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1. 发明申请

WO2014064466A3 BIFUNCTIONAL ORGANIC CATALYSTS 审中-公开
标题翻译：双功能有机催化剂
公开(公告)号：WO2014064466A3
公开(公告)日：2014-06-12
申请号：PCT/GB2013052808
申请日：2013-10-28
申请人： ISIS INNOVATION , DIXON DARREN J , FARLEY ALISTAIR J M , N EZ MARTA G
发明人： DIXON DARREN J , FARLEY ALISTAIR J M , N EZ MARTA G
IPC分类号： B01J31/02
CPC分类号： B01J31/0271 , B01J31/0218 , B01J31/0232 , B01J31/0241 , B01J31/0249 , B01J31/0267 , B01J2231/346 , C07C335/20 , C07D207/16 , C07F9/5054 , C07F9/5355 , C07F9/588 , C07F9/65515 , C07F9/655345
摘要： The present invention provides a bifunctional catalyst of the formula (1): wherein: each R1 is independently selected from an optionally substituted alkyl group, an optionally substituted cycloalkyl group, an optionally substituted aryl group, an optionally substituted heteroaryl group, an optionally substituted aralkyl group and an optionally substituted alkaryl group; Z represents a divalent organic linking moiety optionally containing one or more stereocentres; and EWG represents an electron-withdrawing group.
摘要翻译：本发明提供了式（1）的双官能催化剂：其中：每个R 1独立地选自任选取代的烷基，任选取代的环烷基，任选取代的芳基，任选取代的杂芳基，任选取代的芳烷基基团和任选取代的烷芳基; Z表示任选含有一个或多个立体中心的二价有机连接部分; EWG代表吸电子基团。

2. 发明申请

WO2010022388A2 CATALYSTS AND METHODS FOR POLYMER SYNTHESIS 审中-公开
标题翻译：聚合物合成的催化剂和方法
公开(公告)号：WO2010022388A2
公开(公告)日：2010-02-25
申请号：PCT/US2009/054773
申请日：2009-08-24
申请人： NOVOMER, INC. , ALLEN, Scott, D. , CHERIAN, Anna, E. , SIMONEAU, Chris, A. , FARMER, Jay, J. , COATES, Geoffrey, W. , GRIDNEV, Alexei , LAPOINTE, Robert, E.
发明人： ALLEN, Scott, D. , CHERIAN, Anna, E. , SIMONEAU, Chris, A. , FARMER, Jay, J. , COATES, Geoffrey, W. , GRIDNEV, Alexei , LAPOINTE, Robert, E.
IPC分类号： C08G64/34 , B01J31/22
CPC分类号： C07F15/065 , B01J31/0239 , B01J31/0259 , B01J31/0265 , B01J31/182 , B01J31/183 , B01J31/1835 , B01J31/2243 , B01J2531/0238 , B01J2531/025 , B01J2531/0252 , B01J2531/0294 , B01J2531/31 , B01J2531/62 , B01J2531/845 , C07C251/24 , C07C279/12 , C07C2601/14 , C07D213/53 , C07D487/04 , C07D487/22 , C07F9/5355 , C07F9/6561 , C07F19/005 , C08F4/80 , C08G64/34
摘要： The present invention provides unimolecular metal complexes having increased activity in the copolymerization of carbon dioxide and epoxides. Also provided are methods of using such metal complexes in the synthesis of polymers. According to one aspect, the present invention provides metal complexes comprising an activating species with co-catalytic activity tethered to a multidentate ligand that is coordinated to the active metal center of the complex.
摘要翻译：本发明提供在二氧化碳和环氧化物的共聚合中具有增加的活性的单分子金属络合物。还提供了在合成聚合物中使用这种金属络合物的方法。根据一个方面，本发明提供了包含活性物质的金属络合物，所述活性物质具有与配位于配合物的活性金属中心的多齿配体连接的共催化活性。

3. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

4. 发明申请

WO2003044011A1 PYRROLE SYNTHESIS 审中-公开
标题翻译：光子合成
公开(公告)号：WO2003044011A1
公开(公告)日：2003-05-30
申请号：PCT/EP2002/012747
申请日：2002-11-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ÖHRLEIN, Reinhold , BAISCH, Gabriele
发明人： ÖHRLEIN, Reinhold , BAISCH, Gabriele
IPC分类号： C07D405/06
CPC分类号： C07D207/323 , C07D207/337 , C07D209/08 , C07F9/5355 , C07F9/6552
摘要： The invention relates to a novel process for the preparation of N-substituted pyrroles, especially of formula (V), wherein the radicals are as defined in the description, by intermolecular aza-Wittig reaction starting from organic azides and 1,4-dioxo compounds. The invention relates also to novel iminophosphorane intermediates for this synthesis. The resulting pyrroles are useful, for example, in the organic synthesis of pharmaceuticals or other active substances and chemicals.
摘要翻译：本发明涉及一种用于制备N-取代的吡咯，特别是式（Ⅴ）的新方法，其中基团如描述中所定义，通过分子间氮杂 - 维蒂希反应从有机叠氮化物和1,4-二氧代化合物开始。本发明还涉及用于该合成的新型亚氨基磷酰中间体。得到的吡咯可用于例如药物或其它活性物质和化学品的有机合成。

