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21. 发明授权

US07524405B2 Method for separating out solvent from a reaction mixture resulting from an isocyanate synthesis and for purifying this solvent 有权
标题翻译：从由异氰酸酯合成得到的反应混合物中分离出溶剂并纯化该溶剂的方法
公开(公告)号：US07524405B2
公开(公告)日：2009-04-28
申请号：US10539610
申请日：2003-12-13
申请人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Juergen Pallasch , Peter Van Den Abeel , Filip Deberdt , Jan D. Jacobs , Wolfgang Mackenroth
发明人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Juergen Pallasch , Peter Van Den Abeel , Filip Deberdt , Jan D. Jacobs , Wolfgang Mackenroth
IPC分类号： B01D3/00 , C07C263/20
CPC分类号： C07C263/10 , C07C263/20 , Y10S203/08 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reaction of amines with phosgene in the presence of inert organic solvents in a reactor and subsequent work-up of the reaction mixture leaving the reactor, wherein the solvent is separated off in a two-stage or multistage, preferably two-stage, distillation process in which the solvent is separated off at a pressure of 0.1-15 bar in a first apparatus and at 1-900 mbar in a second apparatus or further apparatuses, with the heat of condensation of the solvent vapor from the first apparatus being used for partial or complete vaporization of solvent in the second apparatus.
摘要翻译：本发明涉及通过在反应器中在惰性有机溶剂存在下胺与光气反应制备异氰酸酯的方法，随后后处理离开反应器的反应混合物，其中将溶剂分离成两段或多级，优选两级蒸馏方法，其中溶剂在第一装置中在0.1-15巴的压力下分离，在第二装置或其它装置中以1-900毫巴分离，其中溶剂的冷凝热来自第一装置的蒸气用于在第二装置中部分或完全蒸发溶剂。

22. 发明申请

US20090023956A1 DIRECT AMINATION OF HYDROCARBONS 失效
标题翻译：油气的直接化学分析
公开(公告)号：US20090023956A1
公开(公告)日：2009-01-22
申请号：US12280634
申请日：2007-02-15
申请人： Frederik van Laar , Ekkehard Schwab , Joachim-Thierry Anders , Sven Crone , Karl Holemann , Wolfgang Mackenroth , Petr Kubanek
发明人： Frederik van Laar , Ekkehard Schwab , Joachim-Thierry Anders , Sven Crone , Karl Holemann , Wolfgang Mackenroth , Petr Kubanek
IPC分类号： C07C209/02
CPC分类号： C07C209/02
摘要： A process for aminating hydrocarbons with ammonia in the presence of catalyst (i) which catalyzes the amination, which comprises supplying oxidizing agent to the reaction mixture and reacting the oxidizing agent with hydrogen which is formed in the amination in the presence of a catalyst (ii) which catalyzes this reaction with hydrogen.
摘要翻译：在催化胺化催化剂（ⅰ）的存在下，用氨胺化氨烃的方法，其中包括向反应混合物中供应氧化剂，并使氧化剂与在催化剂存在下在胺化中形成的氢反应（ii）），其与氢催化该反应。

23. 发明申请

US20080177111A1 METHOD FOR THE PRODUCTION OF AMINES 有权
标题翻译：生产氨基酸的方法
公开(公告)号：US20080177111A1
公开(公告)日：2008-07-24
申请号：US12057617
申请日：2008-03-28
申请人： Frederik van Laar , Ekkehard Schwab , Steffen Oehlenschlager , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
发明人： Frederik van Laar , Ekkehard Schwab , Steffen Oehlenschlager , Hartwig Voss , Wolfgang Mackenroth , Konrad Morgenschweis , Ulrich Penzel , Bernd Weidner
IPC分类号： C07C209/00
CPC分类号： C07C209/36 , B01J21/18 , B01J23/892 , B01J37/03 , B01J37/14 , B01J37/18 , C07C211/51
摘要： The present invention provides a process for hydrogenating aromatic nitro compounds to the corresponding amines in the presence of hydrogenation catalysts, which comprises using hydrogenation catalysts in which nickel and platinum are present on a support in the form of an alloy having an atomic ratio of nickel to platinum in the alloy of between 30:70 and 70:30.
摘要翻译：本发明提供了在氢化催化剂存在下将芳族硝基化合物氢化成相应的胺的方法，该方法包括使用氢化催化剂，其中镍和铂以合金的形式存在于载体上，其原子比为镍与合金中的铂在30:70和70:30之间。

