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1. 发明申请

US20210317060A1 PROCESS OF VITAMIN K2 DERIVATIVES PREPARATION 有权
公开(公告)号：US20210317060A1
公开(公告)日：2021-10-14
申请号：US17045477
申请日：2019-04-06
申请人： INSTYTUT FARMACEUTYCZNY
发明人： Katarzyna SIDORYK , Marek NAPIORKOWSKI , Agnieszka BURZYNSKA-PRAJZNER , Marcin CYBULSKI , Marek KUBISZEWSKI , Kamil JATCZAK , Lukasz JEDYNAK , Jerzy WINIARSKI , Dorota PIETRZKOWSKA , Konrad ZIELINSKI
IPC分类号： C07C46/04
摘要： Provided is an improved process of vitamin K2 derivatives preparation, represented by formula (I) wherein n is an integer from 3 to 13.

2. 发明授权

US5712416A Preparation of benzoquinones by oxidation of phenols 失效
标题翻译：通过酚的氧化制备苯醌
公开(公告)号：US5712416A
公开(公告)日：1998-01-27
申请号：US562639
申请日：1995-11-27
申请人： Thomas Gessner
发明人： Thomas Gessner
IPC分类号： C07C46/02 , B01J31/18 , C07C46/06 , C07C46/08 , C07C50/04 , C07C303/22 , C07C303/32 , C07C309/25 , C09B13/00 , C07C46/04
CPC分类号： C09B13/00 , B01J31/1815 , C07C303/22 , C07C303/32 , C07C46/06 , C07C46/08 , B01J2531/62 , B01J2531/72 , B01J2531/842 , B01J2531/845
摘要： Process for preparing benzoquinones by oxidation of phenols in the presence of a diluent and of an oxygen-transferring catalyst which contains a heavy metal ion bound in a complex, wherein oxygen, hydrogen peroxide, a compound which liberates hydrogen peroxide, an organic hydroperoxide, a percarboxylic acid or peroxomonosulfuric acid or salts thereof are used as oxidizing agent, and wherein the oxygen-transferring catalyst is from the class of iron, manganese or chromium tetraaza�14!annulenes.
摘要翻译：在稀释剂和含有重金属离子的氧转移催化剂存在下，通过氧化酚类来制备苯醌的方法，其中氧，过氧化氢，释放过氧化氢的化合物，有机氢过氧化物，过羧酸或过硫酸或其盐用作氧化剂，其中氧转移催化剂来自铁，锰或铬四氮杂环类。

3. 发明授权

US5616734A Process for the catalytic oxidation of aromatic compounds 失效
标题翻译：芳香族化合物的催化氧化方法
公开(公告)号：US5616734A
公开(公告)日：1997-04-01
申请号：US378231
申请日：1995-01-25
申请人： Wolfgang A. Herrmann , Joao D. G. Correia , Richard Fischer , Waldemar Adam , Jianhua Lin , Chantu R. Saha-Moller , Masao Shimizu
发明人： Wolfgang A. Herrmann , Joao D. G. Correia , Richard Fischer , Waldemar Adam , Jianhua Lin , Chantu R. Saha-Moller , Masao Shimizu
IPC分类号： B01J31/12 , C07B61/00 , C07C27/00 , C07C37/60 , C07C39/07 , C07C39/225 , C07C46/04 , C07C46/06 , C07C50/02 , C07C50/10 , C07C50/28 , C07C51/285 , C07C63/331 , C07D311/74 , C07C50/04
CPC分类号： C07C46/04 , C07C37/60 , C07C46/06 , C07C50/10
摘要： The invention relates to the use of compounds of the formula IR.sup.1.sub.a Re.sub.b O.sub.c (I),where a is from 1 to 6, b is from 1 to 4 and c is from 1 to 14 and the sum of a, b and c is in accordance with the valence of from 5 to 7 of the rhenium, with the proviso that c is not greater than 3.multidot.b, and where R.sup.1 is identical or different and is an aliphatic hydrocarbon radical having from 1 to 10 carbon atoms, an aromatic hydrocarbon radical having from 6 to 10 carbon atoms or an arylalkyl radical having from 7 to 9 carbon atoms, with the radicals R.sup.1 being able, if desired, to be identically or differently substituted independently of one another and, in the case of .sigma.-bonded radicals, at least one hydrogen atom still being bonded to the carbon atom in the .alpha. position, as catalysts for the oxidation of electron-rich aromatic compounds and their derivatives and to a process for the oxidation of electron-rich aromatic compounds which comprises oxidizing electron-rich C.sub.6 -C.sub.22 -aryl compounds and their derivatives in the presence of a catalyst of the formula I and a peroxide-containing compound.
摘要翻译：本发明涉及式Ⅰ化合物R1aRebOc（Ⅰ）的用途，其中a为1至6，b为1至4，c为1至14，a，b和c的和为铼的价数为5至7，条件是c不大于3xb，并且其中R1相同或不同，是具有1至10个碳原子的脂族烃基，具有从 6至10个碳原子或具有7至9个碳原子的芳基烷基，如果需要，基团R1能够彼此相同或不同地取代，并且在σ-键合基团的情况下，至少一个氢原子仍然与α位上的碳原子键合，作为用于氧化富含电子的芳族化合物及其衍生物的催化剂，以及氧化富含电子的芳族化合物的方法，其包括将富含电子的C6- C22-芳基化合物及其衍生物在式I催化剂和含过氧化物的化合物存在下进行。

