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1. 发明申请

WO2004037834A3 RACEMOSELECTIVE PREPARATION OF BRIDGED METALLOCENE COMPLEXES HAVING UNSUBSTITUTED OR 2-SUBSTITUTED INDENYL LIGANDS 审中-公开
标题翻译：具有取代或2-取代的茚基配体的桥式金属茂配合物的经时性选择性制备
公开(公告)号：WO2004037834A3
公开(公告)日：2004-06-24
申请号：PCT/EP0311678
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU HANS-ROBERT-HELLMUTH , MUELLER PATRIK , GARCIA VALERIE , SIDOT CHRISTIAN , TELLIER CHRISTIAN , LELONG JEAN-FRANCOIS , HURIEZ ERIC
发明人： DAMRAU HANS-ROBERT-HELLMUTH , MUELLER PATRIK , GARCIA VALERIE , SIDOT CHRISTIAN , TELLIER CHRISTIAN , LELONG JEAN-FRANCOIS , HURIEZ ERIC
IPC分类号： C07F17/00 , C08F4/60 , C08F4/64 , C08F10/00
CPC分类号： C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing racemic metallocene complexes by reacting transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from -78 to 250 DEG C, to the corresponding metallocene complexes themselves and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使过渡金属配合物与碱金属或碱土金属的环戊二烯基衍生物反应并将以这种方式获得的反应混合物加热至-78-250℃的温度来制备外消旋茂金属配合物的方法，相应的茂金属络合物本身以及它们作为催化剂或作为用于烯属不饱和化合物的聚合或立体选择性合成中的试剂或催化剂的催化剂的组分。

2. 发明申请

WO2004037840A1 RACEMOSELECTIVE SYNTHESIS OF RAC-DIORGANOSILYLBIS(2-METHYLBENZO[E]INDEYL) ZIRCONIUM COMPONDS 审中-公开
标题翻译：异氰脲酸二甲酯（2-甲基苯并[E]吲哚）的组合选择性合成ZIRCONIUM组分
公开(公告)号：WO2004037840A1
公开(公告)日：2004-05-06
申请号：PCT/EP2003/011681
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valerie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-Francois
发明人： DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valerie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-Francois
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C07F15/0073 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The present invention relates to a specific process for the diastereoselective synthesis of racy diorganosilylbis(2methylbenzo[e]indenyl)zirconium compounds of the formula I, by reacting the silyl-bridged bisindenyl ligand with a dihalozirconiumbis(3,5-di-tert-butylphenoxide)- base adduct to form the diorganosilylbis(2-methylbenzo[e]indenyl)zirconium bis(3,5-di-tert-butylphenoxide) and subsequently replacing the phenoxide groups by X using suitable replacement reagents to give the compound of the formula (I); where the substituents X can be identical or different and are each F, CI, Br, I or linear, cyclic or branched C 1-10 -alkyl; and the substituents R can be identical or different and are each linear, cyclic or branched C 1-10 -alkyl or C 6-10 -aryl; and also to the use of these compounds as catalysts.
摘要翻译：本发明涉及通过使甲硅烷基桥连的双茚基配体与二卤代双（3,5-二叔丁基）二苯基膦配位化合物的非对映选择性合成通式I的杂糖二有机甲硅烷基双（2-甲基苯并[e]茚基）丁基苯氧基） - 基加成物形成二有机甲硅烷基双（2-甲基苯并[e]茚基）锆双（3,5-二叔丁基苯酚），随后用合适的替代试剂将X代替苯酚基，得到式（一世）; 其中取代基X可以相同或不同，并且各自为F，Cl，Br，I或直链，环状或支链C 1-10 - 烷基; 并且取代基R可以相同或不同，并且各自是直链，环状或支链C 1-10 - 烷基或C 6-10 - 芳基; 以及这些化合物作为催化剂的使用。

