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1. 发明申请

WO2019132687A1 METAL COMPLEX COMPRISING AMIDINE AND THIOPHENE FUSED CYCLOPENTADIENYL LIGANDS 审中-公开
公开(公告)号：WO2019132687A1
公开(公告)日：2019-07-04
申请号：PCT/RU2017/000969
申请日：2017-12-25
申请人： ARLANXEO NETHERLANDS B.V. , LOMONOSOV MOSCOW STATE UNIVERSITY
发明人： GORYUNOV, Georgy Pavlovich , MLADENTSEV, Dmitry Yur'evich , SAMSONOV, Oleg Vladimirovich , UBORSKY, Dmitry Vadimovich , VOSKOBOYNIKOV, Alexander Zel'manovich , BERTHOUD, Alexandra , VALLA, Maxence
IPC分类号： C07F7/28 , C08F4/659 , C08F10/02 , C08F10/06
CPC分类号： C07F7/28 , C08F4/65908 , C08F4/65912 , C08F210/00 , C08F2410/01 , C08F2420/04 , C08F2420/06 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F2500/01 , C08F210/18 , C08F236/20 , C08F4/6592
摘要： A metal complex of the formula (1) TCyLMX p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, TCy is a thiophene fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 and R 2 being individually selected from the group of hydrogen, halogen, C 1 -C 10 alkyl, C 5 -C 10 cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted С 6 -С 10 aryl, in particular C 1 -C 4 -alkyl substituted phenyl and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -С 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl or R 1 and R 2 together with the 2 double bond carbon atoms of the thiophene ring they are connected to form an unsubstituted or C 1 -C 4 -alkyl substituted aliphatic C 5 -C 6 -cycloalkene ring, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10- aryl, in particular C 1 -C 4 -alkyl substituted phenyl, and SiR 3 , OR, NR 2 , SR, PR 2 , wherein R means individually C 1 -C 10 -alkyl, C 5 -C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl and, L is an amidinate ligand of the formula (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub 4 is bonded to the amino nitrogen atom N 1 , preferably Sub 4 is a C 6 -C 10 aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl.

2. 发明申请

WO2019129502A1 METAL COMPLEX COMPRISING AMIDINE AND THIOPHENE FUSED CYCLOPENTADIENYL LIGANDS 审中-公开
公开(公告)号：WO2019129502A1
公开(公告)日：2019-07-04
申请号：PCT/EP2018/084758
申请日：2018-12-13
申请人： ARLANXEO NETHERLANDS B.V.
发明人： BERTHOUD, Alexandra , VALLA, Maxence , GORYUNOV, Georgy, P. , SAMSONOV, Oleg,V. , MLADENTSEV, Dmitry,Y. , UBORSKY, Dmitry,V. , VOSKOBOYNIKOV, Alexander,Z.
IPC分类号： C07F7/28 , C08F4/659 , C08F10/02 , C08F10/06
CPC分类号： C07F7/28 , C08F4/65908 , C08F4/65912 , C08F210/00 , C08F2410/01 , C08F2420/04 , C08F2420/06 , C08F210/06 , C08F210/16 , C08F2500/03 , C08F2500/01 , C08F210/18 , C08F236/20 , C08F4/6592
摘要： A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is number of 1 to 2, preferably 2, TCy is a thiophene fused cyclopentadienyl-type ligand of the formula (2).