5. 发明申请

WO0249992A2 PROCESS FOR PREPARING SUBSTITUTED ORGANIC COMPOUNDS AND METHOD OF USING A CATALYST FOR SUBSTITUTION REACTION 审中-公开
标题翻译：制备取代有机化合物的方法和使用催化剂进行替代反应的方法
公开(公告)号：WO0249992A2
公开(公告)日：2002-06-27
申请号：PCT/EP0114871
申请日：2001-12-17
申请人： SYMYX TECHNOLOGIES INC , KUEHLEIN KLAUS , WASSERSCHEID PETER
发明人： KUEHLEIN KLAUS , WASSERSCHEID PETER
IPC分类号： C07B39/00 , C07C17/20 , C07C253/30 , C07C255/50 , C07F9/535
CPC分类号： C07F9/5355 , C07B39/00 , C07C17/208 , C07C253/30 , C07C25/13 , C07C255/50
摘要： Disclosed is a process for exchanging substituents, for example chlorine by fluorine, in organic compounds. The process encompasses the application of a compound of Formula (IV) as a catalyst, wherein the R's independently of one another are aliphatic, cycloaliphatic, aromatic or araliphatic groups, A is a q-valent anion and q is an integer from 1-3.
摘要翻译：公开了在有机化合物中交换取代基例如氟的取代基的方法。该方法包括式（Ⅳ）化合物作为催化剂的应用，其中R 3彼此独立地为脂族，脂环族，芳族或芳脂族基团，A q为q价阴离子，q为整数从1-3。

6. 发明申请

WO00005237A1 CATALYST COMPONENT HAVING AT LEAST A PHOSPHINIMINE LIGAND AND A HETEROATOM LIGAND 审中-公开
标题翻译：具有至少一种磷酰胺配体和异源配体的催化组分
公开(公告)号：WO00005237A1
公开(公告)日：2000-02-03
申请号：PCT/CA1999/000525
申请日：1999-06-08
IPC分类号： C07F7/10 , C07F7/28 , C07F9/50 , C07F9/535 , C07F9/59 , C07F19/00 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C07F7/00 , C07F7/30
CPC分类号： C08F10/00 , C07F9/5355 , C07F9/591 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/05 , Y10S526/901 , C08F4/64 , C08F4/659 , C08F2500/12 , C08F210/14 , C08F2500/08
摘要： Organometallic complexes having a phosphinimine ligand, a (non-phosphinimine) heteroligand and at least one activatable ligand are catalyst components for olefin polymerization. Preferred polymerization systems are prepared by combining the organometallic complexes with an ionic activator and/or an alumoxane. Preferred catalyst components contain Ti, Zr or Hf and are activated with an ionic activator to provide ethylene polymerization catalysts.
摘要翻译：具有膦亚胺配体，（非膦亚胺）杂配位体和至少一种可活化配体的有机金属络合物是用于烯烃聚合的催化剂组分。通过将有机金属配合物与离子活化剂和/或铝氧烷组合来制备优选的聚合体系。优选的催化剂组分含有Ti，Zr或Hf，并用离子活化剂活化以提供乙烯聚合催化剂。

