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1. 发明申请

WO2007070040A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070040A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045241
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS, INC. , VOSKOBOYNIKOV, Alexander, Z. , RAYABOV, Alexey, N. , UBORSKY, Dimitry, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RAYABOV, Alexey, N. , UBORSKY, Dimitry, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C07F17/00 , C08F10/00 , C08F4/64
CPC分类号： C07F17/00
摘要： A metallocene compound is represented by the formula (1): AMX n-1 wherein M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; A is a substituted monocyclic or polycyclic arenyl ligand pi-bonded to M, wherein said arenyl ligand includes at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：金属茂化合物由式（1）表示：其中M是具有选自周期表第3,4,5或6族的配位数n的过渡金属原子的元素，或镧系金属原子，或锕系金属原子; A是与M键合键合的取代的单环或多环的烷基配体，其中所述的异戊基配体包括至少一个与配体的可键合环位置上直接连接到任何sp 2碳原子上的卤素取代基; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。

2. 发明申请

WO2007070038A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070038A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045137
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
IPC分类号： C07F17/00 , C08F4/6592 , C08F10/02
CPC分类号： C08F10/02 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F210/16 , C08F4/6592 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：茂金属化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包含至少一个直接连接到sp 2 O 2原子上的卤素取代基所述芳族配体的芳族五元环的可键合环位置。

3. 发明申请

WO2006065906A3 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065906A3
公开(公告)日：2007-02-22
申请号：PCT/US2005045245
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , COKER CATALINA L , CANICH JO ANN M , VOSKOBOYNIKOV ALEXANDER Z , RYABOV ALEXEY N , NIKULIN MIKHAIL V , LYGIN ALEXANDER V , IZMER VYATCHESLAV V , ASACHENKO ANDREY
发明人： COKER CATALINA L , CANICH JO ANN M , VOSKOBOYNIKOV ALEXANDER Z , RYABOV ALEXEY N , NIKULIN MIKHAIL V , LYGIN ALEXANDER V , IZMER VYATCHESLAV V , ASACHENKO ANDREY
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： Ametallocene compound is represented by the formula (1): A 2 Y y MX n-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.
摘要翻译：亚茂金属化合物由式（1）表示：其中：M是具有一个（C 1 -C 6）选自元素周期表第3,4,5或6族的n的配位数，或镧系元素金属原子或锕系金属原子; 每个A独立地是与M键合的取代的多环烷基配体，每个A配位体包括至少一个在可键合的环位置直接键合到sp 2 O 2上的卤素取代基，并且当每个A是取代的茚基配体并且y等于1，并且配体在茚基配体的4,5或6位包含至少一个氯，溴或碘取代基，则A还包括所选择的茚基配体中的至少一个其它取代基由烃基，取代的烃基，卤素，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基，取代的烯基羰基或其它杂原子取代基，其中杂原子直接键合到环结构配体的环碳上，并且是硼，，或16族原子，优选硼，氮，氧，磷或硫; Y是任选的含有至少一个第13,14,15或16族的桥连基团，并且键合到A的环结构的任何单个位置，y为0或1，表示不存在（y = 0）或存在（y = 1）; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当y等于1时，A不是5,6-二氯茚基或在7位具有氟或氯取代基的茚基和在4位上的烃基或取代的烃基取代基，并进一步提供当 y等于0，那么A不是5,6-二氟茚基。

