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    • 6. 发明申请
    • CONJUGATED POLYMERS AS MATERIALS FOR SOLID STATE LASERS
    • 作为固体激光材料的共聚聚合物
    • WO1998003566A1
    • 1998-01-29
    • PCT/US1997012026
    • 1997-07-11
    • THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
    • THE REGENTS OF THE UNIVERSITY OF CALIFORNIADIAZ-GARCIA, MariaSCHWARTZ, BenjaminHIDE, FumitomoHEEGER, Alan, J.
    • C08F112/12
    • H01S3/14C08G61/00H01S3/0635H01S5/30
    • Solid state lasers based upon conjugated polymers are disclosed. A conjugated polymer useful in the practice of this invention is a conjugated polymer which has a ground state and an excited state and which, in the form of a nondiluted thin film, meets the criteria of: i) having a strong absorption in the ground state with an absorption coefficient of at least about 10 cm and an absorption depth not greater than about 1 mu m; ii) having an efficient luminescence emission from the excited state; this emission being shifted to lower energy relative to the ground state absorption: and iii) providing stimulated emission which is not overwhelmed by photoinduced absorption, such that the thin film exhibits gain narrowing and amplified spontaneous emission. These conjugated polymers have gain lengths in the micron or even sub-micron regime and therefore exhibit laser action with low pumping threshold as thin solid films with thicknesses in the micron or even sub-micron regime.
    • 公开了基于共轭聚合物的固态激光器。 可用于实施本发明的共轭聚合物是具有基态和激发态的共轭聚合物,其以非稀释薄膜的形式满足以下标准:i)在基态下具有强吸收 其吸收系数为至少约10 -4 cm -1,吸收深度不大于约1μm; ii)具有来自激发态的有效发光发射; 该发射被转移到相对于基态吸收的较低能量:和iii)提供不被光诱导吸收所淹没的受激发射,使得薄膜表现出增益变窄和放大的自发发射。 这些共轭聚合物具有微米或甚至亚微米状态的增益长度,因此具有低泵浦阈值的激光作用,其厚度为微米或甚至亚微米的薄固体薄膜。