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1. 发明申请

WO2012091880A2 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：从含有原油的地层采收的增强烃的方法和组合物
公开(公告)号：WO2012091880A2
公开(公告)日：2012-07-05
申请号：PCT/US2011/064083
申请日：2011-12-09
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BARNES, Julian Richard , BUECHELE, James Laurel , ELLISON, Robert Hardy , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SMIT, Johan Paul
发明人： BARNES, Julian Richard , BUECHELE, James Laurel , ELLISON, Robert Hardy , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SMIT, Johan Paul
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
CPC分类号： C09K8/584
摘要： A hydrocarbon recovery composition comprising vinylidene based alkoxylate derivatives. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：包含基于亚乙烯基的烷氧基化物衍生物的烃采收组合物。还描述了处理原油地层的方法和制备烃采收组合物的方法。

2. 发明申请

WO2012091881A3 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
公开(公告)号：WO2012091881A3
公开(公告)日：2012-07-05
申请号：PCT/US2011/064088
申请日：2011-12-09
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , WILLIAM MARSH RICE UNIVERSITY , BARNES, Julian Richard , ELLISON, Robert Hardy , PUERTO, Maura , RANEY, Kirk Herbert , SMIT, Johan Paul
发明人： BARNES, Julian Richard , ELLISON, Robert Hardy , PUERTO, Maura , RANEY, Kirk Herbert , SMIT, Johan Paul
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
摘要： A hydrocarbon recovery composition comprising vinylidene olefin sulfonates is described. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.

3. 发明申请

WO2012091881A2 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：来自含有原油的成分的增强烃回收的方法和组合物
公开(公告)号：WO2012091881A2
公开(公告)日：2012-07-05
申请号：PCT/US2011064088
申请日：2011-12-09
申请人： SHELL OIL CO , SHELL INT RESEARCH , UNIV RICE WILLIAM M , BARNES JULIAN RICHARD , ELLISON ROBERT HARDY , PUERTO MAURA , RANEY KIRK HERBERT , SMIT JOHAN PAUL
发明人： BARNES JULIAN RICHARD , ELLISON ROBERT HARDY , PUERTO MAURA , RANEY KIRK HERBERT , SMIT JOHAN PAUL
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
CPC分类号： C09K8/58 , C07C309/20 , C09K8/584 , E21B43/16
摘要： A hydrocarbon recovery composition comprising vinylidene olefin sulfonates is described. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：描述了包含亚乙烯基烯烃磺酸盐的烃回收组合物。还描述了处理原油形成的方法和制备烃回收组合物的方法。

4. 发明申请

WO2008077911A1 LIGANDS AND CATALYST SYSTEMS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：用于烯烃单体低级化的配体和催化剂体系
公开(公告)号：WO2008077911A1
公开(公告)日：2008-07-03
申请号：PCT/EP2007/064398
申请日：2007-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07F9/535 , C07F11/00 , B01J31/18
CPC分类号： C07F11/005 , B01J31/0265 , B01J31/189 , B01J2231/20 , B01J2531/60 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F9/5355
摘要： The present invention relates to a ligand having the general formula (I) : (R 1 ) 2 P-P(R 1 )m(R 2 ) n =N(R3) (I) wherein R3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions, with the proviso that m is 0 or 1, n is 1 or 2 and the total of m + n is 2. The present invention also relates to catalyst systems and a process for the simultaneous trimerization and tetramerization of olefinic monomers using said ligands.
摘要翻译：本发明涉及具有通式（I）的配体：（R 1）2 PP（R 1）2（R 1）其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; 并且R 0-2基团独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当基团是芳族的时，其在任何邻位不含极性取代基，条件是m为0或1，n为1或2，m + n的总和为2.本发明还涉及使用所述配体的烯烃单体的同时三聚和四聚的催化剂体系和方法。