4. 发明申请

WO2007011459A1 POLYALPHA-OLEFIN COMPOSITIONS AND PROCESSES TO PRODUCE THE SAME 审中-公开
标题翻译：聚烯烃组合物及其制备方法
公开(公告)号：WO2007011459A1
公开(公告)日：2007-01-25
申请号：PCT/US2006/021231
申请日：2006-06-02
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WU, Margaret, M. , YANG, Norman , BAUGH, Lisa, S. , CANICH, Jo Ann, M. , RUCKER, Steven, P. , WALZER, John, F. , LEE, Gordon, H. , LO, Frederick, Yip-kwai , JACKSON, Andrew , HAGEMEISTER, Mark , TIRMIZI, Shakeel , JIANG, Peijun , CHEE, Chia, S.
发明人： WU, Margaret, M. , YANG, Norman , BAUGH, Lisa, S. , CANICH, Jo Ann, M. , RUCKER, Steven, P. , WALZER, John, F. , LEE, Gordon, H. , LO, Frederick, Yip-kwai , JACKSON, Andrew , HAGEMEISTER, Mark , TIRMIZI, Shakeel , JIANG, Peijun , CHEE, Chia, S.
IPC分类号： C08F210/14 , C10M143/08
CPC分类号： C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要： This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92 * (V)' °5863, whre V is the Kinematic Viscosity of the polyalpha-olefin measured at 100°C in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z = 8.420*Log(V)-4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000C in cSt This invention also relates to process to produce such polyalpha-olefins.
摘要翻译：本发明涉及包含大于50摩尔％的一种或多种C 5 -C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％或更多的三元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，v是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代烯烃以7摩尔％以上，优选具有Z摩尔％以上的由下式表示的单元：其中，j，k和m各自独立地为3，4，5，6，7，8，9，10，11 ，12,13,14,15,16,17,18,19,20,21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为在100℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

5. 发明申请

WO2005108410A1 PHOSPHORUS SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的磷取代金属化合物
公开(公告)号：WO2005108410A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/008388
申请日：2005-03-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo Ann M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo Ann M.
IPC分类号： C07F17/00
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J31/2447 , B01J31/2457 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R ° where each R" is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R ° substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, cz both X are joined and bound to the metal atom to, form a metallocycle ring, or, both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是在茚基配体的两个位置被PR 2基团取代的茚基配体，其中每个R独立地是烃基，取代的烃基，卤代烃基或取代的卤代烃基取代基，另外E可以被0， 1,2,3,4,5或6个R“，其中每个R”独立地是烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，锗烷基或取代的己基羰基取代基，以及任选的两个或更多相邻的R 0取代基可以连接在一起以形成取代或未取代的，饱和的，部分不饱和的或芳族的环状或多环取代基; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂环芴基配体或其它单阴离子配体，或A可以独立地定义为E或X定义; 每个X独立地是一价阴离子配体，两个X连接并结合到金属原子上，形成金属环，或者两者X连接形成螯合配体，二烯配体或亚烷基配体。

6. 发明申请

WO2004106394A1 COPOLYMERS OF ETHYLENE AND/OR α-OLEFINS AND VICINALLY DISUBSTITUTED OLEFINS 审中-公开
标题翻译：乙烯和/或α-烯烃和维生素分解的烯烃的共聚物
公开(公告)号：WO2004106394A1
公开(公告)日：2004-12-09
申请号：PCT/US2004/005137
申请日：2004-02-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , KACKER, Smita , BERLUCHE, Enoch , SCHAFFER, Timothy, D. , CANICH, Jo, Ann, M.
发明人： KACKER, Smita , BERLUCHE, Enoch , SCHAFFER, Timothy, D. , CANICH, Jo, Ann, M.
IPC分类号： C08F210/02
CPC分类号： C08F210/02 , C08F210/08 , C08F210/16 , C08F2500/20 , C08F2500/03 , C08F210/06
摘要： Substantially random ethylene and/or α-olefin copolymers containing units derived from vicinally disubstituted olefin monomers are described. The vicinally disubstituted olefin monomers may be represented by the generic formula (R 1 )CH=CH(R 2 ), where R 1 and R 2 independently comprise hydrocarbyl or silyl-hydrocarbyl groups containing 1 or more carbon atoms, or may be linear, branched or cyclic substituted or unsubstituted hydrocarbyl groups having from 1-100 carbon atoms, or they may contain 30 or less carbon atoms. The copolymers may be prepared by coordination polymerization by means of contacting at least one vicinally disubstituted olefin monomer and ethylene and/or α-olefin, optionally with one or more other coordination polymerizable monomers, with a catalyst system comprising a monocyclopentadienyl heteroatom-containing Group 4 transition metal catalyst component.
摘要翻译：描述了含有衍生自邻近二取代的烯烃单体的单元的基本上无规的乙烯和/或α-烯烃共聚物。邻位二取代的烯烃单体可以由通式（R 1）CH = CH（R 2）表示，其中R 1和R 2独立地包含含1个或更多个的烃基或甲硅烷基 - 烃基或可以是具有1-100个碳原子的直链，支链或环状的取代或未取代的烃基，或者它们可以含有30个或更少的碳原子。共聚物可以通过使至少一个相邻二取代的烯烃单体和任选与一种或多种其它配位可聚合单体的乙烯和/或α-烯烃与包含单环戊二烯基杂原子的第4组的催化剂体系过渡金属催化剂组分。