4. 发明授权

US4906411A Process for producing 2-methyl-1,4-naphthoquinone 失效
标题翻译： 2-甲基-1,4-萘醌的制备方法
公开(公告)号：US4906411A
公开(公告)日：1990-03-06
申请号：US51380
申请日：1987-05-19
申请人： Atsushi Shinnaka , Yukio Narabu
发明人： Atsushi Shinnaka , Yukio Narabu
IPC分类号： C07B61/00 , B01J31/00 , B01J31/18 , C07C45/00 , C07C46/02 , C07C46/04 , C07C50/10 , C07C67/00
CPC分类号： C07C46/02
摘要： An improved process for producing 2-methyl-1,4-naphthoquinone with a high yield comprising reaction of a 1-lower-alkoxy-2-methyl naphthalene with hydrogen peroxide in the presence of a hexacyanoferric acid or a salt thereof as catalyst. This process does not employ hazardous chromium compounds unlike conventional methods.

5. 发明授权

US4840932A Catalyst for producing 1,4-naphthoquinone 失效
标题翻译：用于生产1,4-萘醌的催化剂
公开(公告)号：US4840932A
公开(公告)日：1989-06-20
申请号：US170057
申请日：1988-03-16
申请人： Ryo Matsuura , Shigeyuki Yoshimura , Yasuo Asanuma , Katsuaki Nasu , Haruo Yoshizumi , Kazumi Tsujimoto , Toshiyuki Kimura
发明人： Ryo Matsuura , Shigeyuki Yoshimura , Yasuo Asanuma , Katsuaki Nasu , Haruo Yoshizumi , Kazumi Tsujimoto , Toshiyuki Kimura
IPC分类号： C07C46/06 , B01J23/22 , B01J27/00 , B01J27/055 , B01J35/02 , C07B61/00 , C07C45/00 , C07C46/04 , C07C50/12 , C07C67/00
CPC分类号： B01J35/026 , B01J23/22 , B01J27/055 , C07C46/04
摘要： A process for producing 1,4-naphthoquinone by oxidizing naphthalene with molecular oxygen in a vapor phase in the presence of a catalyst. The catalyst is made of a mixture of a carrier and fusible catalytic components including vanadium oxide and alkali metal sulfate and pyrosulfate, and has a molded configuration having one or more through-holes.
摘要翻译：在催化剂存在下，通过在气相中用分子氧氧化萘而生产1,4-萘醌的方法。催化剂由载体和包含氧化钒和碱金属硫酸盐和焦硫酸盐的易熔催化组分的混合物制成，并且具有一个或多个通孔的模制构型。