7. 发明申请

WO2009068000A2 CYCLOPENTADIENYLPHOSPHAZENE COMPLEXES (CpPN COMPLEXES) OF METALS OF THE THIRD AND FOURTH GROUP AND OF THE LANTHANOIDS 审中-公开
标题翻译：第三和第四组金属的环戊二烯基膦基苯配合物（CpPN配合物）和第三和第四族的金属
公开(公告)号：WO2009068000A2
公开(公告)日：2009-06-04
申请号：PCT/DE2008001942
申请日：2008-11-25
申请人： UNIV MARBURG PHILIPPS , SUNDERMEYER JOERG , RUFANOV KONSTANTIN , PETROV ALEXANDER , ELFFERDING MICHAEL , WINKENSTETTE MANUEL
发明人： SUNDERMEYER JOERG , RUFANOV KONSTANTIN , PETROV ALEXANDER , ELFFERDING MICHAEL , WINKENSTETTE MANUEL
IPC分类号： C07F17/00 , C07F9/6581 , C08F4/00
CPC分类号： C07F17/00 , C07F9/5352 , C07F9/5355 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F2420/01 , C08F4/6592 , C08F4/52
摘要： The invention relates to cyclopentadienylphosphazene complexes (CpPN complexes) of metals of the III. and VI. group and of the lanthanoids except for lutetium. The complexes of the invention are isolobal and isoelectric with respect to the [(CpSiN)TiR2] complexes. There is exactly one CpPN moiety in the complexes of the invention. The cyclopentadienyl moiety of CpPN represents a monodentate, anionic ligand of the metal atom in all complexes of the invention. The metal atom is also bound to other anionic ligands. In a preferred embodiment, both the cyclopenadienyl moiety and the nitrogen atom within CpPN bind to the metal atom so that CpPN represents a bidentate ligand. Complexes in which CpN represents a bidentate ligand are CpPN Constrained Geometry Complexes (CpPN-CGC). The invention also relates to methods for producing the complexes in situ. The CpPN complexes can be electrically neutral or be present as cationic complexes. Cationic complexes are formed when one of the other anionic ligands of the metal atom is replaced by a neutral ligand; counterions of the cationic CpPN complexes are preferably fluoroborate, tetraphenyl borate, tetrakis-(3,5-trifluormethylphenyl)borate. The complexes are produced in situ by reacting a metal halide with a protonated cyclopentadienylphosphazene CpPNH and an alkaline or alkaline earth salt of the desired other anionic ligand. The complexes according to the invention can be used as catalysts for the hydroamination and polymerization of polyolefins.
摘要翻译：本发明涉及III族金属的环戊二烯基磷腈络合物（CpPN络合物）。和IV。族以及除l以外的镧系元素。本发明的配合物是等容和等电子的[（CpSiN）TiR 2]配合物。在根据本发明的配合物中，恰好存在一个CpPN单元。在本发明的所有配合物中，CpPN的环戊二烯基部分是金属原子的单齿阴离子配体，金属原子也与其它阴离子配体连接。在一个优选的实施方案中，环戊二烯基部分和CpPN内的氮原子都与金属原子结合，使得CpPN表示二齿配体。其中CpN代表双齿配体的本发明配合物是CpPN约束几何配合物（CpPN-CGC）。此外，提供了原位制备本发明配合物的方法。 CpPN配合物可以是电中性的或者以阳离子配合物存在。出现阳离子配合物，其中金属原子的其他阴离子配体之一被中性配体取代; 阳离子CpPN配合物的平衡离子优选为氟硼酸盐，四苯基硼酸盐，四 - （3,5-三氟甲基苯基）硼酸盐。该制备通过使金属卤化物与质子化的环戊二烯基磷腈CpPNH和所需的其他阴离子配体的碱金属或碱土金属盐反应而原位进行。本发明的络合物可以用作烯烃的加氢胺化和聚合的催化剂。

8. 发明申请

WO2007071320A1 ZWITTERIONIC PHOSPHINIMINE CATALYST 审中-公开
标题翻译： ZWITTERICIC磷酰胺催化剂
公开(公告)号：WO2007071320A1
公开(公告)日：2007-06-28
申请号：PCT/EP2006/011642
申请日：2006-12-05
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ZUIDEVELD, Martin, Alexander , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus
发明人： IJPEIJ, Edwin, Gerard , ZUIDEVELD, Martin, Alexander , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus
IPC分类号： C07F9/6506 , C07F9/6503 , B01J31/18
CPC分类号： B01J31/1815 , B01J31/188 , B01J2231/122 , B01J2531/46 , C07F9/5355 , C08F10/00 , C08F4/64113
摘要： The invention relates to an organometallic compound according to formula (I), wherein M is a group 4 metal with valency v, with v being 3 or 4, preferably Ti, Y p is a monoanionic phosphinimine ligand with p ≥ 1, X m is an anionic ligand with m = ≥ 1, with m = v - p - 1 and m being the number of anionic ligands and Q r is a coordinating ligand which is a Lewis base with r ≥ 0 being the number of ligands, and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 can be chosen independently from hydrogen atoms and optionally substituted alkyl or aryl groups having 1 to 20 carbon atoms. The invention further relates to the use of the compound according to Formula (I) as a catalyst for the preparation of polyolefins.
摘要翻译：本发明涉及一种根据式（I）的有机金属化合物，其中M是价态为v的第4族金属，v为3或4，优选Ti，Y为单亚磷酸亚胺配体， p = 1，X m是具有m = = 1的阴离子配体，m = v-p-1，m是阴离子配体的数量，Q 配位配体，其中r = 0的路易斯碱是配体数，R 1，R 2，R 3，R 3， R 5，R 5，R 6，R 7，R 8和R 8，R 8，R 8，可以独立于氢原子和任选取代的具有1至20个碳原子的烷基或芳基选择。本发明还涉及根据式（I）的化合物作为制备聚烯烃的催化剂的用途。

