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1. 发明申请

WO2005081789A3 Formation of CIGS Absorber Layer by Atomic Layer Deposition 审中-公开
标题翻译：通过原子层沉积形成CIGS吸收层
公开(公告)号：WO2005081789A3
公开(公告)日：2007-02-08
申请号：PCT/US2005003748
申请日：2005-02-07
申请人： NANOSOLAR INC , SAGER BRIAN M , ROSCHEISEN MARTIN R , LEIDHOLM CRAIG
发明人： SAGER BRIAN M , ROSCHEISEN MARTIN R , LEIDHOLM CRAIG
IPC分类号： C23C16/00
摘要： An absorber layer may be formed on a substrate using atomic layer deposition reactions. An absorber layer containing elements of groups IB, IIIA and VIB may be formed by placing a substrate in a treatment chamber and performing atomic layer deposition of a group IB element and/or one or more group IIIA elements from separate sources onto a substrate to form a film. A group VIA element is then incorporated into the film and annealed to form the absorber layer. The absorber layer may be greater than about 25 nm thick. The substrate may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The coiled substrate may be placed in a treatment chamber where substantially an entire surface of the one or more coiled substrates may be treated by an atomic layer deposition process. One or more group IB elements and/or one or more group IIIA elements may be deposited onto the substrate in a stoichiometrically controlled ratio by atomic layer deposition using one or more self limiting reactions.
摘要翻译：可以使用原子层沉积反应在衬底上形成吸收层。包含IB，IIIA和VIB族元素的吸收层可以通过将基底放置在处理室中并且将IB族元素和/或一种或多种IIIA族元素从单独的源原子层沉积到基底上形成，以形成一个电影。然后将VIA族元素并入膜中并退火以形成吸收层。吸收层可以大于约25nm厚。衬底可以被卷绕成一个或多个线圈，使得线圈的相邻匝不彼此接触。卷绕的基板可以放置在处理室中，其中可以通过原子层沉积工艺来处理一个或多个卷绕的基板的基本上整个表面。可以通过使用一个或多个自限制反应的原子层沉积以化学计量控制的比例将一个或多个IB族元素和/或一个或多个IIIA族元素沉积到基底上。

2. 发明申请

WO2007065096A3 CHALCOGENIDE SOLAR CELLS 审中-公开
标题翻译： CHALCOGENIDE太阳能电池
公开(公告)号：WO2007065096A3
公开(公告)日：2007-12-21
申请号：PCT/US2006061324
申请日：2006-11-29
申请人： NANOSOLAR INC , VAN DUREN JEROEN K J , BOLLMAN BRENT , ROSCHEISEN MARTIN R , SAGER BRIAN M
发明人： VAN DUREN JEROEN K J , BOLLMAN BRENT , ROSCHEISEN MARTIN R , SAGER BRIAN M
IPC分类号： H01L31/0216 , B05D5/12
CPC分类号： H01L31/0322 , C23C4/123 , C23C18/1204 , C23C18/1225 , C23C18/1241 , C23C18/127 , C23C24/10 , C23C26/00 , C23C26/02 , H01L51/0026 , H01L51/426 , Y02E10/541 , Y02E10/549
摘要： A precursor material for forming a film of a group IB-IIIA- chalcogenide compound and a method of making this film are disclosed. The film contains group IB-chalcogenide nanoparticles and/or group IIIA-chalcogenide nanoparticles and/or nanoglobules and/or nanodroplets and a source of extra chalcogen. Alternatively, the film may contain core-shell nanoparticles having core nanoparticles include group IB and/or IDA elements, which are coated with a shell of elemental chalcogen material. The method of making a film of group IB-IIIA- chalcogenide compound includes mixing the nanoparticles and/or nanoglobules and/or nanodroplets to form an ink, depositing the ink on a substrate, heating to melt the extra chalcogen and to react the chalcogen with the group IB and group IIIA elements and/or chalcogenides to form a dense film.
摘要翻译：公开了用于形成IB-III族 - 硫族化合物化合物的膜的前体材料和制备该膜的方法。该膜含有IB族硫族化物纳米颗粒和/或IIIA族硫族化物纳米颗粒和/或纳米金属和/或纳米微滴和额外硫属元素的来源。或者，膜可以包含具有核心纳米颗粒的核 - 壳纳米颗粒，包括用元素硫族元素材料的外壳涂覆的IB和/或IDA元素。制备IB-III族 - 硫族化合物组合物的膜的方法包括混合纳米颗粒和/或纳米金属和/或纳米质子以形成油墨，将油墨沉积在基材上，加热熔化额外的硫属元素并使硫族元素与 IB族和IIIA族元素和/或硫族化物以形成致密膜。