3. 发明申请

WO2017173080A1 OLEFIN POLYMERIZATION CATALYST SYSTEMS AND METHODS OF USE THEREOF 审中-公开
标题翻译：烯烃聚合催化剂体系及其使用方法
公开(公告)号：WO2017173080A1
公开(公告)日：2017-10-05
申请号：PCT/US2017/025022
申请日：2017-03-30
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： BAILEY, Brad C. , CHRISTIANSON, Matthew D. , DAVIS, Anna V. , PATTON, Jasson T. , PAINE, Tomas
IPC分类号： C08F210/16 , C08F4/642
CPC分类号： C08F210/16 , C08F2410/01 , C08F210/06 , C08F2500/01 , C08F2500/03 , C08F4/64044 , C08F2/38
摘要： Olefin polymerization catalyst systems are provided that include a procatalyst component having a metal-ligand complex of Formula (I): [formula] (I) where each X is a neutral, monoanionic, or dianionic, monodentate or polydentate ligand such that the complex of Formula (I) is neutral; each R 1 and R 10 is a (C 6 -C 40 )aryl, substituted (C 6 -C 40 )aryl, (C 3 -C 40 )heteroaryl, or substituted (C 3 -C 40 )heteroaryl; each R 2 , R 3 , R 4 , R 7 , R 8 , and R 9 is a hydrogen; (C 1 -C 40 )hydrocarbyl; substituted (C 1 -C 40 )hydrocarbyl; (C 1 -C 40 )heterohydrocarbyl; substituted (C 1 -C 40 )heterohydrocarbyl; halogen; or nitro (NO 2 ) group; and each R 5 and R 6 is a (C 1 -C 40 )alkyl; substituted (C 1 -C 40 )alkyl; or [(Si) 1 -(C+Si) 40 ] substituted organosilyl. Additionally, olefin-based polymers and processes for polymerizing one or more olefin-based polymers in the presence of the olefin polymerization catalyst systems are also provided.
摘要翻译：提供了烯烃聚合催化剂体系，其包含具有式（I）的金属 - 配体络合物的前催化剂组分：[式（I）]其中每个X是中性，单阴离子或双阴离子单齿或多齿配体，使得式（I）的络合物是中性的; 每个R 1和R 10是（C≡C-40）芳基，取代的（C _{-C <子> 40 ）杂芳基; 每个R 2，R 3，R 4，R 7，R 8，R 8，R 8，R 8，，而R 9是氢; （C <子> 1 -C <子> 40 ）烃基; 取代的（C 1 -C 40）烃基; （C <子> 1 -C <子> 40 ）杂烃基; 取代的（C 1 -C 40）杂烃基; 卤素; 或硝基（NO 2）基团; 并且每个R 5和R 6是（C 1 -C 40））烷基; 取代的（C 1 -C 40）烷基; 或[（Si）1 - （C + Si）40]取代的有机甲硅烷基。另外，还提供了烯烃基聚合物和在烯烃聚合催化剂体系存在下聚合一种或多种烯烃基聚合物的方法。}

4. 发明申请

WO2016153682A8 BISPHENOLATE TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
标题翻译：双苯乙烯过渡金属配合物，其生产和用途
公开(公告)号：WO2016153682A8
公开(公告)日：2017-07-27
申请号：PCT/US2016019180
申请日：2016-02-23
申请人： EXXONMOBIL CHEMICAL PATENTS INC
发明人： ATIENZA CRISITA CARMEN H , CANO DAVID A , HAGADORN JOHN R , SHAH RHUTESH K
IPC分类号： C07F7/00 , C07F7/28 , C07F17/00 , C08F4/6592 , C08F10/00
CPC分类号： C07F7/006 , C08F210/16 , C08F210/14 , C08F2500/01 , C08F2500/03 , C08F210/06 , C08F10/00 , C08F4/64189 , C08F4/64186 , C08F210/02 , C08F232/06 , C08F236/20
摘要： Bis phenolate transition metal complexes are disclosed for use in alkene polymerization, with optional chain transfer agent, to produce polyolefins.
摘要翻译：双酚盐过渡金属络合物被公开用于烯烃聚合中，用任选的链转移剂来生产聚烯烃。

