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1. 发明申请

WO2006065809A3 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的异质桥联金属化合物
公开(公告)号：WO2006065809A3
公开(公告)日：2006-09-28
申请号：PCT/US2005045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/64
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）取代或未取代的茚基配体，其通过茚基环的4,5,6或7位与Y键合，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。本发明还涉及包含上述转子金属化合物，活化剂和任选的载体的催化剂体系以及它们使烯烃聚合或低聚的用途。

2. 发明申请

WO2006065843A3 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代金属茂化合物
公开(公告)号：WO2006065843A3
公开(公告)日：2006-12-07
申请号：PCT/US2005045138
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , NIKULIN MIKHAIL V , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , RYABOV ALEXEY N , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , NIKULIN MIKHAIL V , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , RYABOV ALEXEY N , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi-bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand.
摘要翻译：茂金属化合物包含过渡金属，与过渡金属π-键合的第一取代或未取代的茚基或芴基配体，与过渡金属键合的第二单阴离子配体和与茚基配体结合的二价桥基和所述第二单阴离子配体其中所述桥连基团与茚基配体的四，五，六或七位或芴基配体的一，二，三，四，五，六，七或八位连接，并且其中至少一个的第一和第二配体之一包含至少一个卤素取代基，所述卤素取代基直接键合到配体的可键合环位置处的任何sp 2碳原子。

3. 发明申请

WO2006065906A3 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065906A3
公开(公告)日：2007-02-22
申请号：PCT/US2005045245
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , COKER CATALINA L , CANICH JO ANN M , VOSKOBOYNIKOV ALEXANDER Z , RYABOV ALEXEY N , NIKULIN MIKHAIL V , LYGIN ALEXANDER V , IZMER VYATCHESLAV V , ASACHENKO ANDREY
发明人： COKER CATALINA L , CANICH JO ANN M , VOSKOBOYNIKOV ALEXANDER Z , RYABOV ALEXEY N , NIKULIN MIKHAIL V , LYGIN ALEXANDER V , IZMER VYATCHESLAV V , ASACHENKO ANDREY
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： Ametallocene compound is represented by the formula (1): A 2 Y y MX n-2 wherein: M is a transition metal atom having a coordination number of n selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom; each A is independently a substituted polycyclic arenyl ligand pi-bonded to M, each A ligand includes at least one halogen substituent directly bonded to an sp 2 carbon at a bondable ring position and, when each A is a substituted indenyl ligand and y is equal to one and the ligand includes at least one chloro, bromo or iodo substituent at the 4, 5, or 6 position of the indenyl ligand, then A also includes at least one other substituent in the indenyl ligand selected from hydrocarbyl, substituted hydrocarbyl, halogen, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, substituted germylcarbyl, or other heteroatom substituents wherein the heteroatom is bonded directly to a ring carbon of the ring structure ligand and is boron, a Group 15 atom, or a Group 16 atom, preferably boron, nitrogen, oxygen, phosphorus, or sulfur; Y is an optional bridging group containing at least one Group 13, 14, 15, or 16 element and is bonded to any single position of the ring structure of A, y is zero or 1, indicating the absence (y = 0) or presence (y =1) of Y; and the or each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when y is equal to 1, then A is not 5,6-dichloroindenyl or an indenyl group having a fluoro- or chloro substituent at the 7 position and a hydrocarbyl or substituted hydrocarbyl substituent at the 4 position, and provided further that when y is equal to 0, then A is not 5,6-difluoroindenyl.
摘要翻译：亚茂金属化合物由式（1）表示：其中：M是具有一个（C 1 -C 6）选自元素周期表第3,4,5或6族的n的配位数，或镧系元素金属原子或锕系金属原子; 每个A独立地是与M键合的取代的多环烷基配体，每个A配位体包括至少一个在可键合的环位置直接键合到sp 2 O 2上的卤素取代基，并且当每个A是取代的茚基配体并且y等于1，并且配体在茚基配体的4,5或6位包含至少一个氯，溴或碘取代基，则A还包括所选择的茚基配体中的至少一个其它取代基由烃基，取代的烃基，卤素，卤代烃基，取代的卤代烃基，甲硅烷基，取代的甲硅烷基，甲硅烷基，取代的烯基羰基或其它杂原子取代基，其中杂原子直接键合到环结构配体的环碳上，并且是硼，，或16族原子，优选硼，氮，氧，磷或硫; Y是任选的含有至少一个第13,14,15或16族的桥连基团，并且键合到A的环结构的任何单个位置，y为0或1，表示不存在（y = 0）或存在（y = 1）; 并且该X或每个X是一价阴离子配体，或两个X连接并结合到金属原子上以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当y等于1时，A不是5,6-二氯茚基或在7位具有氟或氯取代基的茚基和在4位上的烃基或取代的烃基取代基，并进一步提供当 y等于0，那么A不是5,6-二氟茚基。

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