3. 发明申请

WO2006073437A2 PHOTOVOLTAIC THIN-FILM CELL PRODUCED FROM METALLIC BLEND USING HIGH-TEMPERATURE PRINTING 审中-公开
标题翻译：使用高温印刷从金属混合生产的光伏薄膜电池
公开(公告)号：WO2006073437A2
公开(公告)日：2006-07-13
申请号：PCT/US2005013932
申请日：2005-04-22
申请人： NANOSOLAR INC , ROSCHEISEN MARTIN R , SAGER BRIAN M
发明人： ROSCHEISEN MARTIN R , SAGER BRIAN M
IPC分类号： H01L31/00 , A61K9/16 , A61K9/50 , B82B3/00 , H01L21/00 , H01L31/0256 , H01L31/0392 , H01L31/18
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/127 , C23C18/1295 , H01L31/0322 , H01L31/042 , H01L31/0749 , H01L31/18 , H01L31/186 , Y02E10/541 , Y02P70/521
摘要： The metallic components of a IB-IIIA-VIA photovoltaic cell active layer may be directly coated onto a substrate by using relatively low melting point (e.g., less than about 500°C) metals such as indium and gallium. Specifically, CI(G)S thin-film solar cells may be fabricated by blending molten group IIIA metals with solid nanoparticles of group IB and (optionally) group IIIA metals. The molten mixture may be coated onto a substrate in the molten state, e.g., using coating techniques such as hot-dipping, hot microgravure and/or air-knife coating. After coating, the substrate may be cooled and the film annealed, e.g., in a sulfur-containing or selenium-containing atmosphere.
摘要翻译： IB-IIIA-VIA光伏电池活性层的金属组分可以通过使用相对较低的熔点（例如小于约500℃）的金属如铟和镓直接涂覆到基底上。具体地，可以通过将熔融IIIA族金属与IB族和（任选的）IIIA族金属的固体纳米颗粒共混来制造CI（G）S薄膜太阳能电池。熔融混合物可以以熔融状态涂覆在基材上，例如使用涂覆技术，例如热浸，热微凹版和/或气刀涂布。在涂覆之后，可以将基底冷却并将膜退火，例如在含硫或含硒气氛中。

4. 发明申请

WO2007022221A3 PHOTOVOLATIC DEVICES WITH CONDUCTIVE BARRIER LAYERS AND FOIL SUBSTRATES 审中-公开
标题翻译：具有导电障碍层和基底的光电器件
公开(公告)号：WO2007022221A3
公开(公告)日：2007-10-18
申请号：PCT/US2006031906
申请日：2006-08-16
申请人： NANOSOLAR INC , LEIDHOLM CRAIG R , BOLLMAN BRENT , SHEATS JAMES R , KAO SAM , ROSCHEISEN MARTIN R
发明人： LEIDHOLM CRAIG R , BOLLMAN BRENT , SHEATS JAMES R , KAO SAM , ROSCHEISEN MARTIN R
IPC分类号： H02N6/00
CPC分类号： B82Y10/00 , H01L31/022425 , H01L31/02245 , H01L31/03928 , H01L31/046 , H01L31/0465 , H01L31/0512 , H01L31/0749 , H01L51/5203 , H01L2251/5338 , H02S20/23 , Y02B10/12 , Y02E10/541 , Y02P70/521
摘要： Methods and devices are provided for absorber layers formed on foil substrate. In one embodiment, a method of manufacturing photovoltaic devices may be comprised of providing a substrate comprising of at least one electrically conductive aluminum foil substrate, at least one electrically conductive diffusion barrier layer, and at least one electrically conductive electrode layer above the diffusion barrier layer. The diffusion barrier layer may prevent chemical interaction between the aluminum foil substrate and the electrode layer. An absorber layer may be formed on the substrate. In one embodiment, the absorber layer may be a non-silicon absorber layer. In another embodiment, the absorber layer may be an amorphous silicon (doped or undoped) absorber layer. Optionally, the absorber layer may be based on organic and/or inorganic materials.
摘要翻译：为在箔基片上形成的吸收层提供了方法和装置。在一个实施例中，制造光伏器件的方法可以包括提供包括至少一个导电铝箔衬底，至少一个导电扩散阻挡层和在扩散阻挡层上方的至少一个导电电极层的衬底。扩散阻挡层可以防止铝箔衬底和电极层之间的化学相互作用。可以在基板上形成吸收层。在一个实施例中，吸收层可以是非硅吸收层。在另一个实施例中，吸收层可以是非晶硅（掺杂或未掺杂）吸收层。任选地，吸收层可以基于有机和/或无机材料。

