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    • 7. 发明申请
    • USE OF A BARRIER SPUTTER REACTOR TO REMOVE AN UNDERLYING BARRIER LAYER
    • 使用障碍物反应器去除下面的障碍物层
    • WO0239500A3
    • 2004-02-19
    • PCT/US0145167
    • 2001-11-01
    • APPLIED MATERIALS INC
    • CHEN LINGGANGULI SESHADRICAO WEIMARCADAL CHRISTOPHE
    • H01L21/285H01L21/4763H01L21/768
    • H01L21/76844H01L21/2855H01L21/28556H01L21/76843H01L21/76846H01L21/76856H01L21/76865
    • A method and resultant structure of forming barrier layers in a via hole extending through an inter-level dielectric layer. A first barrier layer (30) of TiSin is conformally coated by chemical vapor deposition onto the bottom and sidewalls of the via holes and in the field are on top of the dielectric layer. A single plasma sputter reactor is used to perform two steps. In the first step, the wafer rather than the target is sputtered with high energy ions to remove the barrier layer (30) from the bottom of the via but not from the sidewalls. In the second step, a second barrier layer (40), for example of Ta/TaN, is sputter deposited onto the via bottom and sidewalls. The two steps may be differentiated by power applied to the target, by chamber pressure, or by wafer bias. The second step may include the simultaneous removal of the first barrier layer from the via bottom and sputter deposition of the second barrier layer onto the via sidewalls. Chamber conditions in the first step, including balancing neutrals and ions, may be controlled to remove the first barrier layer from the via bottom while leaving it on the more exposed the field area.
    • 在延伸穿过层间电介质层的通孔中形成势垒层的方法和结果。 TiSin的第一阻挡层(30)通过化学气相沉积保形地涂覆到通孔的底部和侧壁上,并且在场中位于介电层的顶部。 使用单个等离子体溅射反应器执行两个步骤。 在第一步骤中,用高能离子溅射晶片而不是靶,以从通孔的底部除去阻挡层(30),而不是从侧壁去除。 在第二步骤中,例如Ta / TaN的第二阻挡层(40)溅射沉积到通孔底部和侧壁上。 这两个步骤可以通过施加到靶,通过室压力或通过晶片偏置的功率来区分。 第二步骤可以包括从通孔底部同时移除第一阻挡层并将第二阻挡层溅射到通孔侧壁上。 可以控制第一步骤中的室内条件,包括平衡中性粒子和离子,以将第一阻挡层从通孔底部移除,同时将其留在更暴露的场区域。
    • 8. 发明申请
    • W-CVD WITH FLUORINE-FREE TUNGSTEN NUCLEATION
    • W-CVD与无氟钨的成核
    • WO02079537A3
    • 2002-12-19
    • PCT/US0209311
    • 2002-03-25
    • APPLIED MATERIALS INC
    • JIAN PINGGANGULI SESHADRILITTAU KARL AMARCADAL CHRISTOPHECHEN LING
    • C23C16/02C23C16/16H01L21/28H01L21/285H01L21/3205H01L23/52
    • C23C16/0281C23C16/16H01L21/28556
    • In accordance with the present invention, a method is provided for forming an improved tungsten layer. In one embodiment, a CVD method for depositing a tungsten layer on a substrate includes forming a bilayer of titanium-nitride/titanium (TiN/Ti) over the substrate, placing the substrate in a deposition zone of a substrate processing chamber, and introducing a fluorine-free tungsten-containing precursor and a carrier gas into the deposition zone for forming a tungsten nucleation layer over the TiN/Ti bilayer. The Ti layer is between the TiN layer and the substrate. After the tungsten nucleation formation, a process gas including a tungsten-containing source and a reduction agent are introduced into the deposition zone for forming the bulk tungsten layer. In one embodiment, the fluorine-free tungsten-containing precursor includes W(CO)6, and the carrier gas is Argon.
    • 根据本发明,提供了一种用于形成改进的钨层的方法。 在一个实施例中,用于在衬底上沉积钨层的CVD方法包括在衬底上形成氮化钛/钛(TiN / Ti)双层,将衬底放置在衬底处理室的沉积区中, 无氟含钨前体和载气进入沉积区,以在TiN / Ti双层上形成钨成核层。 Ti层位于TiN层和衬底之间。 在钨成核形成之后,包括含钨源和还原剂的工艺气体被引入用于形成块钨层的沉积区中。 在一个实施例中,无氟含钨前体包括W(CO)6,载气是氩。