5. 发明申请

WO2007057455A1 CATALYTIC OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体的催化低聚
公开(公告)号：WO2007057455A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068652
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： B01J31/24 , B01J31/18 , B01J31/34 , C07C2/32 , C07C2/36
CPC分类号： C07C2/36 , B01J31/188 , B01J31/34 , B01J2231/20 , B01J2531/62 , C07C2531/14 , C07C2531/24 , C07F9/46
摘要： A catalyst precursor composition comprising: a) a source of chromium, molybdenum or tungsten; b) a first ligand having the general formula (I) ; (R 1 ) (R 2 ) P-X-P(R 3 ) (R 4 ) wherein: X is a bridging group of the formula -N(R 5 )-, wherein R 5 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; at least three of R 1 to R 4 are independently selected from optionally substituted aromatic groups, each bearing a polar substituent on at least one of the ortho-positions; and optionally one of R 1 to R 4 is independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; c) a second ligand having the general formula (II) ; (R 1 ' ) (R 2 ' ) P-X'-P(R 3 ' ) (R 4 ' ) wherein: X' is a bridging group as defined for X of the first ligand, component (b) , of general formula (I) ; at least R 1 ' and R 2 ' of R 1 ' to R 4 ' are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups with the proviso that when the group is aromatic it does not contain a polar substituent at any of the ortho-positions; and optionally none, one or both of R 3 ' and R 4 ' are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions. The present invention also relates to a catalyst system comprising the catalyst precursor composition of the present invention and additional component; d) a cocatalyst. The present invention further relates to a process for the trimerization and tetramerization of olefinic monomers, particularly the trimerization and tetramerization of ethylene to 1-hexene and 1-octene, wherein the process comprises contacting at least one olefinic monomer with the catalyst system of the present invention.
摘要翻译：一种催化剂前体组合物，其包含：a）铬，钼或钨的来源; b）具有通式（I）的第一配体; （R 1）（R 2）PXP（R 3）（R 4）其中：X是式-N（R 5） - 的桥连基团，其中R 5选自氢，烃基，取代的烃基，杂烃基，取代的异烃基，甲硅烷基或其衍生物; R 1至R 4中的至少三个独立地选自任选取代的芳族基团，其各自在至少一个邻位上带有极性取代基; 并且任选的R 1至R 4中的一个独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，条件是当该基团为芳族时，其不含任何邻位的极性取代基; c）具有通式（II）的第二配体; （R'1）（R 2）P-X'-P（R 3）（R 4）其中：X'是如通式（I）的第一配体组分（b）的X所定义的桥连基团; R 1至R 4的至少R 1'和R 2'独立地选自烃基取代的烃基，杂烃基和取代的杂烃基，条件是当该基团是芳族的时，它在任何邻位不含极性取代基; 并且任选地，R“3”和“R”4中的任一个或两个独立地选自在至少一个邻位取代基上带有极性取代基的任选取代的芳族基团，位置。本发明还涉及包含本发明的催化剂前体组合物和另外的组分的催化剂体系; d）助催化剂。本发明还涉及烯烃单体的三聚和四聚的方法，特别是乙烯对1-己烯和1-辛烯的三聚和四聚，其中该方法包括使至少一种烯属单体与本发明的催化剂体系接触发明。

6. 发明申请

WO2005005354A1 PROCESS FOR PRODUCING LINEAR ALPHA OLEFINS 审中-公开
标题翻译：生产线性ALPHA油脂的方法
公开(公告)号：WO2005005354A1
公开(公告)日：2005-01-20
申请号：PCT/EP2004/051365
申请日：2004-07-06
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , KRAGTWIJK, Eric , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , KRAGTWIJK, Eric , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
IPC分类号： C07C2/32
CPC分类号： C07C2/32 , B01J31/143 , B01J31/1815 , B01J2231/20 , B01J2531/842 , B01J2531/845 , C07C2531/14 , C08F10/00 , C08F4/7042
摘要： A process for the production of alpha-olefins comprising reacting ethylene under oligomerisation conditions in the presence of a mixture comprise ng: (a) a metal salt based on Fe (II), Fe (III), Co (II) or Co(III); (b) a pyridine bis-imine ligand; and (c) a co-catalyst which is the reaction product of water with one or more organometallic aluminium compounds, wherein the one or more organometallic aluminium compounds is selected from: (i) ßδ-branched compounds of Formula (I): Al (CH 2 ,-CR 1 R 2 -CH 2 ,-CR 4 R 5 R 6 ) X R 3 Y H Z ; (ii) ßγ-branched compounds of Formula (II) Al (CH 2 -CR 1 R 2 -CR 4 R 5 R 6 ) X R 3 Y H Z and mixtures thereof; wherein when the metal salt and the bis-arylimine pyridine ligand are mixed together they are soluble in aliphatic or aromatic hydrocarbon solvent.
摘要翻译：一种制备α-烯烃的方法，包括在低聚条件下在混合物存在下使乙烯反应，包括：（a）基于Fe（II），Fe（III），Co（II）或Co（III）的金属盐）; （b）吡啶双亚胺配体; 和（c）作为水与一种或多种有机金属铝化合物的反应产物的助催化剂，其中一种或多种有机金属铝化合物选自：（i）式（I）的β支链化合物：Al CH 2，-CR 1 R 2 -CH 2，-CR 4 R 5 R 6）XR 3 YHZ; （ⅱ）式（II）ßg支链化合物Al（CH 2 -CR 1 R 2 -CR 4 R 5 R 6）XR 3 YHZ及其混合物; 其中当将金属盐和双芳基亚胺吡啶配体混合在一起时，它们可溶于脂族或芳族烃溶剂。