6. 发明授权

US4647349A Oxidation of organic compounds using ceric ions in aqueous trifluoromethanesulfonic acid 失效
标题翻译：在三氟甲磺酸水溶液中氧化有机化合物
公开(公告)号：US4647349A
公开(公告)日：1987-03-03
申请号：US859565
申请日：1986-05-05
申请人： Robert P. Kreh , Robert M. Spotnitz
发明人： Robert P. Kreh , Robert M. Spotnitz
IPC分类号： C25B3/02 , C07B41/06 , C07C45/28 , C07C45/30 , C07C46/04 , C07C47/52 , C07C49/76 , C07C205/47 , C25B3/00
CPC分类号： C25B3/00 , C07C45/30
摘要： A process for oxidizing aromatic and alkyl substituted aromatic compounds to carbonyl containing compounds by contacting an aromatic and alkyl aromatic compound with an aqueous solution of ceric trifluoromethanesulfonate having from at least 0.75 to 7 molar concentration of free acid of trifluoromethanesulfonic acid and at least 0.2 molar cerium ion concentration. The present process provides a highly effective means of forming the desired carbonyl containing product in good yields and high selectivity.
摘要翻译：通过使芳族和烷基芳族化合物与三氟甲磺酸铈的水溶液接触，使芳族和烷基取代的芳香族化合物氧化成含羰基化合物的方法，其具有至少0.75至7摩尔浓度的三氟甲磺酸游离酸和至少0.2摩尔铈离子浓度。本方法提供了以良好的收率和高选择性形成所需的含羰基产物的高效手段。

7. 发明授权

US4536337A Process for the preparation of quinones 失效
标题翻译：醌类制备方法
公开(公告)号：US4536337A
公开(公告)日：1985-08-20
申请号：US596695
申请日：1984-04-04
申请人： Tatsuyoshi Komatsu , Shigeaki Numata , Toshihiko Sumino , Katsumi Matsuzaki , Masao Narita , Katsuhiko Hioki
发明人： Tatsuyoshi Komatsu , Shigeaki Numata , Toshihiko Sumino , Katsumi Matsuzaki , Masao Narita , Katsuhiko Hioki
IPC分类号： C07C46/04 , C07C51/16 , C07C50/02 , C07C50/10 , C07C50/16 , C07C50/22
CPC分类号： C07C46/04 , C07C51/16
摘要： A process for preparing a quinone, which comprises reacting a polynuclear aromatic hydrocarbon and a ceric salt in an aqueous acid solution in the presence of an organic solvent selected from the group consisting of chlorobenzene and an alkylbenzene represented by the general formula: ##STR1## where each of R.sub.1, R.sub.2 and R.sub.3 is an alkyl group and the total carbon number of the alkyl groups is from 3 to 6.
摘要翻译：一种制备醌的方法，其包括在选自氯苯和由以下通式表示的烷基苯的有机溶剂存在下，在酸性水溶液中使多核芳烃和铈盐反应： I），其中R1，R2和R3各自为烷基，烷基的总碳数为3至6。

8. 发明授权

US4446070A Catalytic oxidation of polynuclear aromatic hydrocarbons 失效
标题翻译：多核芳烃的催化氧化
公开(公告)号：US4446070A
公开(公告)日：1984-05-01
申请号：US272414
申请日：1981-06-10
申请人： Derk T. A. Huibers , Cheng-Yih Jenq
发明人： Derk T. A. Huibers , Cheng-Yih Jenq
IPC分类号： C07C46/04 , C07C50/18 , C07C3/00
CPC分类号： C07C46/04
摘要： A process for the catalytic oxidation of polynuclear aromatic hydrocarbons in general and anthracene in particular in an oxygen-containing gas in the presence of a ceric ammonium nitrate catalyst system wherein turnover ratios are increased by: (1) use of acetic acid as solvent; (2) use of pure molecular oxygen as the oxygen-containing gas; (3) use of ammonium vanadate as a promoter; and (4) addition of acetic anhydride to react with water produced as a by-product of the oxidation reaction. By use of the filtrate, remaining after removal of anthraquinone by filtration, to catalyze the oxidation of fresh anthracene, and by addition of nitric acid to restore catalytic activity after a series of oxidation reactions, anthraquinone is produced from anthracene in a continuous system.
摘要翻译：在硝酸铈铵催化剂体系的存在下，通常使用多元芳香烃和蒽的催化氧化方法，特别是在含氧气体中，通过以下方式增加转化率：（1）使用乙酸作为溶剂; （2）使用纯分子氧作为含氧气体; （3）使用钒酸铵作为助剂; 和（4）加入乙酸酐与作为氧化反应的副产物产生的水反应。通过使用滤液，通过过滤除去蒽醌后残留，催化新鲜蒽的氧化，并且通过加入硝酸以在一系列氧化反应后恢复催化活性，在连续体系中由蒽产生蒽醌。