24. 发明申请

US20060089507A1 Method for separating isocyanates out from a reaction mixture 审中-公开
标题翻译：从反应混合物中分离异氰酸酯的方法
公开(公告)号：US20060089507A1
公开(公告)日：2006-04-27
申请号：US10538119
申请日：2003-12-13
申请人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Jurgen Pallasch , Michael Sander , Hans Schwarz , Wolfgang Mackenroth
发明人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Jurgen Pallasch , Michael Sander , Hans Schwarz , Wolfgang Mackenroth
IPC分类号： C07C263/04
CPC分类号： C07C263/20 , C07C263/10 , C07C265/14
摘要： The present invention relates to a process for preparing isocyanates by reaction of amines with phosgene in a reactor and subsequent separation of the isocyanate from the reaction mixture leaving the reactor and purification of the isocyanate, wherein the separation and purification of the isocyanate is carried out in a column having a pressure at the top of 1-950 mbar, preferably 5-50 mbar, particularly preferably 10-20 mbar, and a temperature at the bottom of 90-250° C., preferably 120-170° C., particularly preferably 130-150° C., and the pure isocyanate stream is preferably taken off in liquid or gaseous form at a side offtake of the column.
摘要翻译：本发明涉及通过在反应器中将胺与光气反应制备异氰酸酯的方法，随后将异氰酸酯从离开反应器的反应混合物中分离并纯化异氰酸酯，其中异氰酸酯的分离和纯化在具有顶部压力为1-950毫巴，优选5-50毫巴，特别优选10-20毫巴，塔底温度为90-250℃，优选120-170℃的塔，特别是优选130-150℃，并且纯异氰酸酯流优选在液体或气体形式的塔的出口侧取出。

25. 发明授权

US5237113A Preparation of haloalcohols 失效
标题翻译：卤代醇的制备
公开(公告)号：US5237113A
公开(公告)日：1993-08-17
申请号：US973553
申请日：1992-11-09
申请人： Rainer Becker , Wolfgang Mackenroth , Walter Seufert
发明人： Rainer Becker , Wolfgang Mackenroth , Walter Seufert
IPC分类号： C07C29/62
CPC分类号： C07C29/62
摘要： Haloalcohols of the general formula IHal--X--OH (I)where X is straight-chain or branched, substituted or unsubstituted alkylene of 4 or more carbon atoms in the chain, which may be interrupted by one or more heteroatoms, and Hal is halogen, are prepared by reacting a diol of the general formula IIHO--X--OH (II)where X has the above meanings, with an aqueous hydrogen halide solution in a water-immiscible organic solvent which is inert under the reaction conditions, at from 50.degree. to 150.degree. C., using an excess of hydrogen halide, based on the diol of the general formula II, of from 10 to 200 mole percent and setting a volume ratio of inorganic phase: organic phase of from 1:2 to 1:50.
摘要翻译：通式I Hal-X-OH（I）的卤代醇，其中X是链中4个或更多个碳原子的直链或支链，取代或未取代的亚烷基，其可被一个或多个杂原子间隔，Hal是卤素，通过使具有上述含义的通式II HO-X-OH（II）的二醇与卤化氢水溶液在反应条件下为惰性的水不混溶的有机溶剂中，在从50℃至150℃，使用过量的基于通式II的二醇的卤化氢为10至200摩尔％，并将无机相：有机相的体积比为1:2设定为 1:50。

26. 发明授权

US08829232B2 Process for preparing aromatic isocyanates 有权
标题翻译：制备芳族异氰酸酯的方法
公开(公告)号：US08829232B2
公开(公告)日：2014-09-09
申请号：US13057869
申请日：2009-08-06
申请人： Ulrich Penzel , Torsten Mattke , Andreas Wölfert , Johannes Jacobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
发明人： Ulrich Penzel , Torsten Mattke , Andreas Wölfert , Johannes Jacobs , Tsung-Chieh Cheng , Kerstin Heinen , Eckhard Stroefer , Stefan Maixner , Wolfgang Mackenroth , Christian Tragut , Kai Thiele , Myung Un Won
IPC分类号： C07C263/00 , C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing isocyanates by reacting the corresponding amines with phosgene in the liquid phase, if appropriate in the presence of at least one inert medium, in which the amine and the phosgene are first mixed in a mixing chamber (1) to give a reaction mixture and the reaction mixture is fed to a reactor, the amine being added through an orifice (3) arranged coaxially to the mixing chamber (1) and the phosgene being added through feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1), or the phosgene being added through the orifice (3) arranged coaxially to the mixing chamber and the amine through the feed orifices (5) in at least two planes (7, 9) arranged at right angles to the axis (11) of the mixing chamber (1). At least one plane (9) is arranged upstream and at least one plane (7) downstream of the orifice (3) arranged coaxially to the mixing chamber (1) in main flow direction of the reaction mixture. The mean residence time of the reaction mixture in the mixing chamber (1) is not more than 20 ms.
摘要翻译：本发明涉及通过使相应的胺与液相中的光气反应制备异氰酸酯的方法，如果合适的话，在至少一种惰性介质存在下，其中胺和光气首先在混合室（1）中混合，得到反应混合物并将反应混合物加入到反应器中，通过与混合室（1）同轴设置的孔口（3）加入胺，通过进料孔（5）在至少两个平面中加入光气（7,9），其与所述混合室（1）的轴线（11）成直角排列，或者通过所述孔（3）加入的光气通过所述孔（3）同轴地配置到所述混合室，所述胺通过所述进料孔（5）在与所述混合室（1）的轴线（11）成直角布置的至少两个平面（7,9）中。至少一个平面（9）布置在上游，并且孔（3）下游的至少一个平面（7）在反应混合物的主流动方向上与混合室（1）同轴布置。反应混合物在混合室（1）中的平均停留时间不超过20ms。

