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1. 发明申请

WO2006065809A2 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的杂原子桥联金属茂化合物
公开(公告)号：WO2006065809A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , NIKULIN, Mikhail, V. , RYABOV, Alexey, N. , LEBEDEV, Artyom, Y. , COKER, Catalina, L. , CANICH, Jo Ann, M.
IPC分类号： C08F10/00 , C08F4/64 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M为3,4,5或6族过渡金属原子或镧系金属原子或act系金属原子; E为：1）取代或未取代的茚基配体，其通过茚基环的四，五，六或七位与Y键合，或2）取代或未取代的杂茚基配体，其通过四个，五个或六个位置，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个，6,7或8位的芴基环，或4）取代或未取代的杂芴基配体，其通过杂茚基环的1,2,3,4,5或6位与Y结合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂茚基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的第15族或第16族桥联杂原子取代基; 和X独立地为一价阴离子配体，或两个X连接并键合到金属原子上形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体。本发明进一步涉及包含上述转铁基金属化合物，活化剂和任选的载体的催化剂体系及其用于聚合或低聚烯烃的用途。

2. 发明申请

WO2006065809A3 HETEROATOM BRIDGED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的异质桥联金属化合物
公开(公告)号：WO2006065809A3
公开(公告)日：2006-09-28
申请号：PCT/US2005045056
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , NIKULIN MIKHAIL V , RYABOV ALEXEY N , LEBEDEV ARTYOM Y , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/64
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand. This invention further relates to catalyst systems comprising the above transiotioon metal compounds , activators and optional supports and their use to polymerize or oligomerize olefins.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）取代或未取代的茚基配体，其通过茚基环的4,5,6或7位与Y键合，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。本发明还涉及包含上述转子金属化合物，活化剂和任选的载体的催化剂体系以及它们使烯烃聚合或低聚的用途。

3. 发明申请

WO2006065843A3 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代金属茂化合物
公开(公告)号：WO2006065843A3
公开(公告)日：2006-12-07
申请号：PCT/US2005045138
申请日：2005-12-14
申请人： EXXONMOBIL CHEM PATENTS INC , VOSKOBOYNIKOV ALEXANDER Z , NIKULIN MIKHAIL V , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , RYABOV ALEXEY N , COKER CATALINA L , CANICH JO ANN M
发明人： VOSKOBOYNIKOV ALEXANDER Z , NIKULIN MIKHAIL V , IZMER VYATCHESLAV V , ASACHENKO ANDREI F , RYABOV ALEXEY N , COKER CATALINA L , CANICH JO ANN M
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi-bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand.
摘要翻译：茂金属化合物包含过渡金属，与过渡金属π-键合的第一取代或未取代的茚基或芴基配体，与过渡金属键合的第二单阴离子配体和与茚基配体结合的二价桥基和所述第二单阴离子配体其中所述桥连基团与茚基配体的四，五，六或七位或芴基配体的一，二，三，四，五，六，七或八位连接，并且其中至少一个的第一和第二配体之一包含至少一个卤素取代基，所述卤素取代基直接键合到配体的可键合环位置处的任何sp 2碳原子。

4. 发明申请

WO2006065843A2 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2006065843A2
公开(公告)日：2006-06-22
申请号：PCT/US2005/045138
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , NIKULIN, Mikhail, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , NIKULIN, Mikhail, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , RYABOV, Alexey, N. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
IPC分类号： C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi-bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp 2 carbon atom at a bondable ring position of the ligand.
摘要翻译：包含过渡金属，与过渡金属键合的第一取代或未取代的茚基或芴基配体的茂金属化合物，与过渡金属键合的第二单离子配体和键合到茚基配体和所述第二单离子配体的二价桥连基团其中所述桥连基连接到茚基配体的四，五，六或七位，或连接到芴基配体的一个，二个，三个，四个，五个，六个，七个或八个位置，并且其中至少一个第一和第二配体之一包含在配体的可键合环位置处直接键合到任何sp2碳原子上的至少一个卤素取代基。

5. 发明申请

WO2007070038A1 HALOGEN SUBSTITUTED METALLOCENE COMPOUNDS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的卤素取代的金属化合物
公开(公告)号：WO2007070038A1
公开(公告)日：2007-06-21
申请号：PCT/US2005/045137
申请日：2005-12-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
发明人： VOSKOBOYNIKOV, Alexander, Z. , RYABOV, Alexey, N. , NIKULIN, Mikhail, V. , LYGIN, Alexander, V. , IZMER, Vyatcheslav, V. , ASACHENKO, Andrei, F. , COKER, Catalina, L. , CANICH, Jo, Ann, M.
IPC分类号： C07F17/00 , C08F4/6592 , C08F10/02
CPC分类号： C08F10/02 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F110/02 , C08F210/16 , C08F4/6592 , C08F4/65925 , C08F2500/03 , C08F210/14
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp 2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：茂金属化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包含至少一个直接连接到sp 2 O 2原子上的卤素取代基所述芳族配体的芳族五元环的可键合环位置。

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