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1. 发明申请

WO99046308A1 HOMOPOLYMER OF ETHYLENE 审中-公开
标题翻译：乙烯的共聚物
公开(公告)号：WO99046308A1
公开(公告)日：1999-09-16
申请号：PCT/GB1999/000713
申请日：1999-03-10
IPC分类号： C08J5/18 , C07D213/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/06 , C08F4/659 , C08F4/6592 , C08F4/70 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/61904 , C08F2500/12 , C08F2500/03 , C08F2500/04 , C08F2500/14 , C08F2500/26 , C08F2500/07 , C08F210/14 , C08F2500/10 , C08F4/60089 , C08F4/7042
摘要： A polyethylene is disclosed having the following properties: an annealed density D / weight average molecular weight Mw relationship defined by the equation D > 1104.5Mw , and a Charpy Impact I / High Load Melt Index H relationship defined by the equation I > 35.OH . A polyethylene film is also disclosed having the following properties: a density of at least 957 kg/m ; a Dart Impact of at least 130 g; and a polydispersity of less than 12. Both may be made using a tridentate nitrogen-containing transition metal polymerisation catalyst.
摘要翻译：公开了具有以下特性的聚乙烯：由方程D> 1104.5Mw <-0.0116>定义的退火密度D /重均分子量Mw关系，以及由式I定义的夏比冲击I /高载荷熔融指数H关系 > 35.OH <-0.4>。还公开了具有以下特性的聚乙烯膜：密度为至少957kg / m 3; 至少130克的飞镖撞击; 和多分散性小于12.可以使用三齿含氮过渡金属聚合催化剂来制备。

2. 发明申请

WO2008038173A2 POLYMERISATION (INCLUDING OLIGOMERISATION) OF OLEFINIC COMPOUNDS IN THE PRESENCE OF CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP 审中-公开
标题翻译：在催化剂存在下烯烃化合物的聚合（包括低聚），以及包括卤化有机基团的催化剂活化剂
公开(公告)号：WO2008038173A2
公开(公告)日：2008-04-03
申请号：PCT/IB2007/053590
申请日：2007-09-06
申请人： SASOL TECHNOLOGY (PTY) LIMITED , TOOZE, Robert Paul , HANTON, Martin John , TENZA, Kenny
发明人： TOOZE, Robert Paul , HANTON, Martin John , TENZA, Kenny
IPC分类号： B01J31/22 , B01J31/18 , B01J31/14 , C08F4/70 , C08F10/00
CPC分类号： B01J31/1815 , B01J31/143 , B01J2231/122 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/14 , C08F2500/02 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F4/7042 , C08F4/7047
摘要： According to the present invention there is provided a process for producing a polymenc (including oligomenc) product by the polymerisation (including oligomeπsation) of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom in the form of aluminium The polymeπsation (including ohgomensation) catalyst includes the combination of ι) a source of a transition metal, and n) a ligating compound of the formula (I). The invention also relates to a combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator and to the use of such a combination in a polymerisation (including ohgomensation) process.
摘要翻译：根据本发明，提供了通过至少一种烯属化合物的聚合（包括低聚）生产多聚（包括低聚）产物的方法，通过使至少一种烯属化合物与聚合（包括ohgomensation）催化剂和催化剂活化剂的组合。催化剂活化剂是包括至少一个卤代有机基团的化合物，所述卤代有机基团与选自5A族原子和基团中的一个或多个结合原子结合 6A原子，其中一个或多个结合原子又以铝的形式结合到中心原子上。聚合（包括ohgomensation）催化剂包括以下组合：1）过渡金属源，和n）公式（I）。本发明还涉及聚合（包括ohgomensation）催化剂和催化剂活化剂的组合以及这种组合在聚合（包括ohgomensation）工艺中的用途。

3. 发明申请

WO99046302A1 POLYMERISATION CATALYSTS 审中-公开
标题翻译：聚合催化剂
公开(公告)号：WO99046302A1
公开(公告)日：1999-09-16
申请号：PCT/GB1999/000714
申请日：1999-03-10
IPC分类号： C07D213/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/06 , C08F4/6192 , C08F4/659 , C08F4/6592 , C08F4/70 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerisation of 1-olefins is disclosed, which comprises (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R , R , R , R , R , R and R are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R -R are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties are also disclosed.
摘要翻译：公开了用于1-烯烃聚合的催化剂，其包括（1）式B的化合物，其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III] Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂; 并且当R 1 -R 7中的任何两个或更多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。还公开了使用具有特定物理性质的催化剂制备的共聚物。

4. 发明申请

WO2004106390A2 CATALYST COMPOSITION II 审中-公开
标题翻译：聚四氟乙烯聚合催化剂
公开(公告)号：WO2004106390A2
公开(公告)日：2004-12-09
申请号：PCT/US2004/016724
申请日：2004-05-27
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SOLAN, Gregory, A. , DAVIES, Christopher, J.
发明人： SOLAN, Gregory, A. , DAVIES, Christopher, J.
IPC分类号： C08F10/00
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX 2 or (LMX 2 ) 2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9 or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C 3 -C 50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C 3 -C 50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoamionic ligand, or two X may join together to form a bidentale dianionic ligand.
摘要翻译：本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地为第7至11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二价二离子配体。