7. 发明申请

WO2005090371A1 TRANSITION METAL COMPLEXES 审中-公开
标题翻译：过渡金属复合物
公开(公告)号：WO2005090371A1
公开(公告)日：2005-09-29
申请号：PCT/EP2005/051316
申请日：2005-03-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
发明人： DE BOER, Eric, Johannes, Maria , VAN DER HEIJDEN, Harry , ON, Quoc, An , SMIT, Johan, Paul , VAN ZON, Arie
IPC分类号： C07F13/00
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0244 , B01J2531/842 , B01J2531/845 , C07F11/005 , C07F15/025 , C07F15/065 , C08F10/00 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： A transition metal complex which is a bis-arylimine pyridine MX n complex, comprising a bis-arylimine pyridine ligand having the formula (I), wherein R 1 -R 5 , R 7 -R 9 , R 12 and R 14 are each, independently, hydrogen, optionally substituted hydrocarbyl, an inert functional group, or any two of R 1 -R 3 and R 7 -R 9 vicinal to one another taken together may form a ring, and R 6 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 7 or R 4 to form a ring, R 10 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 9 or R 4 to form a ring, R 11 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 12 or R 5 to form a ring, R 15 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R 14 or R 5 to form a ring, provided that R 13 and at least one of R 12 and R 14 are independently selected from optionally substituted C 1 -C 30 alkyl, optionally substituted C 4 -C 30 alkyloxy, halogen and optionally substituted C 5 -C 20 aryl, or R 13 taken together with R 12 or R 14 form a ring, or R 12 taken together with R 11 form a ring and R 14 taken together with R 15 form a ring, and provided that at least one of R 12 , R 13 and R 14 is optionally substituted C 4 -C 30 alkyloxy; M is a transition metal atom in particular selected from Ti, V, Cr, Mn, Fe, Co, Ni, Pd, Rh, Ru, Mo, Nb, Zr, Hf, Ta, W, Re, Os, Ir or Pt; n matches the formal oxidation state of the transition metal atom M; and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co)oligomerization, polymerization and dimerization reactions.
摘要翻译：一种二芳基亚胺吡啶MXn络合物的过渡金属络合物，其包含具有式（I）的双芳基亚胺吡啶配体，其中R1-R5，R7-R9，R12和R14各自独立地为氢，任选取代的烃基，惰性官能团或彼此相邻的R 1 -R 3和R 7 -R 9中的任何两个可以一起形成环，并且R 6是氢，任选取代的烃基，惰性官能团，或与R 7或R 4一起形成环，R 10为氢，任选取代的烃基，惰性官能团，或与R 9或R 4一起形成环，R 11为氢，任选取代的烃基，惰性官能团，或与R 12或R 5一起形成环，R 15是氢，任选取代的烃基，惰性官能团，或与R 14或R 5一起形成环，条件是R 13和R 12和R 14中的至少一个独立地选自任选取代的C 1 -C 30烷基，选项烯基取代的C 4 -C 30烷氧基，卤素和任选取代的C 5 -C 20芳基，或R 13与R 12或R 14一起形成环，或R 12与R 11一起形成环，R 14与R 15一起形成环， R 12，R 13和R 14中的至少一个是任选取代的C 4 -C 30烷氧基; M是特别选自Ti，V，Cr，Mn，Fe，Co，Ni，Pd，Rh，Ru，Mo，Nb，Zr，Hf，Ta，W，Re，Os，Ir或Pt中的过渡金属原子; n匹配过渡金属原子M的正式氧化态; X是卤化物，任选取代的烃基，醇盐，酰胺或氢化物。本发明的过渡金属络合物，它们与非配位阴离子的配合物和含有这种络合物的催化剂体系在非极性介质和化学惰性非极性溶剂，特别是芳族烃溶剂中具有良好的溶解性。催化剂体系可用于广泛的（共）低聚，聚合和二聚反应。

8. 发明申请

WO2012091880A3 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A FORMATION CONTAINING A CRUDE OIL 审中-公开
标题翻译：来自含有原油的成分的增强烃的回收方法和组合物
公开(公告)号：WO2012091880A3
公开(公告)日：2012-08-23
申请号：PCT/US2011064083
申请日：2011-12-09
申请人： SHELL OIL CO , SHELL INT RESEARCH , BARNES JULIAN RICHARD , BUECHELE JAMES LAUREL , ELLISON ROBERT HARDY , RANEY KIRK HERBERT , SEMPLE THOMAS CARL , SMIT JOHAN PAUL
发明人： BARNES JULIAN RICHARD , BUECHELE JAMES LAUREL , ELLISON ROBERT HARDY , RANEY KIRK HERBERT , SEMPLE THOMAS CARL , SMIT JOHAN PAUL
IPC分类号： C09K8/58 , C09K8/32 , E21B43/16
CPC分类号： C09K8/584
摘要： A hydrocarbon recovery composition comprising vinylidene based alkoxylate derivatives. A method of treating a crude oil formation and a method of preparing the hydrocarbon recovery composition are also described.
摘要翻译：一种含有亚乙烯基的烷氧基化物衍生物的烃回收组合物。还描述了处理原油形成的方法和制备烃回收组合物的方法。