7. 发明申请

WO2009091480A2 PRODUCTION OF PROPYLENE-BASED POLYMERS 审中-公开
标题翻译：生产丙烯聚合物
公开(公告)号：WO2009091480A2
公开(公告)日：2009-07-23
申请号：PCT/US2008/087664
申请日：2008-12-19
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , CANICH, Jo Ann, M. , JIANG, Peijun , CASTY, Gary, L. , KISS, Gabor , VOSKOBOYNIKOV, Alexander, Z.
发明人： CANICH, Jo Ann, M. , JIANG, Peijun , CASTY, Gary, L. , KISS, Gabor , VOSKOBOYNIKOV, Alexander, Z.
IPC分类号： C08F10/06 , C08F4/6592
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y02P20/544 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/17 , C08F2500/20
摘要： In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.
摘要翻译：在制备丙烯类烯烃均聚物或共聚物的方法中，包含丙烯的单体组合物在均相聚合条件（如溶液，超溶剂或超临界条件）下与聚合催化剂体系接触，其中聚合催化剂体系包括活化剂和在4位被咔唑（未取代或取代的）取代的桥连双茚基过渡金属（4族）化合物。

8. 发明申请

WO2007070041A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070041A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045244
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V.
发明人： COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V.
IPC分类号： C07F17/00 , C08F10/00 , C08F4/64
CPC分类号： C07F17/00
摘要： A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
摘要翻译：金属茂化合物由式（1）表示：其中：M是第3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子，优选选自钛的第4族过渡金属原子，锆或铪; E是与M键合的取代或未取代的单环或多环的烷基配体; A是取代或未取代的与M配体结合并具有不同于E配体的环结构的多环烷基配体; A和E配体中的至少一个配体包括在可键合的环位置上直接键合到sp 2 O 2上的至少一个卤素取代基; Y是含有至少一个第13,14,15或16族元素和A的环结构的任何单个位置和E的环结构的任何单个位置的桥连基团; y为0或1，表示Y不存在（y = 0）或存在（y = 1）; 并且每个X是一价阴离子配体，或两个X连接并结合到金属原子以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当E是未取代的环戊二烯基配体时，y是1或A不是2-溴芴基或2,7-二溴芴基。

9. 发明申请

WO2006065906A2 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065906A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045245
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrey
发明人： COKER, Catalina, L. , CANICH, Jo Ann, M. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrey
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： Ametallocene compound is represented by the formula (1): A 2 Y y MX n-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.
摘要翻译：亚茂金属化合物由式（1）表示：其中：M是具有一个（C 1 -C 6）选自元素周期表第3,4,5或6族的n的配位数，或镧系元素金属原子或锕系金属原子; 每个A独立地是与M键合的取代的多环烷基配体，每个A配位体包括至少一个在可键合的环位置直接键合到sp 2 O 2上的卤素取代基，并且当每个A是取代的茚基配体并且y等于1，并且配体在茚基配体的4,5或6位包含至少一个氯，溴或碘取代基，则A还包括所选择的茚基配体中的至少一个其它取代基由烃基，取代的烃基，卤素，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基，取代的烯基羰基或其它杂原子取代基，其中杂原子直接键合到环结构配体的环碳上，并且是硼，，或16族原子，优选硼，氮，氧，磷或硫; Y是任选的含有至少一个第13,14,15或16族的桥连基团，并且键合到A的环结构的任何单个位置，y为0或1，表示不存在（y = 0）或存在（y = 1）; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当y等于1时，A不是5,6-二氯茚基或在7位具有氟或氯取代基的茚基和在4位上的烃基或取代的烃基取代基，并进一步提供当 y等于0，那么A不是5,6-二氟茚基。

10. 发明申请

WO2006065844A2 PROCESS FOR PRODUCING SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：生产用于烯烃聚合的取代的金属化合物的方法
公开(公告)号：WO2006065844A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045140
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

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