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    • 8. 发明申请
    • 2, 2'-AZINO-BIS-THIAZOLINES AND USES THEREOF AS AIR- AND WATER- STABLE RADICAL PRECURSORS
    • 2,2'-AZINO-BIS-THIAZOLINES及其作为空气和水稳定放射性前体的用途
    • WO2005026136A3
    • 2005-06-23
    • PCT/FR2004002320
    • 2004-09-13
    • ARMAND MICHELHAMMAMI AMERCAVALIE-KOSHEIRY HICHAM
    • ARMAND MICHELHAMMAMI AMERCAVALIE-KOSHEIRY HICHAM
    • C07D277/18C07D277/50C07D417/14
    • C07D417/14C07D277/18C07D277/50
    • The invention concerns a chemical compound of general formula (I), wherein: RF and R'F', identical or different, represent each a halogen atom or an organic group selected among an alkyl, an alkenyl, an aralkyl, and alkyl-alkenyl, an aryl-alkenyl, said groups being linear or branched, a cycloalkyl, an aryl containing 1 to 28 carbon atoms, said organic group being halogenated, for example at least 40 % of its hydrogen atoms being substituted by a halogen, said organic group optionally comprising one or several heteroatoms such as -O-, =N-, -S-, =P-, =(P=O)-, -SO-, -SO2-, and RF and R'F' are each optionally part of a polymeric chain or a network; R and R', identical or different, represent each an organic group having 1 to 400 carbon atoms, and are each optionally part of a polymeric chain or of a network; R1 and R , identical or different, have each one of the meanings of R and may also represent a hydrogen atom. The invention also concerns the use of such compounds as air- and water-stable radical precursors.
    • 本发明涉及通式(I)的化合物,其中:相同或不同的RF和R'F'表示卤素原子或选自烷基,链烯基,芳烷基和烷基 - 烯基中的有机基团 ,芳基 - 烯基,所述基团是直链或支链的,环烷基,含有1至28个碳原子的芳基,所述有机基团被卤化,例如其氢原子的至少40%被卤素取代,所述有机基团 任选地包含一个或多个杂原子,例如-O - , - N - , - S-,= P - ,=(P = O) - , - SO-,-SO 2 - ,以及RF和R' 聚合物链或网络的一部分; R和R'相同或不同,表示每个具有1至400个碳原子的有机基团,并且各自任选为聚合物链或网络的一部分; R 1和R 1'相同或不同,具有R的每个含义并且也可以表示氢原子。 本发明还涉及这种化合物如空气和水稳定的前体的用途。