9. 发明申请

WO2005014669A1 IMPROVED METHOD OF PREPARING A HYDROCARBYLATED METAL-ORGANIC COMPOUND 审中-公开
标题翻译：改进的制备金属有机化合物的方法
公开(公告)号：WO2005014669A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/008712
申请日：2004-08-03
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo
发明人： IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo
IPC分类号： C08F10/00
CPC分类号： C07F9/5355 , C07F17/00 , C08F4/65908 , C08F4/6592 , C08F10/00 , C08F210/06 , C08F210/16 , C08F2420/04 , C08F2500/17 , C08F4/64044
摘要： The invention relates to a process for the preparation of a hydrocarbylated metal organic compound, comprising a hydrocarbyl group, a spectator ligand and optionally a ligand, by contacting a metal-organic reagent with a spectator ligand in the presence of at least 2 equivalents of a hydrocarbylating agent. The invention further relates to a hydrocarbylated metal organic compound according to the following formula (I) containing a spectator ligand S equal to (Ar-Z-) s Y(-Z-DR' n ) q , wherein Y represents the an anionic moiety of S bonded to M of the metal-organic compound, Z an optional bridging group between the Y moiety and the DR' n and/or Ar group, D an electron donating hetero atom chosen f rom group 15 or 16, R' an optional substituent, Ar an electron-donating aryl group, n the number of R' groups bonded to D, q and s integers with q + s ≥ 1, wherein Y is an imine radical, or wherein the electron donating hetero atom containing group DR'- n is a ketimide, phosphinimide, guanidine, or iminoimidazoline, or a combination thereof.
摘要翻译：本发明涉及一种制备烃基金属有机化合物的方法，其包括烃基，观察配体和任选的配体，通过使金属有机试剂与观察配体在至少2当量的烃基化剂。本发明还涉及含有等于（Ar-Z-）sY（-Z-DR'n）q的观众配体S的下式（I）的烃基金属有机化合物，其中Y表示 S与金属有机化合物的M键合，Z是Y部分和DR'n和/或Ar基团之间的任选的桥连基，D是选自第15或16族的给电子杂原子，R'是任选的取代基 Ar为给电子芳基，n为与D结合的R'基团的数目，q和s为整数q + s> = 1，其中Y为亚胺基，或其中含有供体杂原子的基团DR' -n是酮酰亚胺，次膦酰亚胺，胍或咪唑并咪唑啉，或其组合。

10. 发明申请

WO2005014664A1 PROCESS FOR THE PREPARATION OF A METAL-ORGANIC COMPOUND COMPRISING AT LEAST ONE IMINE LIGAND 审中-公开
标题翻译：制备包含至少一个IMINE LIGAND的金属有机化合物的方法
公开(公告)号：WO2005014664A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/008711
申请日：2004-08-03
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VON DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
发明人： IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VON DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
IPC分类号： C08F4/64
CPC分类号： C08F10/00 , C07F7/00 , C07F7/28 , C07F7/30 , C07F9/00 , C07F9/5355 , C07F17/00 , C07F19/00 , C08F4/65908 , C08F4/6592 , C08F210/06 , C08F210/16 , C08F2420/04 , C08F2500/17
摘要： The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y=N-H as formula (1), and M v (L 1 ) k (L 2 ) l (L 3 ) m (L 4 ) n X as formula (2),and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L 1 , L 2 , L 3 , and L 4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n = 0, 1, 2, 3, 4 with k+l+m+n+l =V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.
摘要翻译：本发明涉及一种制备金属有机化合物的方法，其包括至少一种膦亚胺配体，其特征在于将根据式（1）的膦亚胺配体的HA加合物与式（1）的金属有机试剂 2）在至少2当量的碱的存在下，其中HA表示酸，其中H表示其质子，A表示其缀合碱，Y = NH，如式（1）所示，M（Ⅴ） k（L2）l（L3）m（L4）nX，其中Y是取代的磷原子，M表示第4族或第5族金属离子，V表示金属离子的化合价， 3，4或5 L1，L2，L3和L4表示M上的配体或17族卤素原子，并且可以相同或不同，k，l，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V，X表示17族卤素原子。本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，所述金属 - 有机化合物在任何地方或之前被活化聚合反应器。

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