5. 发明申请

WO2006101986A2 METTALIC DISPERSION AND FORMATION OF COMPOUND FILM FOR PHOTOVOLTAIC DEVICE ACTIVE LAYER 审中-公开
标题翻译：金属分散体和形成用于光伏器件活性层的复合膜
公开(公告)号：WO2006101986A2
公开(公告)日：2006-09-28
申请号：PCT/US2006009534
申请日：2006-03-16
申请人： NANOSOLAR INC , ROBINSON MATTHEW R , ROSCHEISEN MARTIN R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J , LEIDHOLM CRAIG R
发明人： ROBINSON MATTHEW R , ROSCHEISEN MARTIN R , EBERSPACHER CHRIS , VAN DUREN JEROEN K J , LEIDHOLM CRAIG R
IPC分类号： H02N6/00
CPC分类号： H01L31/0322 , C23C18/02 , C23C18/1216 , C23C18/1258 , C23C18/1279 , C23C18/1287 , H01L21/02568 , H01L21/02601 , H01L21/02628 , H01L31/0749 , Y02E10/541
摘要： A compound film may be formed by formulating a mixture of elemental nanoparticles composed of the IB, the IIIA, and, optionally, the VIA group of elements having a controlled overall composition. The nanoparticle mixture is combined with a suspension of nanoglobules of gallium to form a dispersion. The dispersion may be deposited onto a substrate to form a layer on the substrate. The layer may then be reacted in a suitable atmosphere to form the compound film. The compound film may be used as a light-absorbing layer in a photovoltaic device. Optionally, the compound film for an active layer of a photovoltaic device may be formed in two or more sub-layers. A first sub-layer having a first component of the active layer may be formed on a substrate with a first process. A second sub-layer including a second component of the active layer may then be formed using a second process such that the first sublayer is disposed between the second sub-layer and the substrate. The second component may have a different chemical composition than the first component. The first and/or second sub-layer may comprise one or more components in the form of particles and/or globules. This procedure may be repeated any number of times for any number of sub-layers so that active layer can be built up sequentially. The different chemical compositions of the components in the sub-layers can provide the active layer with a graded bandgap.
摘要翻译：可以通过配制由IB，IIIA和任选地具有受控整体组成的元素的VIA族组成的元素纳米颗粒的混合物来形成化合物膜。将纳米颗粒混合物与镓的纳米金属的悬浮液组合以形成分散体。可以将分散体沉积在基底上以在基底上形成层。然后可以在合适的气氛中反应该层以形成化合物膜。复合膜可以用作光伏器件中的光吸收层。可选地，用于光伏器件的有源层的化合物膜可以形成为两个或更多个子层。具有有源层的第一分量的第一子层可以用第一工艺形成在衬底上。然后可以使用第二工序形成包括有源层的第二部件的第二子层，使得第一子层设置在第二子层和衬底之间。第二组分可以具有与第一组分不同的化学组成。第一和/或第二子层可以包括颗粒和/或小球形式的一种或多种组分。对于任何数量的子层，该过程可以重复任意次数，以便可以顺序地建立活动层。子层中组分的不同化学组成可以为活性层提供渐变的带隙。

6. 发明申请

WO2008137966A3 STRUCTURES FOR LOW COST, RELIABLE SOLAR ROOFING 审中-公开
标题翻译：低成本，可靠的太阳能屋顶结构
公开(公告)号：WO2008137966A3
公开(公告)日：2009-02-05
申请号：PCT/US2008062967
申请日：2008-05-07
申请人： STANCEL ROBERT , ROSCHEISEN MARTIN R , SAGER BRIAN M , ADRIANI PAUL M
发明人： STANCEL ROBERT , ROSCHEISEN MARTIN R , SAGER BRIAN M , ADRIANI PAUL M
IPC分类号： E04D13/18 , H01L31/048
CPC分类号： H01L31/02008 , F24J2/0455 , H01L31/0521 , H02S20/25 , Y02A30/62 , Y02B10/12 , Y02B10/20 , Y02E10/44 , Y02E10/50
摘要： Improved photovoltaic devices, and more specifically, improved building integrated photovoltaic devices are described herein. In one embodiment, the photovoltaic roofing structure may be comprised of a roofing tile having a top surface, a bottom surface, and a recessed portion; a photovoltaic module sized to fit within the recessed portion of the roofing structure.
摘要翻译：本文描述了改进的光伏器件，更具体地，改进的建筑集成光伏器件。在一个实施例中，光伏屋顶结构可以由具有顶表面，底表面和凹陷部分的屋顶瓦片组成; 尺寸适于装配在屋顶结构的凹陷部分内的光伏组件。

