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1. 发明申请

WO2004039932A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2004039932A1
公开(公告)日：2004-05-13
申请号：PCT/GB2003/004625
申请日：2003-10-28
申请人： RECKITT BENCKISER N.V. , RECKITT BENCKISER (UK) LIMITED , WIEDEMANN, Ralf , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josee , HAZENKAMP, Menno , RICHTER, Grit , SCHLINGLOFF, Gunther , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter , WIEPRECHT, Torsten
发明人： WIEDEMANN, Ralf , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josee , HAZENKAMP, Menno , RICHTER, Grit , SCHLINGLOFF, Gunther , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter , WIEPRECHT, Torsten
IPC分类号： C11D3/39
CPC分类号： C11D3/3932 , C11D3/168
摘要： An automatic dishwasher detergent formulation comprising: - (a) a metal complex compounds of formula (1) [ L n Me m ,X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a co-ordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z / (charge Y), and L is a ligand of formula (2); wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 1O and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -N(R 13 ) -NR' 13 R ' ' 13 wherein R 13 , R ' 13 and R ' ' 13 are as defined above for R 13 ; -NR 14 NR 15 or - N ⊕ R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them from an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are not simultaneously hydrogen, as a catalyst for oxidation reactions; and (b) an enzyme.
摘要翻译：一种自动洗碗机洗涤剂配方，其包含：（a）式（1）的金属络合物[LnMem，Xp] zq其中Me是锰，钛，铁，钴，镍或铜，X是配位的或桥接基团，n和m各自独立地为具有1至8的整数的整数，p为0至32的整数，z为金属络合物的电荷，Y为计数器 - ，q = z /（电荷Y），L是式（2）的配体; 其中R1，R2，R3，R4，R5，R6，R7，R8，R9，R1O和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; SR13，-SO2R13或-OR13，其中R13各自为氢或未取代或取代的C1-C18烷基或芳基; -N（R 13）-NR 13 R 13，其中R 13，R'13和R“13如上文对R 13所定义; -NR14NR15或-N4R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与氮原子一起与未取代或未取代的取代的5-，6-或7-元环，其可以任选地含有另外的杂原子; 条件是作为氧化反应的催化剂，R1，R2，R3，R4，R5，R6，R7，R8，R9，R10和R11不同时为氢; 和（b）酶。

2. 发明申请

WO0053708A3 WASHING AND CLEANING PROCESS 审中-公开
标题翻译：洗涤和清洁过程
公开(公告)号：WO0053708A3
公开(公告)日：2000-12-28
申请号：PCT/EP0001624
申请日：2000-02-28
申请人： CIBA SC HOLDING AG , HAZENKAMP MENNO , BACHMANN FRANK , MAKOWKA CORNELIA , DUBS MARIE JOSEE , RICHTER GRIT , SCHLINGLOFF GUNTHER , DANNACHER JOSEF
发明人： HAZENKAMP MENNO , BACHMANN FRANK , MAKOWKA CORNELIA , DUBS MARIE-JOSEE , RICHTER GRIT , SCHLINGLOFF GUNTHER , DANNACHER JOSEF
IPC分类号： C11D3/39 , C11D3/395
CPC分类号： C11D3/3932 , C11D3/3947
摘要： A bleaching process within the compass of washing and cleaning processes, which comprises adding to the corresponding liquor comprising a peroxide-containing washing and cleaning agent 1-500 mu mol per litre of liquor of one or more than one compound of the salene type.
摘要翻译：在洗涤和清洁过程的罗盘内进行漂白过程，其包括向相应的液体中加入含有过氧化物的洗涤和清洁剂1-500μmol/升的一种或多种一种或多种salene型化合物的液体。