9. 发明申请

WO2010120833A1 METHOD AND COMPOSITION FOR ENHANCED HYDROCARBONS RECOVERY FROM A VERY HIGH SALINITY, HIGH TEMPERATURE FORMATION 审中-公开
标题翻译：来自非常高的盐度，高温形成的增强烃的回收方法和组合
公开(公告)号：WO2010120833A1
公开(公告)日：2010-10-21
申请号：PCT/US2010/030960
申请日：2010-04-14
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BARNES, Julian Richard , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SHPAKOFF, Paul Gregory , SMIT, Johan Paul , SMIT, Jasper Roelf
发明人： BARNES, Julian Richard , RANEY, Kirk Herbert , SEMPLE, Thomas Carl , SHPAKOFF, Paul Gregory , SMIT, Johan Paul , SMIT, Jasper Roelf
IPC分类号： C09K8/584
CPC分类号： C09K8/584
摘要： A method of treating a very high salinity high temperature hydrocarbon containing formation is described. The method includes (a) providing a hydrocarbon recovery composition to at least a portion of a hydrocarbon containing formation having a brine salinity of above about 13 wt% and a temperature of above about 7°C, wherein the composition comprises a C 15-18 internal olefin sulfonate; and (b) allowing the composition to interact with hydrocarbons in the hydrocarbon containing formation.
摘要翻译：描述了处理非常高盐度的高温含烃地层的方法。该方法包括（a）向至少一部分具有高于约13重量％的盐水盐度和高于约7℃的温度的含烃地层提供烃回收组合物，其中所述组合物包含C15-18内部烯烃磺酸盐; 和（b）允许组合物与含烃地层中的烃相互作用。

10. 发明申请

WO2007057458A1 CATALYTIC PROCESS FOR THE OLIGOMERIZATION OF OLEFINIC MONOMERS 审中-公开
标题翻译：烯烃单体低级化的催化方法
公开(公告)号：WO2007057458A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068659
申请日：2006-11-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
发明人： DE BOER, Eric Johannes Maria , VAN DER HEIJDEN, Harry , ON, Quoc An , SMIT, Johan Paul , VAN ZON, Arie
IPC分类号： C07C2/36 , C07C11/107 , B01J31/24
CPC分类号： B01J31/188 , B01J31/143 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07C2/36 , C07C2531/24 , C07F9/46
摘要： A process for the simultaneous trimerization and tetramerization of olefinic monomers , wherein the process comprises contacting at least one olefinic monomer with catalyst system comprising : a) a source of chromium, molybdenum or tungsten; b) a ligand having the general formula (I) ; (R 1 ) 2 P-X-P (R 1 ) m (R 2 )n wherein : X is a bridging group of the formula -N(R 3 )-, wherein R 3 is selected from hydrogen, a hydrocarbyl group, a substituted hydrocarbyl group, a heterohydrocarbyl group, a substituted heterohydrocarbyl group, a silyl group or derivative thereof; the R 1 groups are independently selected from an optionally substituted aromatic group bearing a polar substituent on at least one of the ortho-positions; and the R 2 groups are independently selected from hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl and substituted heterohydrocarbyl groups and c) a cocatalyst, at a pressure in the range of from below atmospheric to about 40 barg and at a temperature in the range of from about 0 °C to about 120 °C. The present invention further relates to a process for the simultaneous trimerization and tetramerization of ethylene to 1-hexene and 1-octene.
摘要翻译：一种用于烯烃单体的同时三聚和四聚的方法，其中所述方法包括使至少一种烯属单体与催化剂体系接触，所述催化剂体系包括：a）铬，钼或钨的来源; b）具有通式（I）的配体; （R 1）2 PXP（R 1）2（R 2）2（R 2） n其中：X是式-N（R 3 O 3） - 的桥连基团，其中R 3选自氢，烃基，取代的烃基，杂烃基，取代的杂烃基，甲硅烷基或其衍生物; R 1基团独立地选自在至少一个邻位上带有极性取代基的任选取代的芳族基团; R 2和R 2独立地选自烃基，取代的烃基，杂烃基和取代的杂烃基，和c）助催化剂，其压力范围为低于大气压至约40巴，温度为在约0℃至约120℃的范围内。本发明还涉及一种将乙烯同时三聚和四聚到1-己烯和1-辛烯的方法。

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