7. 发明申请

WO2006078985A3 OPTOELECTRONIC ARCHITECTURE HAVING COMPOUND CONDUCTING SUBSTRATE 审中-公开
标题翻译：具有复合导电衬底的光电子结构
公开(公告)号：WO2006078985A3
公开(公告)日：2006-12-14
申请号：PCT/US2006002182
申请日：2006-01-20
申请人： NANOSOLAR INC , SHEATS JAMES R , KAO SAM , MILLER GREGORY , ROSCHEISEN MARTIN R
发明人： SHEATS JAMES R , KAO SAM , MILLER GREGORY , ROSCHEISEN MARTIN R
IPC分类号： H01L31/062 , H01L21/00
CPC分类号： H01L31/18 , H01L27/3204 , H01L31/0392 , H01L31/03923 , H01L31/03925 , H01L31/046 , H01L31/0463 , H01L31/0465 , H01L31/0749 , H01L51/5203 , Y02E10/541 , Y02P70/521
摘要： Optoelectronic device modules, arrays optoelectronic device modules and methods for fabricating optoelectronic device modules are disclosed. The device modules are made using a starting substrate having an insulator layer sandwiched between a bottom electrode made of a flexible bulk conductor and a conductive back plane. An active layer is disposed between the bottom electrode and a transparent conducting layer. One or more electrical contacts between the transparent conducting layer and the back plane are formed through the transparent conducting layer, the active layer, the flexible bulk conductor and the insulating layer. The electrical contacts are electrically isolated from the active layer, the bottom electrode and the insulating layer.
摘要翻译：公开了光电子器件模块，阵列光电子器件模块和用于制造光电子器件模块的方法。器件模块使用具有夹在由柔性块状导体制成的底部电极和导电背板之间的绝缘体层的起始衬底制成。有源层设置在底部电极和透明导电层之间。透明导电层和背面之间的一个或多个电接触通过透明导电层，活性层，柔性块状导体和绝缘层形成。电触点与有源层，底电极和绝缘层电隔离。

8. 发明申请

WO2005081788A3 HIGH THROUGHPUT SURFACE TREATMENT ON COILED FLEXIBLE SUBSTRATES 审中-公开
标题翻译：卷绕柔性基板上的高强度表面处理
公开(公告)号：WO2005081788A3
公开(公告)日：2006-05-04
申请号：PCT/US2005003691
申请日：2005-02-07
申请人： NANOSOLAR INC , ROSCHEISEN MARTIN R , PICHLER KARL
发明人： ROSCHEISEN MARTIN R , PICHLER KARL
IPC分类号： B05D3/12 , C23C16/00 , C23C16/40 , C23C16/455 , C23C16/458 , C23C16/54
CPC分类号： C23C16/45544 , C23C16/405 , C23C16/458 , C23C16/4581 , C23C16/545 , C25D7/0614 , C25D17/02 , H01L31/022425 , H01L31/0322 , H01L31/0392 , H01L31/03926 , H01L31/1864 , H01L31/1876 , Y02E10/541 , Y02P70/521
摘要： One or more substrates (106) may be coiled into one or more coils in such a way that adjacent turns of the coils do not touch one another. The one or more coiled substrates (106) are placed in a treatment chamber (102) where substantially an entire surface of the one or more coiled substrates (106) may be treated with a surface treatment process. One or more spacers (116) may be placed between adjacent layers of the coiled substrate (106) before a full turn of the substrate (106) has been coiled around the carousel (104).
摘要翻译：一个或多个衬底（106）可以被卷绕成一个或多个线圈，使得线圈的相邻匝不彼此接触。一个或多个卷绕的基板（106）被放置在处理室（102）中，其中一个或多个卷绕的基板（106）的基本上整个表面可以用表面处理工艺处理。一个或多个间隔物（116）可以在基片（106）的整圈被卷绕在圆盘传送带（104）之前被放置在盘绕的基底（106）的相邻层之间。