5. 发明申请

WO2017099491A1 올레핀계 중합체 审中-公开
标题翻译：烯烃聚合物
公开(公告)号：WO2017099491A1
公开(公告)日：2017-06-15
申请号：PCT/KR2016/014369
申请日：2016-12-08
申请人： 주식회사 엘지화학
发明人： 박상은 , 박해웅 , 이충훈 , 정승환 , 우지윤 , 김효주 , 이영우
IPC分类号： C08F10/00 , C08F210/00
CPC分类号： C08F210/16 , C08F2/04 , C08F4/42 , C08F10/00 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/14 , C08F212/08 , C08F212/36 , C08F236/045 , C08F236/06 , C08F2500/01 , C08F2500/04 , C08F2500/08 , C08F2800/20
摘要： 본 발명에서는 하기 (1) 내지 (4)의 요건을 충족하여, 인장 강도 등의 기계적 물성의 저하 없이 개선된 충격 강도를 나타낼 수 있는 올레핀계 중합체를 제공한다: (1) 밀도(d): 0.850 내지 0.910 g/cc, (2) 용융지수(MI, 190 ℃, 2.16 kg 하중 조건): 0.1 내지 100 g/10분, (3) 분자량 분포(MWD): 1.5 내지 3.0, (4) 온도상승 용리 분별(TREF; temperature rising elution fractionation) 측정시 -20 ℃ 내지 120 ℃ 온도 범위에서 2개의 피크를 가지며, T(90)-T(50)≥60℃ (여기서, T(90)은 올레핀계 중합체의 90중량%가 용출되는 온도이고, T(50)은 올레핀계 중합체의 50중량%가 용출되는 온도이다)
摘要翻译：本发明提供满足以下要求（1）至（4）的烯烃聚合物，并且可以表现出改进的冲击强度而不降低机械性能如拉伸强度：（1）密度（d）：0.850-0.910g / cc，（2）熔体指数（MI，190℃，2.16kg负荷条件）：0.1-100g / （4）T（90）-T（50）≥60℃，其中当测量升温洗脱分级时，T（2）在-20℃至120℃的温度范围内具有两个峰（90）为烯烃聚合物洗脱90重量％时的温度，T（50）为50重量％烯烃聚合物洗脱时的温度。

6. 发明申请

WO2017093169A1 A PROCATALYST FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：烯烃聚合反应的催化剂
公开(公告)号：WO2017093169A1
公开(公告)日：2017-06-08
申请号：PCT/EP2016/078962
申请日：2016-11-28
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： ALMOHAMMADI, Bandar, Abdullah , MOMAN, Akhlaq , ALSHAIBAN, Ahmad, Abdullah , SIDDIQUI, Inaamul, Haq , PADMANABHAN, Sudhakar, R
IPC分类号： C08F110/06 , C08F4/651 , C08F10/06
CPC分类号： C08F110/06 , C08F4/651 , C08F10/06 , C08F2500/01 , C08F2500/04
摘要： The present invention relates to a procatalyst for polymerization of olefins, which procatalyst is based on a magnesium compound of the formula MgR'R" wherein R' is an alkoxide or aryloxide group and wherein R" is an alkoxide or aryloxide group or halogen, preferably a magnesium dialkoxide compound, that has been reacted with a tetravalent titanium halide, an activator being a monoester and an internal donor represented by a compound according to formula B:wherein each R 80 group is independently a linear, branched or cyclic hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 30 carbon atoms; R 81 , R 82 , R 83 , R 84 , R 85 , and R 86 are each independently selected from hydrogen or a linear, branched or cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 20 carbon atoms; R 87 is a hydrogen or a linear, branched or cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. Moreover, the present invention relates to a polymerization catalyst system comprising the procatalyst, a co-catalyst and optionally an external electron donor; to a process of making a polyolefin, preferably a polypropylene by contacting an olefin with the catalyst system; to a polyolefin, preferably a polypropylene, obtained by or obtainable by the process; to a polyolefin, preferably a polypropylene, having a molecular weight distribution of between 3 and 15, a molecular weight (M w ) of between 200,000 to 1,000,000 g/mol, a melting temperature of more than 145 °C, a value for the xylene solubles of less than 4 wt.% and a shaped article therefrom.
摘要翻译：本发明涉及用于烯烃聚合的前催化剂，其主催化剂基于式MgR'R“的镁化合物，其中R'是醇盐或芳族氧化物基团，并且其中R“ 是已经与四价钛卤化物反应的醇盐或芳基氧化物基团或卤素，优选二醇镁化合物，活化剂是单酯和由式B化合物代表的内部给体：其中每个R 80 基团独立地为选自烷基，烯基，芳基，芳烷基或烷芳基的线性，支化或环状烃基，以及它们的一种或多种组合，优选具有1至30个碳原子; R 81，R 82，R 83，R 84，R 85，R 85，和R 86各自独立地选自氢或选自烷基，链烯基，芳基，芳烷基或烷芳基的直链，支链或环状烃基，以及它们的一种或多种组合，优选具有 1至20个碳原子; R 87是氢或选自烷基，烯基，芳基，芳烷基，烷氧基羰基或烷基芳基的直链，支链或环状烃基，以及它们的一种或多种组合，优选具有1-20 碳原子; N是氮原子; O是氧原子; C是碳原子。此外，本发明涉及包含前催化剂，助催化剂和任选的外电子给体的聚合催化剂体系; 涉及通过使烯烃与催化剂体系接触来制备聚烯烃，优选聚丙烯的方法; 涉及由该方法获得或可由该方法获得的聚烯烃，优选聚丙烯; 涉及分子量分布为3至15，分子量（M w）为200,000至1,000,000g / mol，熔融温度高于145℃的聚烯烃，优选聚丙烯 ; C，小于4重量％的二甲苯可溶物的值和由其形成的成形制品。

