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1. 发明申请

WO2011056431A3 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
公开(公告)号：WO2011056431A3
公开(公告)日：2011-08-25
申请号：PCT/US2010053378
申请日：2010-10-20
申请人： EXXONMOBIL CHEM PATENTS INC , GIESBRECHT GARTH R , BOLLER TIMOTHY M , VOSKOBOYNIKOV ALEXANDER Z , ASACHENKO ANDREY F , NIKULIN MIKHAIL V , TSAREV ALEXEY A
发明人： GIESBRECHT GARTH R , BOLLER TIMOTHY M , VOSKOBOYNIKOV ALEXANDER Z , ASACHENKO ANDREY F , NIKULIN MIKHAIL V , TSAREV ALEXEY A
IPC分类号： C08F4/64 , B01J31/12 , C08F10/00 , C08F210/16
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly a-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.

2. 发明申请

WO2007070046A1 HALOGEN SUBSTITUTED HETEROATOM-CONTAINING METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的含异戊烯的金属化合物
公开(公告)号：WO2007070046A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045292
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , COKER, Catalina, L. , CANICH, Jo Ann, M. , UBORSKY, Dmitry, V.
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F2420/02 , C08F2420/05 , C08F4/6592
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配位体，其与金属原子键合，并且包含至少一个与可结合环上的sp 2碳原子键合的卤素取代基配体的位置，其中所述或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

3. 发明申请

WO2006065809A2 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的杂原子桥联金属茂化合物
公开(公告)号：WO2006065809A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C08F10/00 , C08F4/64 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M为3,4,5或6族过渡金属原子或镧系金属原子或act系金属原子; E为：1）取代或未取代的茚基配体，其通过茚基环的四，五，六或七位与Y键合，或2）取代或未取代的杂茚基配体，其通过四个，五个或六个位置，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个，6,7或8位的芴基环，或4）取代或未取代的杂芴基配体，其通过杂茚基环的1,2,3,4,5或6位与Y结合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的第15族或第16族桥联杂原子取代基; 和X独立地为一价阴离子配体，或两个X连接并键合到金属原子上形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。本发明进一步涉及包含上述转铁基金属化合物，活化剂和任选的载体的催化剂体系及其用于聚合或低聚烯烃的用途。

4. 发明申请

WO2011056424A2 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
标题翻译：催化剂化合物及其用途
公开(公告)号：WO2011056424A2
公开(公告)日：2011-05-12
申请号：PCT/US2010/053324
申请日：2010-10-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , ASACHENKO, Andrey, F. , BOLLER, Timothy, M. , NIKULIN, Mikhail, V. , VOSKOBOYNIKOV, Alexander, Z. , GIESBRECHT, Garth, Ronald , TSAREV, Alexey, A.
发明人： ASACHENKO, Andrey, F. , BOLLER, Timothy, M. , NIKULIN, Mikhail, V. , VOSKOBOYNIKOV, Alexander, Z. , GIESBRECHT, Garth, Ronald , TSAREV, Alexey, A.
IPC分类号： C08F4/64 , C08F10/00 , C08F210/16 , B01J31/12
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefms, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：提供了含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可以有或没有活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

5. 发明申请

WO2006065809A3 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的异质桥联金属化合物
公开(公告)号：WO2006065809A3
公开(公告)日：2006-09-28
申请号：PCT/US2005045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/64
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）取代或未取代的茚基配体，其通过茚基环的4,5,6或7位与Y键合，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。本发明还涉及包含上述转子金属化合物，活化剂和任选的载体的催化剂体系以及它们使烯烃聚合或低聚的用途。

6. 发明申请

WO2005108435A1 PHOSPHORUS BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的磷酸盐桥联金属化合物
公开(公告)号：WO2005108435A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/008093
申请日：2005-03-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , KAZYULKIN, Denis, N. , IZMER, Vyatcheslav, V. , RYABOV, Alexey, N. , CANICH, Jo, Ann, M.
IPC分类号： C08F4/64
CPC分类号： B01J31/2295 , B01J31/143 , B01J31/146 , B01J2531/0225 , B01J2531/0297 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/02 , C08F210/16 , Y10S526/943 , C08F4/65927 , C08F2500/03 , C08F210/14
摘要： This invention relates to metallocene compounds represented by formula: wherein, M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is a substituted or unsubstituted indenyl ligand that is bonded to Y through the two position of the indenyl ring; A is bonded to Y, and is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substututed or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E; Y is a phosphorus containing group that is bonded to both E and A, and is bonded via the phosphorus atom to E; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的茂金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是通过茚基环的两个位置与Y键合的取代或未取代的茚基配体; A与Y结合，为取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的芴基配位体，或其它单阴离子配体，或者A可以独立地定义为E; Y是与E和A键合的含磷基团，通过磷原子与E结合; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

7. 发明申请

WO2012134613A3 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
公开(公告)号：WO2012134613A3
公开(公告)日：2012-10-04
申请号：PCT/US2012/022473
申请日：2012-01-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , HAGADORN, John, R. , GANESH, Renuka, N. , UBORSKY, Dmitry, V. , BORISOV, Iiya, S. , PRUSS, Ivan, V. , VOSKOBOYNIKOV, Alexander, Z.
发明人： HAGADORN, John, R. , GANESH, Renuka, N. , UBORSKY, Dmitry, V. , BORISOV, Iiya, S. , PRUSS, Ivan, V. , VOSKOBOYNIKOV, Alexander, Z.
IPC分类号： C07F7/28 , C07F7/00 , C07F3/00 , C07F9/00 , C07F11/00 , C07F13/00
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization.

