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1. 发明申请

WO2004014552A1 A PHOSPHA-ADAMANTANE (S) CATALYTIC SYSTEM 审中-公开
标题翻译： PHOSPHA-ADAMANTANE（S）催化体系
公开(公告)号：WO2004014552A1
公开(公告)日：2004-02-19
申请号：PCT/GB2003/003419
申请日：2003-08-06
申请人： LUCITE INTERNATIONAL UK LIMITED , EASTHAM, Graham, Ronald , CAMERON, Paul, Andrew , TOOZE, Robert, Paul , CAVELL, Kingsley, John , EDWARDS, Peter, Gerald , COLEMAN, Dennis, Lee
发明人： EASTHAM, Graham, Ronald , CAMERON, Paul, Andrew , TOOZE, Robert, Paul , CAVELL, Kingsley, John , EDWARDS, Peter, Gerald , COLEMAN, Dennis, Lee
IPC分类号： B01J31/24
CPC分类号： B01J31/1895 , B01J31/2457 , B01J35/0013 , B01J2231/321 , B01J2531/0258 , B01J2531/60 , B01J2531/80 , B01J2531/824 , C07C67/38 , C07C2603/74 , C07F9/5018 , C07F9/5027 , C07F9/5045 , C07F9/52 , C07C69/24 , C07C69/67
摘要： A catalyst system capable of catalysing the carbonylation of an olefinally unsaturated compound is described. The 5 catalyst system is obtainable by combining: (a) a metal of Group VIB or Group VIII B or a compound thereof; and (b) a bidentate phosphine of general formula (I) Ad) s (CR 4 R 5 R 6 ) T Q 2 -A- (K, D) Ar (E, Z) -B-Q 1 (Ad) u (CR 1 R 2 R 3 ) v . Ad represents an optionally substituted adamantyl radical bonded to the phosphorous atom via any one of its tertiary carbon atoms. A method of production of the catalyst is also illustrated.
摘要翻译：描述了能够催化烯属不饱和化合物羰基化的催化剂体系。 5催化剂体系可通过以下方法获得：（a）VIB族或VIIIB族金属或其化合物; 和（b）通式（I）的二齿膦Ad）s（CR 4 R 5 R 6）TQ 2 -A-（K，D）Ar（E，Z）-BQ （Ad）u（CR 1 R 2 R 3）v。Ad表示任意取代的金刚烷基，其通过其叔碳原子中的任何一个与磷原子键合。还示出了催化剂的生产方法。

2. 发明申请

WO1998011274A1 PRE-TREATMENT OF STEEL 审中-公开
标题翻译：预处理钢
公开(公告)号：WO1998011274A1
公开(公告)日：1998-03-19
申请号：PCT/GB1997002495
申请日：1997-09-12
申请人： BRITISH STEEL PLC , BAIRD, Amanda, Jane , JEFFS, Brian, David , EDWARDS, Peter, Gerald , GOODWIN, Terence, John
发明人： BRITISH STEEL PLC
IPC分类号： C23C22/68
CPC分类号： C23C22/50 , C23C22/53 , C23C22/68
摘要： The application discloses a method of pre-treating steel articles, in particular galvanised steel articles, prior to application of one or more paint layers. A pre-treatment compound is disclosed which comprises the complex formable in solution by immersion of a metallic species in a solution of the compound R-PO(OH)2, where R includes an organic group. The metal can be in native form or as a salt. A solution of this complex can be used as a pre-treatment bath for steel items, resulting in superior adhesion of the paint layer. The application refers to the complex, a solution of the complex, the use of the complex as a coating, and to a method of coating a steel article involving the complex. The R group preferably includes at least one of an epoxy, hydroxy, unsaturated hydrocarbon, amide or carboxylic group, or a combination thereof. Suitable unsaturated hydrocarbon groups include alkenes, vinyl or acrylate groups. Other preferred forms are those in which the R group includes an aliphatic chain to which the paint layer can form an interlocking network. Such a chain is preferably at least C4 long and may be substituted. A solution of the invention preferably includes an accelerator compound, such as peroxide, which may be present in a catalytic amount.
摘要翻译：该申请公开了在施加一个或多个涂料层之前预处理钢制品，特别是镀锌钢制品的方法。公开了一种预处理化合物，其包含通过将金属物质浸入化合物R-PO（OH）2的溶液中而形成的复合物，其中R包括有机基团。金属可以是天然形式或盐。该复合物的溶液可用作钢制品的预处理浴，导致涂料层的优异粘附性。应用是指复合物，复合物的溶液，复合物作为涂层的使用，以及涉及复合物的钢制品的涂布方法。 R基团优选包括环氧基，羟基，不饱和烃，酰胺或羧基中的至少一种或其组合。合适的不饱和烃基包括烯烃，乙烯基或丙烯酸酯基团。其它优选的形式是其中R基团包括脂族链的那些，其中涂料层可以形成互锁网络。这样的链优选为至少C4长，并且可以被取代。本发明的溶液优选包括可以以催化量存在的促进剂化合物，例如过氧化物。