3. 发明申请

WO2005108408A3 PROCESS FOR THE RACEMOSELECTIVE PREPARATION OF ANSA-METALLOCENES 审中-公开
标题翻译：方法制备ANSA-METALLOCENES的方法
公开(公告)号：WO2005108408A3
公开(公告)日：2006-01-05
申请号：PCT/EP2005004832
申请日：2005-05-04
申请人： BASELL POLYOLEFINE GMBH , GARCIA VALERIE , MUELLER PATRIK , SIDOT CHRISTIAN , TELLIER CHRISTIAN , DELANCRAY LUDOVIC , CHEVALIER REYNALD
发明人： GARCIA VALERIE , MUELLER PATRIK , SIDOT CHRISTIAN , TELLIER CHRISTIAN , DELANCRAY LUDOVIC , CHEVALIER REYNALD
IPC分类号： C07F11/00 , C07F17/00
CPC分类号： C07F17/00
摘要： The present invention relates to a process for the racemoselective preparation of ansametallocene complexes of the formula (I) which comprises reacting a ligand starting compound of the formula (II) with a transition metal compound of the formula (III).
摘要翻译：本发明涉及式（I）的顺式选择性配制的顺式选择性制备方法，该方法包括使式（II）的配体起始化合物与式（III）的过渡金属化合物反应。

4. 发明申请

WO2004037839A1 RACEMOSELECTIVE PREPARATION OF ISOLABLE ANSA-METALLOCENE BIPHENOXIDE COMPLEXES 审中-公开
标题翻译：不溶性安非他明烷化二苯醚复合物的选择性制备
公开(公告)号：WO2004037839A1
公开(公告)日：2004-05-06
申请号：PCT/EP2003/011680
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valerie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-François
发明人： DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valerie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-François
IPC分类号： C07F17/00
CPC分类号： C07F17/00
摘要： The invention relates to a process for preparing racemic metallocene biphenoxide complexes by reacting bridged transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from -78 to 250°C, to the corresponding metallocene biphenoxide complexes and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使桥连过渡金属配合物与碱金属或碱土金属的环戊二烯基衍生物反应来制备外消旋茂金属二氧化物络合物的方法，并将以这种方式获得的反应混合物加热至-78至250℃ 对应于相应的金属茂双氧化物络合物，以及它们作为催化剂或作为用于烯属不饱和化合物的聚合的催化剂或作为立体选择性合成中的试剂或催化剂的成分的用途。

5. 发明申请

WO2004037838A1 PREPARATION OF PARTIALLY HYDROGENATED RAC-ANSA-METALLOCENE COMPLEXES 审中-公开
标题翻译：部分加氢仲胺 - 金属茂复合物的制备
公开(公告)号：WO2004037838A1
公开(公告)日：2004-05-06
申请号：PCT/EP2003/011679
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , DUCHIRON, Stéphanie , LELONG, Jean-François
发明人： DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , DUCHIRON, Stéphanie , LELONG, Jean-François
IPC分类号： C07F17/00
CPC分类号： B01J31/2234 , B01J31/2295 , B01J2531/30 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/58 , B01J2531/60 , C07B53/00 , C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing hydrogenated or partially hydrogenated, racemic ansa-metallocene complexes by reacting bridged or unbridged transition metal complexes with alkali metal compounds or alkaline earth metal compounds, heating the resulting reaction mixture to a temperature in the range from -78 to 250°C and at least partially hydrogenating the reaction products in the presence of a suitable catalyst, to the corresponding hydrogenated or partially hydrogenated metallocenes and to their use as catalysts or as a constituent of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及通过使桥联或未桥连的过渡金属配合物与碱金属化合物或碱土金属化合物反应制备氢化或部分氢化的外消旋的仲茂金属络合物的方法，将得到的反应混合物加热至-78℃ 至250℃，并在合适的催化剂存在下将反应产物至少部分氢化至相应的氢化或部分氢化的金属茂，并将其用作催化剂或用作烯属不饱和化合物或试剂的聚合催化剂的用途或立体选择性合成中的催化剂。

