人： Werner Hoffmann , Karl VON Fraunberg
IPC分类号： C07C69/025 , A61K8/33 , A61K8/34 , A61Q13/00 , C07C27/00 , C07C33/12 , C07C35/06 , C07C41/00 , C07C43/303 , C07C45/00 , C07C47/225 , C07C67/00 , C07D317/12 , C07D319/06 , C11B9/00 , C11D3/50 , C11D9/44 , C07C47/40
CPC分类号： C11B9/003 , C07C33/12 , C07C35/06 , C07C47/225 , C07D317/12
摘要： Cyclopentene derivatives (I) ##STR1## where R.sup.1 is isopropyl or isopropenyl, R.sup.2 is alkyl of 1 to 3 carbon atoms, X is --CHO, a dialkyl acetal or 1,2- or 1,3-alkylene acetal thereof where the acetal radical is of 2 to 6 carbon atoms, --CH.sub.2 OH or --CH.sub.2 OCOR.sup.3 where R.sup.3 is hydrogen or alkyl or alkenyl of up to 3 carbon atoms. The manufacture of I from the corresponding halomethyl cyclopentenes and aldehydes R.sup.2 --CH(CH.sub.3)--CHO in the presence of a base and a quaternary ammonium salt, followed if desired by acetalization or conversion of the --CHO group to the --CH.sub.2 OH or --CH.sub.2 O--CO--R.sup.3 groups. The compounds are useful as fragrance materials.
摘要翻译：环戊烯衍生物（I）其中R 1是异丙基或异丙烯基，R 2是1至3个碳原子的烷基，X是-CHO，二烷基缩醛或其1,2-或1,3-亚烷基缩醛，其中缩醛基团为2至6个碳原子，-CH 2 OH或-CH 2 OCOR 3，其中R 3为氢或至多3个碳原子的烷基或链烯基。在碱和季铵盐的存在下，由相应的卤代甲基环戊烯和醛类R 2 -CH（CH 3）-CHO制备I化合物，如果需要，则通过缩醛化或将-CHO基团转化为-CH 2 OH或-CH 2 O -CO-R3基团。这些化合物可用作香料。

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