27. 发明授权

US08614356B2 Method for producing toluylenediamine by hydrogenating dinitrotoluene 失效
标题翻译：通过氢化二硝基甲苯生产甲苯二胺的方法
公开(公告)号：US08614356B2
公开(公告)日：2013-12-24
申请号：US13142718
申请日：2009-12-21
申请人： Joana Coelho Tsou , Steffen Oehlenschlaeger , Ekkehard Schwab , Wolfgang Mackenroth , Hartwig Voss , Stefan Maixner , Samuel Neto , Sven Boehmeke , Frederik Van Laar
发明人： Joana Coelho Tsou , Steffen Oehlenschlaeger , Ekkehard Schwab , Wolfgang Mackenroth , Hartwig Voss , Stefan Maixner , Samuel Neto , Sven Boehmeke , Frederik Van Laar
IPC分类号： C07C209/00 , C07C211/00
CPC分类号： C07C209/36 , C07C211/50
摘要： A process for preparing tolylenediamine by hydrogenating dinitrotoluene with hydrogen in the presence of a suspended catalyst in a vertically upright reactor (1), at the upper end of which is arranged a motive jet nozzle (2) through which the reaction mixture drawn off from the reactor bottom, via an external loop, is sprayed into the upper region of the reactor (1) and then flows into a central inserted tube (4) which is arranged in the longitudinal direction of the reactor, flows through the latter from the top downward and flows upward again outside the inserted tube (4) in an internal loop motion, with a heat exchanger (6) in the interior of the reactor (1), through which cooling water flows, and absorbs some of the heat of reaction as it does so, with a feed for the dinitrotoluene at the upper end of the reactor (1) and a feed for the hydrogen at the lower end of the reactor (1), and wherein, in addition to the heat exchanger (6) arranged in the interior of the reactor (1), a further heat exchanger (W) is used in the external loop, in which water absorbs the rest of the heat of reaction by indirect heat exchange with the reaction mixture, which comprises utilizing the heat of reaction to raise steam with a pressure of at least 4 bar gauge by performing the hydrogenation of dinitrotoluene to tolylenediamine at a temperature of ≧180° C.
摘要翻译：一种通过在悬浮催化剂存在下用氢气将二硝基甲苯氢化在垂直直立反应器（1）中来制备甲苯二胺的方法，其上端设置有动力喷嘴（2），反应混合物从其中排出反应器底部通过外部环路喷射到反应器（1）的上部区域中，然后流入沿着反应器的纵向布置的中心插入管（4），其从顶部向下流动并且在反应器（1）的内部具有热交换器（6），内部循环运动再次向外流过插入的管（4），冷却水通过该换热器（6）流过，并吸收一些反应热用反应器（1）上端的二硝基甲苯进料和反应器（1）下端的氢气进料，并且其中除了设置在反应器（1）的下端的热交换器反应器（1）的内部，一个furt 她的热交换器（W）用于外部回路中，其中水通过与反应混合物的间接热交换吸收剩余的反应热，其中包括利用反应热量以至少4的压力升高蒸汽通过在> = 180℃的温度下进行二硝基甲苯氢化成甲苯二胺来测定。