6. 发明申请

WO2005058929A1 MESO-SELECTIVE SYNTHESIS OF ANSA-METALLOCENES 审中-公开
标题翻译： MESO选择性合成ANSA-METALLOCENES
公开(公告)号：WO2005058929A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/014247
申请日：2004-12-15
申请人： BASELL POLYOLEFINE GMBH , CHEVALIER, Reynald , GARCIA, Valerie , MÜLLER, Patrik , SIDOT, Christian , TELLIER, Christian , DELANCRAY, Ludovic
发明人： CHEVALIER, Reynald , GARCIA, Valerie , MÜLLER, Patrik , SIDOT, Christian , TELLIER, Christian , DELANCRAY, Ludovic
IPC分类号： C07F17/00
CPC分类号： C07F17/00 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65927
摘要： The present invention relates to a process for the meso-selective preparation of ansa-metallocene complexes of the formula (I), which comprises reacting a ligand starting compound of the formula (II) with a transition metal compound of the formula III, where R 1 , R 1 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R 2 , R 2 are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R 3 is a bulky organic radical which has at least 3 carbon atoms, is bound to the oxygen atom via a nonaromatic carbon or silicon atom and may be substituted by halogen atoms or further organic radicals having from 1 to 20 carbon atoms and may also contain heteroatoms selected from the group consisting of Si, N, P, O and S, T, T’ are identical or different and are each a divalent organic group which has from 1 to 40 carbon atoms and together with the cyclopentadienyl ring forms at least one further saturated or unsaturated, substituted or unsubstituted ring system having a ring size of from 5 to 12 atoms, where T and T’ may contain the heteroatoms Si, Ge, N, P, As, Sb, O, S, Se or Te within the ring system fused to the cyclopentadienyl ring, A is a bridge consisting of a divalent atom or a divalent group, M 1 is an element of group 3, 4, 5 or 6 of the Periodic Table of the Elements or the lanthanides, the radicals X are identical or different and are each an organic or inorganic radical which is able to be replaced by a cyclopentadienyl anion, x is a natural number from 1 to 4, M 2 is an alkali metal, an alkaline earth metal or a magnesium monohalide fragment, p is 1 in the case of doubly positively charged metal ions or 2 in the case of singly positively charged metal ions or metal ion fragments, LB is an uncharged Lewis base ligand, and y is a natural number from 0 to 6, and also the subsequent reaction of these complexes to form ansa-metallocenes of the formula (IV), the use of transition metal compounds of the formula (III) for preparing metallocenes and also transition metal compounds of the formula (III), ansa-metallocene complexes of the formula (I) and the use of these as constituents of catalyst systems for the polymerization of olefines.
摘要翻译：本发明涉及式（I）的硫杂茂金属络合物的中选择性制备方法，其包括使式（II）的配体原料化合物与式III的过渡金属化合物反应，其中R R 1相同或不同，各自为氢或具有1〜40个碳原子的有机基团，R 2，R 2相同或不同，各自为氢或有机基团具有1至40个碳原子的基团，R 3是具有至少3个碳原子的体积大的有机基团，其通过非芳族碳原子或硅原子与氧原子结合，并且可被卤原子或其它有机基团取代具有1至20个碳原子并且还可以含有选自Si，N，P，O和S的杂原子，T，T'相同或不同，并且各自为具有1至40个碳原子的二价有机基团原子和环戊二烯基环一起形成至少一个饱和或不饱和的取代或未取代的环体积为5至12个原子的环系，其中T和T'可含有杂原子Si，Ge，N，P，As，Sb，O，S，Se或Te 与环戊二烯基环稠合的环系，A是由二价原子或二价基团组成的桥，M 1是元素周期表第3,4,5或6族元素或镧系元素，基团X相同或不同，各自为有机或无机基团，其能够被环戊二烯基阴离子代替，x为1至4的自然数，M 2为碱金属，碱土金属或一卤化镁片段，在双正电荷金属离子的情况下，p为1，在带正电荷的金属离子或金属离子片的情况下，p为1，LB为不带电荷的路易斯碱配体，y为0〜6的自然数，以及这些络合物随后的反应形成式（IV）的硫代金属茂，其用途用于制备金属茂的式（III）的过渡金属化合物和式（III）的过渡金属化合物，式（I）的仲茂金属络合物和它们作为用于烯烃聚合的催化剂体系的组分的用途。