7. 发明申请

WO2017019529A1 COMPOSITIONS CONTAINING LOW MOLECULAR WEIGHT PROPYLENE-BASED POLYMERS 审中-公开
标题翻译：含有低分子量丙烯聚合物的组合物
公开(公告)号：WO2017019529A1
公开(公告)日：2017-02-02
申请号：PCT/US2016/043631
申请日：2016-07-22
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： MCLENNAGHAN, Allan Walter , JIN, Yi , VAN DUN, Jozef J.
IPC分类号： C09J123/14 , C08F210/06
CPC分类号： C08L23/142 , C08F210/06 , C08F2500/01 , C08F2500/08 , C08F2500/15 , C08F2500/17 , C08L23/12 , C08L2207/10 , C09J123/142 , C08F210/14
摘要： The present disclosure provides a composition comprising: A) a propylene/C4-C10 alpha-olefin interpolymer; (i)) a total unsaturation per mole of propylene from 0.010% to 0.030%, (ii) a density from 0.855 g/cc to 0.890 g/cc, and (iii) a melt viscosity, at 177C, from 500 cP to 200,000 cP.
摘要翻译：本公开提供了一种组合物，其包含：A）丙烯/ C 4 -C 10α-烯烃互聚物; （i））每摩尔丙烯的总不饱和度为0.010％至0.030％，（ii）0.855g / cc至0.890g / cc的密度，和（iii）在177℃下的熔融粘度为500cP至200,000 厘。