3. 发明申请

WO2009135813A1 DEGRADABLE MATERIAL 审中-公开
标题翻译：可降解材料
公开(公告)号：WO2009135813A1
公开(公告)日：2009-11-12
申请号：PCT/EP2009/055341
申请日：2009-05-04
申请人： BASF SE , CIBA S.P.A. , PASTI, Claudia , LORENZETTI, Cesare , SCHLINGLOFF, Gunther , GARDI, Stefano , SALA, Massimiliano
发明人： PASTI, Claudia , LORENZETTI, Cesare , SCHLINGLOFF, Gunther , GARDI, Stefano , SALA, Massimiliano
IPC分类号： C08K5/00 , C08K5/098 , C08K5/17 , C08K5/34 , A01G13/02
CPC分类号： A01G13/0275
摘要： A composition containing the components (A), (B-I) and (B-Il) wherein component (A) is an organic polymer; component (B-I) is an amine derivative of the formula (I) N(X 1 )(X 2 )(X 3 ) wherein X 1 is C 8 -C 36 alkyl or C 8 -C 36 alkenyl; X 2 is hydrogen, C 1 C 36 alkyl, C 2 -C 36 alkyl substituted by 1, 2 or 3 radicals selected from the group consisting of -OH and -N(Y 11 )(Y 12 ); C 8 -C 36 alkenyl or C 5 -C 8 cycloalkyl; or X 1 and X 2 , together with the nitrogen atom, form morpholino; X 3 is C 1 C 36 alkyl, C 2 -C 36 alkyl substituted by 1, 2 or 3 radicals selected from the group consisting of -OH and -N(Y 11 )(Y 12 ); C 8 -C 36 alkenyl, C 5 -C 8 cycloalkyl or a group of the formula (a) or the radicals X 2 and X 3 form together a group of the formula (b), (c) or (d) Y 11 and Y 12 are independently of one another hydrogen, C 8 -C 36 alkyl or C 2 -C 36 hydroxyalkyl; Y 21 and Y 22 are independently of one another a group -N(Y 11 )(Y 12 ) or morpholino; Y 31 is C 8 -C 36 alkyl or C 8 -C 38 alkenyl; Y 41 and Y 42 are independently of one another C 8 -C 36 alkyl or C 8 -C 38 alkenyl; Y 51 is C 8 -C 36 alkyl or C 8 -C 36 alkenyl; if X 2 and X 3 form together a group of the formula (d), X 1 can additionally be C 2 -C 36 hydroxyalkyl; and component (B-Il) is an inorganic or organic salt of a transition metal.
摘要翻译：含有组分（A），（B-I）和（B-II）的组合物，其中组分（A）是有机聚合物; 组分（B-I）是式（I）N（X1）（X2）（X3）的胺衍生物，其中X1是C8-C36烷基或C8-C36烯基; X2是氢，C1C36烷基，被1,2或3个选自-OH和-N（Y11）（Y12）的基团取代的C2-C36烷基。 C 8 -C 36烯基或C 5 -C 8环烷基; 或X1和X2与氮原子一起形成吗啉代; X3是C1C36烷基，被1,2和3个选自-OH和-N（Y11）（Y12）的基团取代的C2-C36烷基。 C 8 -C 36烯基，C 5 -C 8环烷基或式（a）的基团或基团X 2和X 3一起形成式（b），（c）或（d）的基团Y 11和Y 12彼此独立地为氢， C 8 -C 36烷基或C 2 -C 36羟烷基; Y 21和Y 22彼此独立地为基团-N（Y 11）（Y 12）或吗啉代; Y31是C8-C36烷基或C8-C38烯基; Y 41和Y 42彼此独立地为C 8 -C 36烷基或C 8 -C 38烯基; Y51为C8-C36烷基或C8-C36烯基; 如果X2和X3一起形成式（d）的基团，则X1可以另外是C 2 -C 36羟烷基; 和组分（B-11）是过渡金属的无机或有机盐。