7. 发明申请

WO2004037834A2 RACEMOSELECTIVE PREPARATION OF BRIDGED METALLOCENE COMPLEXES HAVING UNSUBSTITUTED OR 2-SUBSTITUTED INDENYL LIGANDS 审中-公开
标题翻译：具有非取代或二取代的茚基配位体的桥联金属络合物的选择性制备
公开(公告)号：WO2004037834A2
公开(公告)日：2004-05-06
申请号：PCT/EP2003/011678
申请日：2003-10-22
申请人： BASELL POLYOLEFINE GMBH , DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-François , HURIEZ, Eric
发明人： DAMRAU, Hans-Robert-Hellmuth , MÜLLER, Patrik , GARCIA, Valérie , SIDOT, Christian , TELLIER, Christian , LELONG, Jean-François , HURIEZ, Eric
IPC分类号： C07F
CPC分类号： C07F17/00 , C08F10/00 , Y10S526/943 , C08F4/65927
摘要： The invention relates to a process for preparing racemic metallocene complexes by reacting transition metal complexes with cyclopentadienyl derivatives of alkali metals or alkaline earth metals and heating the reaction mixture obtained in this way to a temperature in the range from -78 to 250 °C, to the corresponding metallocene complexes themselves and to their use as catalysts or as constituents of catalysts for the polymerization of olefinically unsaturated compounds or as reagents or catalysts in stereoselective synthesis.
摘要翻译：本发明涉及一种通过使过渡金属络合物与碱金属或碱土金属的环戊二烯基衍生物反应制备外消旋茂金属络合物的方法，并将以这种方式获得的反应混合物加热至-78至250℃的温度，相应的茂金属络合物本身以及它们作为催化剂或用作烯属不饱和化合物的聚合催化剂或作为立体选择性合成中的试剂或催化剂的成分的用途。

8. 发明申请

WO2005108408A2 PROCESS FOR THE RACEMOSELECTIVE PREPARATION OF ANSA-METALLOCENES 审中-公开
标题翻译：方法制备ANSA-METALLOCENES的方法
公开(公告)号：WO2005108408A2
公开(公告)日：2005-11-17
申请号：PCT/EP2005/004832
申请日：2005-05-04
申请人： BASELL POLYOLEFINE GMBH , GARCIA, Valerie , MÜLLER, Patrik , SIDOT, Christian , TELLIER, Christian , DELANCRAY, Ludovic , CHEVALIER, Reynald
发明人： GARCIA, Valerie , MÜLLER, Patrik , SIDOT, Christian , TELLIER, Christian , DELANCRAY, Ludovic , CHEVALIER, Reynald
IPC分类号： C07F17/00
CPC分类号： C07F17/00
摘要： The present invention relates to a process for the racemoselective preparation of ansametallocene complexes of the formula (I) which comprises reacting a ligand starting compound of the formula (II) with a transition metal compound of the formula (III) where R 1 , R 1’ are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R 2 , R 2’ are identical or different and are each hydrogen or an organic radical having from 1 to 40 carbon atoms, R 3 is an organic having from 1 to 40carbon atoms.
摘要翻译：本发明涉及一种式（I）的顺式选择性制备磺酰亚胺配合物的方法，该方法包括使式（II）的配体起始化合物与式（III）的过渡金属化合物反应，其中R 1， R 1相同或不同，各自为氢或具有1至40个碳原子的有机基团，R 2，R 2'相同或不同，并且各自为氢或具有1以上的有机基团至40个碳原子，R 3是具有1至40个碳原子的有机物。

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