8. 发明申请

WO2016200180A1 접착 필름 및 이를 포함하는 유기전자장치 审中-公开
标题翻译：粘合膜和包含其的有机电子器件
公开(公告)号：WO2016200180A1
公开(公告)日：2016-12-15
申请号：PCT/KR2016/006131
申请日：2016-06-09
申请人： 주식회사 엘지화학
发明人： 배경열 , 조윤경 , 유현지 , 양세우
IPC分类号： C09J123/22 , C09J4/00 , C09J7/02 , H01L51/52 , H01L51/00 , H01L51/56 , H01L27/32
CPC分类号： C09J7/381 , C08F2500/01 , C08F2500/02 , C09J4/00 , C09J7/20 , C09J7/30 , C09J11/08 , C09J109/00 , C09J123/22 , C09J163/00 , C09J2203/326 , C09J2423/00 , C09J2425/00 , C09J2463/00 , H01L27/32 , H01L51/00 , H01L51/004 , H01L51/0043 , H01L51/0097 , H01L51/52 , H01L51/5246 , H01L51/56 , H01L2251/5338 , H05K1/028 , H05K1/0313
摘要： 본 출원은 접착 필름, 이를 포함하는 유기전자장치, 및 이를 포함하는 조명 장치 및 디스플레이 장치에 관한 것으로서, 우수한 수분 차단 특성을 구현할 뿐만 아니라, 플랙서블한 특성을 가지면서 고온 고습 조건에서 내구 신뢰성이 우수한 유기전자장치를 제공한다.
摘要翻译：本申请涉及一种粘合膜，包括它的有机电子器件，以及一种照明装置和包括该照明装置的显示装置。本申请使得有机电子器件能够显示出优异的防潮性能，并且在高温和高湿度下具有柔性以及优异和可靠的耐久性。

9. 发明申请

WO2016196331A1 SUPPORTED METALLOCENE CATALYST SYSTEMS FOR POLYMERIZATION 审中-公开
标题翻译：支持用于聚合的金属催化剂体系
公开(公告)号：WO2016196331A1
公开(公告)日：2016-12-08
申请号：PCT/US2016/034755
申请日：2016-05-27
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： YANG, Jian , LUO, Lubin , BROWN, Steven, D. , LIAN, Xiongdong
IPC分类号： C08F110/06 , C08F4/6592
CPC分类号： C08F10/06 , C07F17/00 , C08F4/65912 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F4/65927 , C08F4/65916 , C08F4/6492 , C08F2500/01 , C08F2500/03 , C08F2500/04 , C08F2500/05
摘要： This invention relates to supported metallocene catalyst systems for polymerization, the catalyst systems comprising asymmetrically substituted indenyl groups, high surface area supports, and aluminoxane activators. This invention also relates to methods for polymerizing olefins, including methods for producing isotactic polypropylene.
摘要翻译：本发明涉及用于聚合的负载型茂金属催化剂体系，催化剂体系包括不对称取代的茚基，高表面积的载体和铝氧烷活化剂。本发明还涉及烯烃聚合方法，包括制备全同立构聚丙烯的方法。

10. 发明申请

WO2016171810A1 SUPPORTED CATALYST SYSTEMS AND PROCESSES FOR USE THEREOF 审中-公开
标题翻译：支持的催化剂体系及其使用方法
公开(公告)号：WO2016171810A1
公开(公告)日：2016-10-27
申请号：PCT/US2016/021757
申请日：2016-03-10
申请人： EXXONMOBIL CHEMICAL PATENTS INC.
发明人： YE, Xuan , HAGADORN, John, R. , HOLTCAMP, Matthew, W. , DAY, Gregory, S. , SANDERS, David, F. , LOPEZ-BARRON, Carlos, R.
IPC分类号： C08F4/642 , C08F4/6592 , C08F4/02 , C08F10/02
CPC分类号： C08F210/16 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F2500/04 , C08F2500/05 , C08F2500/12 , C08F4/64148 , C08F4/60148 , C08F4/65904 , C08F210/14 , C08F2500/01 , C08F2500/03 , C08F2500/18 , C08F2500/11 , C08F2500/13 , C08F4/025
摘要： This invention relates to a supported catalyst system and process for use thereof. In particular, the catalyst system includes a pyridyldiamido transition metal complex, a metallocene compound, a support material and, optionally, an activator. The catalyst system may be used for preparing multi-modal poly olefins.
摘要翻译：本发明涉及一种负载型催化剂体系及其使用方法。特别地，催化剂体系包括吡啶基二酰氨基过渡金属络合物，茂金属化合物，载体材料和任选的活化剂。催化剂体系可用于制备多模聚烯烃。

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