4. 发明申请

WO2009021270A1 DEGRADABLE POLYMERIC FILMS 审中-公开
标题翻译：可降解的聚合物薄膜
公开(公告)号：WO2009021270A1
公开(公告)日：2009-02-19
申请号：PCT/AU2008/001149
申请日：2008-08-08
申请人： POLYMERS CRC LTD , GEORGE, Graeme , JOHNSTONE, Peter , WARNER, Jamie , HALLEY, Peter , LAYCOCK, Bronwyn , GARDI, Stefano , PASTI, Claudia , SCHLINGLOFF, Gunther
发明人： GEORGE, Graeme , JOHNSTONE, Peter , WARNER, Jamie , HALLEY, Peter , LAYCOCK, Bronwyn , GARDI, Stefano , PASTI, Claudia , SCHLINGLOFF, Gunther
IPC分类号： C08J3/28 , C08K3/22 , C08J11/10 , C08K5/09
CPC分类号： A01G9/1438 , C08J3/28 , C08J5/18 , C08J2323/02 , C08K3/22 , C08K5/098 , Y02A40/252
摘要： A method of controlling the degradation of a polymeric film to cause the film to degrade after an intended useful life time includes providing a polymeric film comprising a polymer and prodegradant for the polymer adapted to be activated on irradiation with a controlled dosage of electromagnetic radiation, activating one or more sources of artificial radiation adapted to emit electromagnetic radiation and irradiating at least part of the polymeric film with the artificial radiation. The electromagnetic radiation comprises wavelengths less than about 400 nm. A system for predisposing a polymeric film containing a prodegradant to degrade after an intended service life includes one or more sources of artificial radiation and an irradiation controller, together with a film dispenser dispensing film into the irradiation zone.
摘要翻译：控制聚合物膜的降解以在预定使用寿命之后降解的方法包括提供聚合物膜，所述聚合物膜包含用于聚合物的聚合物和降解剂，所述聚合物适用于在受控剂量的电磁辐射照射时被活化适于发射电磁辐射的一种或多种人造辐射源并用人造辐射照射聚合物膜的至少一部分。电磁辐射包括小于约400nm的波长。用于在预期使用寿命之后使包含降解降解剂降解的聚合物薄膜的系统包括一种或多种人造辐射源和照射控制器，以及胶片分配器将胶片分配到照射区域中。

5. 发明申请

WO2007090461A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2007090461A1
公开(公告)日：2007-08-16
申请号：PCT/EP2006/050701
申请日：2006-02-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , NIVALKAR, Kishor, Ramachandra , WIEPRECHT, Torsten , DUBS, Marie-Josée , END, Nicole
发明人： SCHLINGLOFF, Gunther , NIVALKAR, Kishor, Ramachandra , WIEPRECHT, Torsten , DUBS, Marie-Josée , END, Nicole
IPC分类号： B01J31/18 , C07B33/00 , A61L2/18 , A61L2/23 , A61L12/12 , C11D3/39 , C11D17/00 , D06L3/02 , D06M11/32 , D06M11/50 , D21C9/16 , C02F1/72 , C02F1/74 , C07D213/22 , C07D401/14
CPC分类号： B01J31/1835 , A61L2/186 , A61L2/23 , A61L12/124 , A61L12/128 , A61L2202/17 , A61L2202/26 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/184 , B01J2231/70 , B01J2531/0258 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C02F1/683 , C02F1/722 , C02F1/725 , C02F2303/04 , C07D213/22 , C07D213/74 , C07D401/14 , C07D471/04 , C11D3/3932 , C11D17/0039 , C11D17/06 , D06M11/32 , D06M11/50 , D21C9/1036 , D21C9/163
摘要： The present invention relates to the use, as oxidation catalysts, of metal complex compounds having tetradentate ligands of formula (2) wherein all subsitutents have the meanings as defined in Claim 1. The present invention relates also to formulations comprising such metal complex compounds, to novel metal complex compounds and to novel ligands.
摘要翻译：本发明涉及作为氧化催化剂的具有式（2）的四齿配体的金属络合物的用途，其中所有的取代基具有如权利要求1中所定义的含义。本发明还涉及包含这种金属络合物的制剂，新型金属络合物和新配体。

6. 发明申请

WO2007131919A1 POLYMER ARTICLE MODIFIED WITH A METAL CATION CONTAINING COMPOUND 审中-公开
标题翻译：用含金属化合物改性的聚合物制品
公开(公告)号：WO2007131919A1
公开(公告)日：2007-11-22
申请号：PCT/EP2007/054462
申请日：2007-05-09
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CIBA SPECIALTY CHEMICALS S.P.A. , GARDI, Stefano , SALA, Massimiliano , SCHLINGLOFF, Gunther
发明人： GARDI, Stefano , SALA, Massimiliano , SCHLINGLOFF, Gunther
IPC分类号： C08L23/08 , C08K5/098 , C08F210/02 , C08J5/18
CPC分类号： C08J5/18 , C08F8/44 , C08J3/226 , C08J2323/00 , C08J2423/00 , C08K5/005 , C08K5/098 , C08L23/0815 , C08L23/0876 , Y10T428/1334 , Y10T428/139 , C08F20/06 , C08F210/02 , C08L2666/04 , C08L2666/02
摘要： An agricultural article made of a composition containing (a) an organic polymer, and (b-I) a polyacrylic acid sodium salt or a sodium salt of ethylene/methacrylic acid copolymer, and (b-II) manganese stearate.
摘要翻译：由（a）有机聚合物和（b-I）聚丙烯酸钠盐或乙烯/甲基丙烯酸共聚物的钠盐和（b-II）硬脂酸锰组成的组合物制成的农业制品。