9. 发明授权

US4255343A Preparation of 2-T-alkylanthracene 失效
标题翻译： 2-T-alkylanthracene的制备
公开(公告)号：US4255343A
公开(公告)日：1981-03-10
申请号：US65862
申请日：1979-08-13
申请人： Lawrence W. Gosser
发明人： Lawrence W. Gosser
IPC分类号： C07C2/66 , C07C2/70 , C07C2/86 , C07C4/18 , C07C6/12 , C07C15/28 , C07C46/04 , C07C45/28 , C07C2/64 , C07C50/18
CPC分类号： C07C46/04 , C07C15/28 , C07C2/66 , C07C2/70 , C07C2/862 , C07C2/864 , C07C2/865 , C07C4/18 , C07C6/126 , C07C2103/24 , C07C2521/12 , C07C2529/04 , C07C2531/025 , C07C2531/04 , C07C2531/10
摘要： Process for preparing 2-t-alkylanthracene, which process comprises contacting and reacting, with good mixing, at a temperature of at least 110.degree. C., anthracene and a branched-chain alkylating agent, the alkylating moiety of which contains at least four carbon atoms, in the presence of a catalyst selected from hydrocarbonsulfonic acids which are free of nonaromatic unsaturation, organic carboxylic acids having a K.sub.a of 0.6 to 0.001, acid zeolites, amorphous silica-aluminas, and polymeric arenesulfonic acid resins, to give a product mixture of which the major constituent is 2-t-alkylanthracene.
摘要翻译：制备2-叔 - 烷基蒽的方法，该方法包括在至少110℃的温度下，良好的混合下接触和反应，蒽和支链烷基化剂，其烷基化部分含有至少四个碳在选自不具有非芳族不饱和键的烃磺酸的催化剂，Ka为0.6〜0.001的有机羧酸，酸性沸石，无定形二氧化硅 - 氧化铝和聚合芳族磺酸树脂的存在下，得到产物混合物主要成分是2-叔烷基蒽。

10. 发明授权

US4202828A Process for separation of naphthoquinone and phthalic acid 失效
标题翻译：分离萘醌和邻苯二甲酸的方法
公开(公告)号：US4202828A
公开(公告)日：1980-05-13
申请号：US868349
申请日：1978-01-10
申请人： Ryo Matsuura , Tatsuyoshi Komatsu , Yukio Nomiyama , Kenji Usui
发明人： Ryo Matsuura , Tatsuyoshi Komatsu , Yukio Nomiyama , Kenji Usui
IPC分类号： C07C46/04 , C07C46/10 , C07C51/487 , C07C45/24 , C07C49/66 , C07C51/48 , C07C63/16
CPC分类号： C07C46/10 , C07C46/04 , C07C51/487
摘要： In a process for separation of naphthoquinone and phthalic acid from an aqueous slurry prepared by contacting a reaction mixture gas formed by a catalytic vapor phase oxidation of naphthalene with an aqueous medium, the decomposition of naphthoquinone is prevented and phthalic acid is substantially separated by adding a base to the aqueous slurry so as to neutralize only sulfuric acid component and maleic acid component without substantially neutralizing phthalic acid component and heating the aqueous slurry to dissolve phthalic acid to form a slurry of naphthoquinone in an aqueous solution of phthalic acid and extracting naphthoquinone with a solvent while preventing a crystallization of phthalic acid.A pH of the aqueous slurry is adjusted in a range of 1.2 to 2.5 before the heat dissolution of phthalic acid and the extraction of naphthoquinone.An aqueous phase obtained after the extraction of naphthoquinone is cooled to crystallize phthalic acid and then the filtrate separating from the resulting slurry is used as an aqueous medium for contacting with the reaction mixture gas, optionally after adjusting pH in a range of 1.2 to 2.5.
摘要翻译：在通过将通过萘的催化气相氧化形成的反应混合物气体与水性介质接触而制备的水性浆液分离萘醌和邻苯二甲酸的方法中，萘醌的分解被防止，邻苯二甲酸通过加入以仅中和硫酸成分和马来酸成分，而基本不中和邻苯二甲酸成分，加热含水浆料溶解邻苯二甲酸，形成萘醌在邻苯二甲酸水溶液中的浆液，并用萘磺酸提取萘醌溶剂，同时防止邻苯二甲酸的结晶。在邻苯二甲酸的热溶解和萘醌的萃取之前，将水性浆液的pH调节在1.2〜2.5的范围内。冷却萃取萘醌后得到的水相，使邻苯二甲酸结晶，然后将所得浆液分离出的滤液用作与反应混合物气体接触的水性介质，任选在将pH调节在1.2〜2.5的范围内后，

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