5. 发明申请

WO00069923A1 TRANSITION METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：过渡金属复合物和烯烃聚合方法
公开(公告)号：WO00069923A1
公开(公告)日：2000-11-23
申请号：PCT/US2000/007164
申请日：2000-03-17
IPC分类号： C07D213/53 , C07D401/14 , C07D413/14 , C07F5/00 , C07F7/00 , C07F7/28 , C07F9/00 , C07F11/00 , C07F13/00 , C07F15/02 , C08F4/42 , C08F4/60 , C08F4/605 , C08F10/00 , C08F10/06 , C08F110/06 , C07F15/00
CPC分类号： C08F10/06 , C07F5/003 , C07F7/006 , C07F9/005 , C07F11/005 , C07F13/005 , C07F15/025 , C08F10/00 , C08F110/06 , C08F4/619 , C08F4/52 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F2500/03 , C08F2500/15 , C08F4/7042
摘要： Metal complexes comprising a polydentate chelating group, catalysts and polymerization processes using the same for the polymerization of olefins, especially propylene, are disclosed.
摘要翻译：公开了包含多齿螯合基团的金属络合物，其催化剂和使用该金属配合物用于烯烃聚合，特别是丙烯的聚合方法。

6. 发明申请

WO99042492A1 POLYMERISATION CATALYST COMPONENT 审中-公开
标题翻译：聚合催化剂组分
公开(公告)号：WO99042492A1
公开(公告)日：1999-08-26
申请号：PCT/GB1999/000362
申请日：1999-02-04
IPC分类号： C07F5/06 , C08F4/60 , C08F10/00 , C07F5/00
CPC分类号： C08F10/00 , C07F5/066 , C08F4/65908 , C08F4/6592 , C08F4/65912 , C08F4/60089 , C08F4/7042
摘要： A catalyst activator composition useful for the polymerisation of 1-olefins is disclosed, comprising the reaction product of a component (A) comprising a compound having the general formula: R3M wherein R is a hydrocarbyl group and M is a Group III metal, and a component (B) comprising a compound of Formula (I) or a tautomer thereof, wherein Y and Z are each independently O or NR , X is (CR R )n or NR ; R , R and R are each independently C1-C6 hydrocarbyl or halohydrocarbyl; R , R and R are each independently hydrogen or C1-C6 hydrocarbyl or halohydrocarbyl; and n is 0 or an integer of from 1 to 6; or an aluminium, boron or gallium complex of the compound of Formula (I).
摘要翻译：公开了一种可用于1-烯烃聚合的催化剂活化剂组合物，其包含包含具有以下通式的化合物的组分（A）的反应产物：其中R为烃基，M为第III族金属，包含式（I）化合物或其互变异构体的组分（B），其中Y和Z各自独立地为O或NR 5，X为（CR 3 R 4）n或NR 6; R 1，R 2和R 5各自独立地为C 1 -C 6烃基或卤代烃基; R 3，R 4和R 6各自独立地为氢或C 1 -C 6烃基或卤代烃基; n为0或1〜6的整数，或式（I）化合物的铝，硼或镓络合物。

7. 发明申请

WO2008038173A3 POLYMERISATION (INCLUDING OLIGOMERISATION) OF OLEFINIC COMPOUNDS IN THE PRESENCE OF CATALYST, AND A CATALYST ACTIVATOR INCLUDING A HALOGENATED ORGANIC GROUP 审中-公开
标题翻译：在催化剂存在下的烯烃化合物的聚合（包括低级化）和包含有机有机组的催化剂活化剂
公开(公告)号：WO2008038173A3
公开(公告)日：2008-09-18
申请号：PCT/IB2007053590
申请日：2007-09-06
申请人： SASOL TECH PTY LTD , TOOZE ROBERT PAUL , HANTON MARTIN JOHN , TENZA KENNY
发明人： TOOZE ROBERT PAUL , HANTON MARTIN JOHN , TENZA KENNY
IPC分类号： B01J31/22 , B01J31/14 , B01J31/18 , C08F4/70 , C08F10/00
CPC分类号： B01J31/1815 , B01J31/143 , B01J2231/122 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08F10/00 , C08F110/02 , C08F110/14 , C08F2500/02 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F4/7042 , C08F4/7047
摘要： According to the present invention there is provided a process for producing a polymenc (including oligomenc) product by the polymerisation (including oligomepsation) of at least one olefinic compound, by contacting the at least one olefinic compound with the combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator The catalyst activator is a compound which includes at least one halogenated organic group which is bound to one or more binding atoms selected from the group consisting of a group 5A atom and a group 6A atom, which one or more binding atoms are in turn bound to a central atom in the form of aluminium The polymepsation (including ohgomensation) catalyst includes the combination of ?) a source of a transition metal, and n) a ligating compound of the formula (I). The invention also relates to a combination of a polymerisation (including ohgomensation) catalyst and a catalyst activator and to the use of such a combination in a polymerisation (including ohgomensation) process.
摘要翻译：根据本发明，提供了通过使至少一种烯烃化合物与聚合（包括偶联）的组合接触，通过使至少一种烯属化合物进行聚合（包括少量吞吐）来生产多聚（包括寡聚）产物的方法）催化剂和催化剂活化剂催化剂活化剂是一种化合物，其包括至少一个与一个或多个选自5A族原子和6A族原子的结合原子结合的卤代有机基团，其中一个或多个结合原子又以铝的形式结合到中心原子。聚醚（包括偶联）催化剂包括α）过渡金属源和n）式（I）的连接化合物的组合。本发明还涉及聚合（包括偶联）催化剂和催化剂活化剂的组合以及在聚合（包括偶联）方法中使用这种组合。

