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1. 发明申请

WO2013007664A1 HETEROPHASIC COPOLYMERS 审中-公开
标题翻译：异构共聚物
公开(公告)号：WO2013007664A1
公开(公告)日：2013-01-17
申请号：PCT/EP2012/063332
申请日：2012-07-06
申请人： BOREALIS AG , HAFNER, Norbert , RESCONI, Luigi , GAHLEITNER, Markus , WANG, Jimgbo , CASTRO, Pascal , KULYABIN, Pavel Sergeevich , IZMER, Vyatcheslav , VOSKOBOYNIKOV, Alexander , KONONOVICH, Dmitry , VIRKKUNEN, Ville
发明人： HAFNER, Norbert , RESCONI, Luigi , GAHLEITNER, Markus , WANG, Jimgbo , CASTRO, Pascal , KULYABIN, Pavel Sergeevich , IZMER, Vyatcheslav , VOSKOBOYNIKOV, Alexander , KONONOVICH, Dmitry , VIRKKUNEN, Ville
IPC分类号： C08L23/12 , C08F2/00
CPC分类号： C07F7/0818 , C07C13/36 , C07C13/38 , C07C13/465 , C07C41/01 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/12 , C08L2207/02 , C08L2314/06 , C08L23/16 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A heterophasic polypropylene resin comprising a polypropylene homopolymer matrix phase (A) and an ethylene-propylene copolymer phase (B) dispersed within the matrix, wherein the xylene soluble fraction of the heterophasic polypropylene resin is in the range 20 to less than 50 wt%; the heterophasic polypropylene resin has an MFR2 of 0.01 to 50 g/10min; the ethylene content of the xylene soluble fraction of the heterophasic polypropylene resin is in the range of at least 20 wt% to less than 50 wt%; the heterophasic polypropylene resin has a notched charpy impact strength at -20C of at least 25 kJ/m 2 , preferably at least 50 kJ/m 2 ; and wherein the MFR 2 (Matrix)/MFR 2 (XS) ≥ 5, preferably ≥10.
摘要翻译：包含分散在基质内的聚丙烯均聚物基质相（A）和乙烯 - 丙烯共聚物相（B）的多相聚丙烯树脂，其中所述多相聚丙烯树脂的二甲苯可溶部分在20至小于50重量％的范围内; 多相聚丙烯树脂的MFR 2为0.01〜50g / 10min; 多相聚丙烯树脂的二甲苯可溶部分的乙烯含量在至少20重量％至小于50重量％的范围内; 多相聚丙烯树脂在-20℃下具有至少25kJ / m 2，优选至少50kJ / m 2的缺口夏比冲击强度; 并且其中MFR 2（Matrix）/ MFR 2（XS）= 5，优选= 10。

2. 发明申请

WO2011056431A3 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
公开(公告)号：WO2011056431A3
公开(公告)日：2011-08-25
申请号：PCT/US2010053378
申请日：2010-10-20
申请人： EXXONMOBIL CHEM PATENTS INC , GIESBRECHT GARTH R , BOLLER TIMOTHY M , VOSKOBOYNIKOV ALEXANDER Z , ASACHENKO ANDREY F , NIKULIN MIKHAIL V , TSAREV ALEXEY A
发明人： GIESBRECHT GARTH R , BOLLER TIMOTHY M , VOSKOBOYNIKOV ALEXANDER Z , ASACHENKO ANDREY F , NIKULIN MIKHAIL V , TSAREV ALEXEY A
IPC分类号： C08F4/64 , B01J31/12 , C08F10/00 , C08F210/16
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly a-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.

3. 发明申请

WO2007070046A1 HALOGEN SUBSTITUTED HETEROATOM-CONTAINING METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的含异戊烯的金属化合物
公开(公告)号：WO2007070046A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045292
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F2420/02 , C08F2420/05 , C08F4/6592
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配位体，其与金属原子键合，并且包含至少一个与可结合环上的sp 2碳原子键合的卤素取代基配体的位置，其中所述或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

4. 发明申请

WO2006065809A2 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的杂原子桥联金属茂化合物
公开(公告)号：WO2006065809A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C08F10/00 , C08F4/64 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M为3,4,5或6族过渡金属原子或镧系金属原子或act系金属原子; E为：1）取代或未取代的茚基配体，其通过茚基环的四，五，六或七位与Y键合，或2）取代或未取代的杂茚基配体，其通过四个，五个或六个位置，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个，6,7或8位的芴基环，或4）取代或未取代的杂芴基配体，其通过杂茚基环的1,2,3,4,5或6位与Y结合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的第15族或第16族桥联杂原子取代基; 和X独立地为一价阴离子配体，或两个X连接并键合到金属原子上形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。本发明进一步涉及包含上述转铁基金属化合物，活化剂和任选的载体的催化剂体系及其用于聚合或低聚烯烃的用途。

5. 发明申请

WO2011056424A2 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
标题翻译：催化剂化合物及其用途
公开(公告)号：WO2011056424A2
公开(公告)日：2011-05-12
申请号：PCT/US2010/053324
申请日：2010-10-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ASACHENKO, Andrey, F. , BOLLER, Timothy, M. , NIKULIN, Mikhail, V. , VOSKOBOYNIKOV, Alexander, Z. , GIESBRECHT, Garth, Ronald , TSAREV, Alexey, A.
发明人： ASACHENKO, Andrey, F. , BOLLER, Timothy, M. , NIKULIN, Mikhail, V. , VOSKOBOYNIKOV, Alexander, Z. , GIESBRECHT, Garth, Ronald , TSAREV, Alexey, A.
IPC分类号： C08F4/64 , C08F10/00 , C08F210/16 , B01J31/12
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefms, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：提供了含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可以有或没有活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