28. 发明授权

US07851661B2 Method for producing dinitrotoluene 有权
标题翻译：二硝基甲苯生产方法
公开(公告)号：US07851661B2
公开(公告)日：2010-12-14
申请号：US10586683
申请日：2005-02-02
申请人： Johannes Buettner , Wolfgang Mackenroth , Heinrich Hermann , Peter Konieczny , Juergen Gebauer
发明人： Johannes Buettner , Wolfgang Mackenroth , Heinrich Hermann , Peter Konieczny , Juergen Gebauer
IPC分类号： C07C205/00
CPC分类号： C07C201/08 , C07C201/14 , C07C205/06
摘要： The present invention provides a process for preparing dinitrotoluene, comprising the steps of a) reacting toluene with nitric acid in the presence of sulphuric acid to give mononitrotoluene, b) separating the reaction product from step a) into an organic phase comprising mononitrotoluene and an aqueous phase comprising sulfuric acid, c) reacting the organic phase comprising mononitrotoluene with nitric acid in the presence of sulphuric acid to give dinitrotoluene, d) separating the reaction product from step c) into an organic phase comprising dinitrotoluene and an aqueous phase comprising sulfuric acid, wherein the reaction product from step a) has a content of toluene of from 3.0 to 8% by weight, based on the organic phase, and a content of nitric acid of from 0.1 to 1.2% by weight, based on the aqueous phase, and the phase separation in step b) is effected in such a way that further reaction of the toluene with the nitric acid is prevented.
摘要翻译：本发明提供了制备二硝基甲苯的方法，包括以下步骤：a）在硫酸存在下使甲苯与硝酸反应得到一硝基甲苯，b）将步骤a）中的反应产物分离成包含单硝基甲苯和水相，包括硫酸，c）在硫酸存在下使包含一硝基甲苯的有机相与硝酸反应，得到二硝基甲苯，d）将步骤c）中的反应产物分离成包含二硝基甲苯和含有硫酸的水相的有机相，其中步骤a）的反应产物的甲苯含量为3.0-8重量％，基于有机相，硝酸含量为0.1-1.2重量％，基于水相，和步骤b）中的相分离是以防止甲苯与硝酸进一步反应的方式进行的。

29. 发明授权

US07851648B2 Method for the continuous production of isocyanates 有权
标题翻译：连续生产异氰酸酯的方法
公开(公告)号：US07851648B2
公开(公告)日：2010-12-14
申请号：US10539802
申请日：2003-12-13
申请人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Juergen Pallasch , Rene Leuthold , Andreas Brodhagen , Andreas Woelfert , Wolfgang Mackenroth , Markus Maurer
发明人： Martin Sohn , Eckhard Stroefer , Filip Nevejans , Ulrich Penzel , Hans-Juergen Pallasch , Rene Leuthold , Andreas Brodhagen , Andreas Woelfert , Wolfgang Mackenroth , Markus Maurer
IPC分类号： C07C249/00
CPC分类号： C07C263/10 , C07C265/14
摘要： The invention relates to a process for preparing polyisocyanates by reacting organic amines with phosgene, wherein the reaction is carried out in at least three stages, with the first stage being carried out in a mixing apparatus, the second stage in at least one residence apparatus and the third stage in at least one separation apparatus and the pressure in each successive stage being lower than that in the previous stage.
摘要翻译：本发明涉及一种通过使有机胺与光气反应制备多异氰酸酯的方法，其中反应进行至少三个阶段，第一阶段在混合装置中进行，第二阶段在至少一个停留装置中进行，在至少一个分离装置中的第三阶段，并且每个连续阶段中的压力低于前一阶段的压力。

30. 发明授权

US07838702B2 Direct amination of hydrocarbons 失效
标题翻译：碳氢化合物的直接胺化
公开(公告)号：US07838702B2
公开(公告)日：2010-11-23
申请号：US12280070
申请日：2007-02-13
申请人： Frederik Van Laar , Ekkehard Schwab , Joachim-Thierry Anders , Sven Crone , Karl Hoelemann , Wolfgang Mackenroth , Petr Kubanek
发明人： Frederik Van Laar , Ekkehard Schwab , Joachim-Thierry Anders , Sven Crone , Karl Hoelemann , Wolfgang Mackenroth , Petr Kubanek
IPC分类号： C07C209/02 , C07C209/60
CPC分类号： C07C209/02 , C07C211/46
摘要： A process for aminating hydrocarbons with ammonia, wherein the N2 content in the mixture at the reactor exit is less than 0.1% by volume based on the total volume of the mixture at the reactor exit.
摘要翻译：用氨胺化胺的方法，其中反应器出口处混合物中的N 2含量基于反应器出口处混合物的总体积小于0.1体积％。

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