8. 发明申请

WO2005103099A1 CATALYST SYSTEM FOR OLEFIN POLYMERIZATION, ITS PRODUCTION AND USE 审中-公开
标题翻译：用于烯烃聚合的催化剂体系，其生产和使用
公开(公告)号：WO2005103099A1
公开(公告)日：2005-11-03
申请号：PCT/EP2005/004255
申请日：2005-04-21
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , SCHMITZ, Harald
发明人： MIHAN, Shahram , SCHMITZ, Harald
IPC分类号： C08F110/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F2/34 , C08F4/61904 , C08F4/65916 , C08F4/025 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： Process for producing a catalyst system, which comprises the following steps: A) provision of a mixture of at least two different organic transition metal compounds, at least one hydrolyzed organoaluminum compound and a solvent and impregnation of a dry porous support component with the mixture from step A), with the total volume of the mixture being from 0.6 to 1.5 times the total pore volume of the support component, and also catalyst systems obtainable in this way and their use for olefin polymerization.
摘要翻译：制备催化剂体系的方法，其包括以下步骤：A）提供至少两种不同的有机过渡金属化合物，至少一种水解的有机铝化合物和溶剂的混合物，并将干燥多孔载体组分浸渍在混合物中步骤A），混合物的总体积为载体组分的总孔体积的0.6-1.5倍，以及可以以这种方式获得的催化剂体系及其在烯烃聚合中的用途。

9. 发明申请

WO2005042150A1 DIIMINE LIGAND, METAL COMPOUND, OLEFIN POLYMERIZATION PROCESS 审中-公开
标题翻译：金属配体，金属化合物，烯烃聚合方法
公开(公告)号：WO2005042150A1
公开(公告)日：2005-05-12
申请号：PCT/US2004/030705
申请日：2004-09-17
申请人： FINA TECHNOLOGY, INC. , ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
发明人： ABBAS, Razavi , MARIN, Vladimir , LOPEZ, Margarito
IPC分类号： B01J31/00
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2531/842 , C07F15/025 , C08F10/00 , C08F110/02 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/19 , C08F2500/17 , C08F4/60089 , C08F4/7042
摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C 3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula (I) wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C 1 - C 2 alkyl group, PY is a pyridinyl group, R' and R" are each C 1 - C 20 hydrocarbyl group, A 1 is a mononuclear aromatic group, and A 2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis-amino ligand suitable for use in forming the catalyst component.
摘要翻译：具有Cs对称性的催化剂组合物和利用Cs对称催化剂组分用于烯属不饱和单体聚合以产生聚合物（包括共聚物或均聚物）的方法。聚合或共聚的单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。催化剂组分的特征在于式（I）其中M为4-11族过渡金属，n为1-3的整数，Q为卤素或C1-C2烷基，PY为吡啶基，R '和R“分别为C1-C20烃基，A1为单核芳族基团，A2为三联苯等多元芳香族基团，催化剂成分与铝氧烷等活化助催化剂成分配合使用。还公开了制备适于用于形成催化剂组分的吡啶基连接的双 - 氨基配体的方法。

10. 发明申请

WO99012981A1 POLYMERISATION CATALYSTS 审中-公开
标题翻译：聚合催化剂
公开(公告)号：WO99012981A1
公开(公告)日：1999-03-18
申请号：PCT/GB1998/002638
申请日：1998-09-02
IPC分类号： C08F4/60 , C07D213/53 , C07F13/00 , C07F15/00 , C07F15/02 , C07F15/06 , C08F4/659 , C08F4/6592 , C08F4/70 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/60089 , C08F4/7042 , C08F4/6546
摘要： Catalyst systems useful for the polymerisation of 1-olefins are disclosed, which contain nitrogen-containing transition metal compounds comprising the skeletal unit depicted in Formula (B), wherein M is Fe[II], Fe[III], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R , R , R , R and R are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R and R are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl.
摘要翻译：公开了可用于1-烯烃聚合的催化剂体系，其含有包含式（B）所示骨架单元的含氮过渡金属化合物，其中M为Fe [II]，Fe [III]，Ru [II]， Ru [III]或Ru [IV]; X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4和R 6独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; R 5和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基。

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