6. 发明申请

WO2009027075A3 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2009027075A3
公开(公告)日：2009-07-02
申请号：PCT/EP2008007007
申请日：2008-08-27
申请人： BOREALIS TECH OY , VOSKOBOYNIKOV ALEXANDER ZELMAN , ASACHENKO ANDREI FYODOROVICH , KONANOVICH DMITRY , NIKULIN MIKHAIL V , TZAREV ALEXEY , MAARANEN JANNE , VANNE TIINA , KAUHANEN JYRKI , MANSNER ERIK , KOKKO ESA , SAARINEN LAURA
发明人： VOSKOBOYNIKOV ALEXANDER ZELMANOVICH , ASACHENKO ANDREI FYODOROVICH , KONANOVICH DMITRY , NIKULIN MIKHAIL V , TZAREV ALEXEY , MAARANEN JANNE , VANNE TIINA , KAUHANEN JYRKI , MANSNER ERIK , KOKKO ESA , SAARINEN LAURA
IPC分类号： C08F4/656 , C07C13/465 , C07F17/00 , C08F10/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is -(Si(R5)2)p-, where p is 1 or 2, -(C(R5)2 )n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）配体的配合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团一起形成任选取代的5-至8-元稠合环; 每个可以相同或不同的R 2是氢，是氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基或任选取代的杂环基; 与茚基的6元环结合的R3是 - （Si（R5）2）p-，其中p是1或2， - （C（R5）2）n-，其中n是 2或更多; 每个可以相同或不同的R 4是氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或邻近碳上的两个R 4基团原子结合在一起可形成任选取代的5-至8-元稠合碳环; 每个可以相同或不同的R5为氢，任选取代的C1-20烃基或两个R5基团一起形成任选取代的5-至8-元环; a是0到3; b是0至3; c是0至4; 与金属离子复合，M.

7. 发明申请

WO2007111537A2 SYNTHESIS OF SUBSTITUTED FLUORENES 审中-公开
标题翻译：取代的荧光素的合成
公开(公告)号：WO2007111537A2
公开(公告)日：2007-10-04
申请号：PCT/RU2007/000148
申请日：2007-03-28
申请人： GOSUDARSTVENNOE UCHEBNO-NAUCHNOE UCHREZHDENIE KHIMICHESKY FAKULTET MOSKOVSKOGO GOSUDARSTVENNOGO UNIVERSITETA IM. M.V.LOMONOSOVA , TOTAL PETROCHEMICALS RESEARCH FELUY , LEBEDEV, Artyom Yuryevich , ASACHENKO, Andrei Fyodorovich , VOSKOBOYNIKOV, Alexander Zelmanovich , RAZAVI, Abbas
发明人： LEBEDEV, Artyom Yuryevich , ASACHENKO, Andrei Fyodorovich , VOSKOBOYNIKOV, Alexander Zelmanovich , RAZAVI, Abbas
CPC分类号： C07C1/28 , B01J31/1805 , B01J2231/641 , B01J2531/847 , C07C13/567 , C07C17/12 , C07C2523/06 , C07C2531/22 , C07C2603/18 , C07C25/18
摘要： The present invention describes a cost-efficient method for preparing di-substituted fluorenes in high yield.
摘要翻译：本发明描述了高收率制备二取代芴的具有成本效益的方法。

8. 发明申请

WO2006065809A3 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的异质桥联金属化合物
公开(公告)号：WO2006065809A3
公开(公告)日：2006-09-28
申请号：PCT/US2005045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/64
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）取代或未取代的茚基配体，其通过茚基环的4,5,6或7位与Y键合，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。本发明还涉及包含上述转子金属化合物，活化剂和任选的载体的催化剂体系以及它们使烯烃聚合或低聚的用途。

9. 发明申请

WO2005108435A1 PHOSPHORUS BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的磷酸盐桥联金属化合物
公开(公告)号：WO2005108435A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/008093
申请日：2005-03-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
IPC分类号： C08F4/64
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F210/14
摘要： This invention relates to metallocene compounds represented by formula: wherein, M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is a substituted or unsubstituted indenyl ligand that is bonded to Y through the two position of the indenyl ring; A is bonded to Y, and is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substututed or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E; Y is a phosphorus containing group that is bonded to both E and A, and is bonded via the phosphorus atom to E; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是通过茚基环的两个位置与Y键合的取代或未取代的茚基配体; A与Y结合，为取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的芴基配位体，或其它单阴离子配体，或者A可以独立地定义为E; Y是与E和A键合的含磷基团，通过磷原子与E结合; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

10. 发明申请

WO2012084961A1 BRIDGED METALLOCENE CATALYSTS 审中-公开
标题翻译： BRIDGED METALLOCENE催化剂
公开(公告)号：WO2012084961A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073426
申请日：2011-12-20
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
发明人： RESCONI, Luigi , CASTRO, Pascal , VOSKOBOYNIKOV, Alexander Z , IZMER, Vyatcheslav V , KONOVICH, Dmitry S
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R '2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R 18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R 5 group; each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 ; and each R 7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环稠合成可任选地被一个或两个基团R 5取代的W 1; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

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