7. 发明申请

WO2005105303A1 USE OF METAL COMPLEXES HAVING BISPYRIDYLPYRIMIDINE OR BISPYRIDYLTRIAZINE LIGANDS AS CATALYSTS FOR REACTIONS WITH PEROXY COMPOUNDS FOR BLEACHING COLOURED STAINS ON HARD SURFACES 审中-公开
标题翻译：作为具有过氧化合物的反应用于将硬化表面上的着色物质漂白的反应的金属络合物用作双嘧啶基吡啶或双嘧啶系配体
公开(公告)号：WO2005105303A1
公开(公告)日：2005-11-10
申请号：PCT/EP2005/051732
申请日：2005-04-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , WIEPRECHT, Torsten , DUBS, Marie-Josée , SCHLINGLOFF, Gunther
发明人： WIEPRECHT, Torsten , DUBS, Marie-Josée , SCHLINGLOFF, Gunther
IPC分类号： B01J31/18
CPC分类号： B01J31/1815 , B01J31/182 , C07D401/14 , C11D3/3932 , C11D11/0023
摘要： The present invention relates to the use of certain manganese complexes having bispyridylpyrimidine or bispyridyltriazine ligands or mixtures of such ligands as catalysts for reactions with peroxy compounds for bleaching coloured stains on hard surfaces, especially dishes in automatic dishwashers. The invention relates also to cleaning formulations for hard surfaces comprising such catalysts.
摘要翻译：本发明涉及具有双吡啶基嘧啶或双吡啶基三嗪配体的某些锰配合物或这些配体的混合物作为与过氧化合物反应的催化剂用于漂白硬表面上的着色污渍，特别是自动洗碗机中的餐具的用途。本发明还涉及包含这种催化剂的硬表面的清洁制剂。

8. 发明申请

WO2005068075A1 USE OF A COMPOSITION COMPRISING METAL COMPLEX COMPOUNDS AND POLYPHOSPHONATES AS CATALYSTS FOR OXIDATIONS 审中-公开
标题翻译：使用包含金属复合化合物和聚氧乙烯醚作为催化剂进行氧化的组合物
公开(公告)号：WO2005068075A1
公开(公告)日：2005-07-28
申请号：PCT/EP2005/050003
申请日：2005-01-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , HEINZ, Uwe , WIEPRECHT, Torsten , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
发明人： HEINZ, Uwe , WIEPRECHT, Torsten , XIA, Juntao , SCHLINGLOFF, Gunther , DUBS, Marie-Josée
IPC分类号： B01J31/18
CPC分类号： B01J31/0259 , B01J31/0201 , B01J31/1815 , B01J31/182 , B01J2231/70 , B01J2231/72 , B01J2531/0238 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/84 , B01J2531/96 , B01J2540/42 , C11D3/364 , C11D3/3932 , C11D3/3935
摘要： The invention accordingly relates to the use of a composition comprising (i) at least one metal complex of formula (1) [L n Me m X p ] Z Y q (1), wherein all substituents have the meanings as defined in the claims and (ii) at least one polyphosphonate as oxidation catalyst for peroxide compounds, as well as to novel detergent compositions.
摘要翻译：因此，本发明涉及包含（i）至少一种式（1）的金属络合物[Ln MemXp] Yq（1））的组合物的用途，其中所有取代基具有如权利要求中所定义的含义，和（ii ）至少一种聚膦酸酯作为过氧化物化合物的氧化催化剂，以及新型洗涤剂组合物。