3. 发明申请

WO0164698A3 MACROCYCLIC LIGANDS AND COMPLEXES THEREOF 审中-公开
标题翻译： MACROCYCLIC配偶及其复合物
公开(公告)号：WO0164698A3
公开(公告)日：2002-01-31
申请号：PCT/GB0100911
申请日：2001-03-01
申请人： UNIV CARDIFF , EDWARDS PETER GERALD , NEWMAN PAUL DAVID
发明人： EDWARDS PETER GERALD , NEWMAN PAUL DAVID
IPC分类号： C07F9/6568 , C07F17/00 , C07F17/02 , C07F15/02 , A61K31/66 , B01J31/24 , C07F9/02 , C07F9/50
CPC分类号： C07F17/00 , C07F9/65683 , C07F17/02
摘要： A complex of formula (I) where M represents Fe(II), Co(III) or Mn(I); n is 0 or 1; x represents an optionally substituted ring system selected from (a), (b).
摘要翻译：其中M表示Fe（II），Co（III）或Mn（I）的式（I）的络合物; n为0或1; x表示选自（a），（b）的任选取代的环系。

4. 发明申请

WO1997007123A1 CYCLIC PHOSPHINES, PHOSPHINE OXIDES AND COMPLEXES THEREOF 审中-公开
标题翻译：环磷酰胺，磷酸氧化物及其复合物
公开(公告)号：WO1997007123A1
公开(公告)日：1997-02-27
申请号：PCT/GB1996001943
申请日：1996-08-09
申请人： UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED , EDWARDS, Peter, Gerald , FLEMING, James, Stephen , LIYANAGE, Sudantha, Susila, Lekam, Wasam
发明人： UNIVERSITY COLLEGE CARDIFF CONSULTANTS LIMITED
IPC分类号： C07F09/6568
CPC分类号： B01J31/2438 , B01J31/1875 , B01J2531/16 , B01J2531/62 , B01J2531/821 , B01J2531/822 , B01J2531/842 , B01J2531/847 , C07F1/005 , C07F9/65683 , C07F9/65685 , C07F15/0053 , C07F15/008 , C07F15/025
摘要： The invention relates to processes for the preparation of phosphine derivatives, to certain novel phosphine derivatives obtainable by this process and to their uses, for example in catalysis. In particular, to a process for the preparation of a compound of formula (I) where R , R and R may be the same or different and are hydrogen, or optionally substituted hydrocarbyl or optionally substituted heterocyclyl groups; and X, Y and Z may be the same or different and are optionally substituted alkylene or arylene groups.
摘要翻译：本发明涉及制备膦衍生物的方法，可通过该方法获得的某些新的膦衍生物及其用途，例如在催化中。特别地，关于制备式（I）化合物的方法，其中R 1，R 2和R 3可以相同或不同，为氢，或任选取代的烃基或任选取代的杂环基组; 并且X，Y和Z可以相同或不同，并且是任选取代的亚烷基或亚芳基。

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