9. 发明申请

WO2010063018A3 WIND UPLIFT RESISTANT MODULE MOUNTING SYSTEM 审中-公开
标题翻译：抗风拔模块安装系统
公开(公告)号：WO2010063018A3
公开(公告)日：2010-09-16
申请号：PCT/US2009066030
申请日：2009-11-27
申请人： STANCEL ROBERT , ROSCHEISEN MARTIN R
发明人： STANCEL ROBERT , ROSCHEISEN MARTIN R
IPC分类号： F24J2/52 , H01L31/042
CPC分类号： F24J2/5256 , F24J2/4638 , F24J2/5207 , F24J2/5239 , F24J2/5241 , F24J2/5245 , F24J2002/5281 , F24J2002/5286 , H02S20/00 , H02S20/24 , H02S20/30 , Y02B10/12 , Y02B10/20 , Y02E10/47 , Y02E10/50
摘要： Methods and devices are provided for improved rooftop solar module mounting assemblies. In one embodiment, an assembly is provided for mounting a plurality of photovoltaic devices over a roof surface. The assembly comprises of a plurality of elongate metal rods, wherein the elongate metal rods are connected together to define a support grid; a plurality of non-roof penetrating grid supports configured to elevate the support grid above the roof surface, wherein the panels are grouped to define a rigid combination of modules and beams wherein the combination covers sufficient area and has sufficient rigidity which minimizes the risk of module lift off. Some embodiments are non-ballasted systems without features added to increase the weight of the system above a minimum required for conventional wind load ballasting for solar installations.
摘要翻译：提供了用于改进的屋顶太阳能模块安装组件的方法和装置。在一个实施例中，提供了用于在屋顶表面上安装多个光伏装置的组件。该组件包括多个细长金属杆，其中细长金属杆连接在一起以限定支撑格栅; 多个非屋顶穿透栅格支撑件，其被构造成将支撑栅格升高到屋顶表面上方，其中，所述面板被分组以限定模块和梁的刚性组合，其中所述组合覆盖足够的面积并且具有足够的刚度，从而最小化模块升空。一些实施例是非压载系统，没有添加特征以将系统的重量增加到太阳能装置的常规风力压载压载所需的最小值以上。

10. 发明申请

WO2008106565A3 STRUCTURES FOR LOW COST, RELIABLE SOLAR MODULES 审中-公开
标题翻译：低成本，可靠的太阳能模块结构
公开(公告)号：WO2008106565A3
公开(公告)日：2008-11-27
申请号：PCT/US2008055201
申请日：2008-02-27
申请人： ADRIANI PAUL M , SCHOLZ JEREMY H , ROSCHEISEN MARTIN R , CAPPS PHILIP C , STANCEL ROBERT
发明人： ADRIANI PAUL M , SCHOLZ JEREMY H , ROSCHEISEN MARTIN R , CAPPS PHILIP C , STANCEL ROBERT
IPC分类号： H01L31/042
CPC分类号： B32B17/10018 , B32B17/10889 , H01L31/02013 , H01L31/049 , H02S20/25 , H02S30/20 , H02S40/34 , Y02B10/12 , Y02E10/50 , Y10T29/49002
摘要： Methods and devices are provided for improved large-scale solar installations. In one embodiment, a photovoltaic module is provided comprising a module front layer comprising a glass plate, a module back layer comprising an electrically conductive foil, and a plurality of solar cells arranged to be protected by the front layer and the back layer. In some embodiments, the module back layer is aluminum foil. The module back layer may have an externally exposed surface. The module back layer may be electrically grounded. An electrically insulating pottant material may be used with the solar cells to separate them from the module back layer. This allows for a high voltage withstand between the cells and the outer surface of the back layer.
摘要翻译：提供了改进的大规模太阳能装置的方法和装置。在一个实施例中，提供了一种光伏模块，其包括包含玻璃板的模块前层，包含导电箔的模块背层以及布置成由前层和后层保护的多个太阳能电池。在一些实施例中，模块背面层是铝箔。模块背层可具有外部暴露的表面。模块背层可以电接地。电绝缘灌封材料可以与太阳能电池一起使用以将它们与模块背层分离。这允许在电池和背层的外表面之间承受高电压。

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