9. 发明申请

WO2004007657A1 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2004007657A1
公开(公告)日：2004-01-22
申请号：PCT/EP2003/007121
申请日：2003-07-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Josef , DUBS, Marie-Josée , HAZENKAMP, Menno , HEINZ, Uwe , FREY, Markus , SCHNEIDER, Albert
IPC分类号： C11D3/395
CPC分类号： C11D3/168 , C07D213/68 , C07D213/74 , C11D3/3932
摘要： Use of metal complex compounds of formula (1) [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 12 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N o R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R 15 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C 1 -C 6 alkylene)-N o R 14 R 15 R 16 , -N[C 1 -C 6 alkylene)-N o R 14 R 15 R 16 ] 2 ; -N(R 13 )-N-R 14 R 15 or -N(R 13 )-N o R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R 1 -R 11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I' nor CI' in the case that Me is Mn(II), R 1 -R 5 and R 7 -R 11 are hydrogen and R 6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.
摘要翻译：使用式（1）的金属络合物[LnMemXp] zq其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥键基团，n和m各自独立地为整数值为1〜8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为是式（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 12 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - （C 1 -C 6亚烷基）-NR 14 R 15; -N R14R15R16; - （C 1 -C 6亚烷基）-N R14R15R16; -N（R13） - （C 1 -C 6亚烷基）-NR 14 R 15; -N [（C1-C6亚烷基）-NR 14 R 15] 2; -N（R 13） - （C 1 -C 6亚烷基）-N 14 R 15 R 16，-N [C 1 -C 6亚烷基）-N R 14 R 15 R 16] 2; -N（R 13）-N-R 14 R 15或-N（R 13）-N R 14 R 15 R 16，其中R 13如上所定义，R 14，R 15和R 16各自独立地为氢或未取代或取代的C1- C 18烷基或芳基，或R 14和R 15与与它们键合的氮原子一起形成未取代或取代的5-，6-或7-元环，其可以任选地含有其它杂原子; 条件是（i）至少一个取代基R 1 -R 11含有不直接与三个吡啶A，B或C中的一个键合的季铵化原子，并且（ii）Y不是I'和Cl' Me是Mn（II），R1-R5和R7-R11是氢的情况，R6是作为氧化反应的催化剂的式（III），式（1）的新型金属络合物，式 2）及其起始材料。

10. 发明申请

WO2002088289A2 USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 审中-公开
标题翻译：使用金属复合化合物作为氧化催化剂
公开(公告)号：WO2002088289A2
公开(公告)日：2002-11-07
申请号：PCT/EP2002/004572
申请日：2002-04-25
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , RICHTER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
发明人： SCHLINGLOFF, Gunther , WIEPRECHT, Torsten , BACHMANN, Frank , DANNACHER, Joseph , DUBS, Marie-Josée , HAZENKAMP, Menno , RICHTER, Grit , SCHMIDT, Brigitte , SCHNEIDER, Albert , WEINGARTNER, Peter
IPC分类号： C11D3/39
CPC分类号： B01J31/1815 , B01J23/34 , B01J2231/70 , B01J2231/72 , B01J2531/16 , B01J2531/46 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07D213/61 , C07D213/68 , C07D213/74 , C07F13/005 , C11D3/3932 , D06L4/10 , D06L4/12 , D06P5/02 , D06P5/153 , D21C9/1036 , D21C9/163
摘要： Use of metal complex compounds of formula (1): [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl;-N(R 13 )-NR' 13 R" 13 wherein R 13 , R' 13 and R" 13 are as defined above for R 13 ; -NR 14 R 15 or -N + R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , and R 11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).
摘要翻译：使用式（1）的金属络合物：其中Me是锰，钛，铁，钴，镍或铜，X是配位或桥接基团，n和m各自独立地为具有1至8的整数，p为0至32的整数，z为金属络合物的电荷，y为抗衡离子，q = z /（电荷Y），L是式（2）的配体，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R 13）-NR 13 R 13，其中R 13，R 13和R 13如上定义对于R13; -NR14R15或-N + R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与键合氮原子一起形成未取代或未取代的取代的5-，6-或7-元环，其可以任选地含有另外的杂原子; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且新的式（1）金属络合物和式（2）的新配体。

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