8. 发明申请

WO2012134613A2 PYRIDYLDIAMIDO TRANSITION METAL COMPLEXES, PRODUCTION AND USE THEREOF 审中-公开
标题翻译： PYRIDYLDIAMIDO过渡金属复合物，生产和使用
公开(公告)号：WO2012134613A2
公开(公告)日：2012-10-04
申请号：PCT/US2012022473
申请日：2012-01-25
申请人： EXXONMOBIL CHEM PATENTS INC , HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
发明人： HAGADORN JOHN R , GANESH RENUKA N , UBORSKY DMITRY V , BORISOV IIYA S , PRUSS IVAN V , VOSKOBOYNIKOV ALEXANDER Z
IPC分类号： C07F7/28 , C07F3/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F13/00
CPC分类号： C07F7/006 , B01J31/143 , B01J31/146 , B01J31/1815 , B01J31/183 , B01J2531/0241 , B01J2531/0297 , B01J2531/48 , B01J2531/49 , C07D213/38 , C07D213/48 , C07D213/53 , C07F7/00 , C07F7/003 , C08F10/00 , C08F110/06 , C08F210/16 , C08F2500/03 , C08F210/14 , C08F4/64148 , C08F4/64144
摘要： Pyridyldiamido transition metal complexes are disclosed for use in alkene polymerization.
摘要翻译：公开了用于烯烃聚合的吡啶基二酰氨基过渡金属络合物。

9. 发明申请

WO2011056424A3 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
标题翻译：催化剂化合物及其用途
公开(公告)号：WO2011056424A3
公开(公告)日：2011-08-18
申请号：PCT/US2010053324
申请日：2010-10-20
申请人： EXXONMOBIL CHEM PATENTS INC , ASACHENKO ANDREY F , BOLLER TIMOTHY M , NIKULIN MIKHAIL V , VOSKOBOYNIKOV ALEXANDER Z , GIESBRECHT GARTH RONALD , TSAREV ALEXEY A
发明人： ASACHENKO ANDREY F , BOLLER TIMOTHY M , NIKULIN MIKHAIL V , VOSKOBOYNIKOV ALEXANDER Z , GIESBRECHT GARTH RONALD , TSAREV ALEXEY A
IPC分类号： C08F4/64 , B01J31/12 , C08F10/00 , C08F210/16
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly a-olefms, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：提供含有双阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可以在有或没有活化剂的情况下用于聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

10. 发明申请

WO2011056432A2 CATALYST COMPOUNDS AND USE THEREOF 审中-公开
标题翻译：催化剂化合物及其用途
公开(公告)号：WO2011056432A2
公开(公告)日：2011-05-12
申请号：PCT/US2010/053385
申请日：2010-10-20
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , GIESBRECHT, Garth, R. , BOLLER, Timothy, M. , VOSKOBOYNIKOV, Alexander, Z. , ASACHENKO, Andrey, F. , NIKULIN, Mikhail, V. , TSAREV, Alexey, A.
发明人： GIESBRECHT, Garth, R. , BOLLER, Timothy, M. , VOSKOBOYNIKOV, Alexander, Z. , ASACHENKO, Andrey, F. , NIKULIN, Mikhail, V. , TSAREV, Alexey, A.
IPC分类号： C08F4/64 , C08F10/00 , C08F10/02 , B01J31/12
CPC分类号： C07F7/00 , C07F7/003
摘要： This invention relates to Group 4 dialkyl compounds supported by a pyridyl-amido-aryl ("PAA"), an anisole-amido-aryl ("AAA"), a phenoxy-amido-pyridyl ("PAPY"), an anisole- amido-phenoxy ("AAP") or a anisole-amido-phenoxy ("AAP") tridentate ligand. Such compounds can polymerize olefins, such as ethylene.
摘要翻译：本发明涉及由吡啶基 - 酰氨基 - 芳基（“PAA”），苯甲醚 - 酰氨基 - 芳基（“AAA”），苯氧基 - 酰胺基 - 吡啶基（“PAPY”），苯甲酰胺基 - 苯氧基（“AAP”）或苯甲醚 - 酰氨基 - 苯氧基（“AAP”）三齿配体。这样的化合物可以聚合烯烃，如乙烯。

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