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    • 1. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 使用金属复合化合物作为氧化催化剂
    • WO2004039932A1
    • 2004-05-13
    • PCT/GB2003/004625
    • 2003-10-28
    • RECKITT BENCKISER N.V.RECKITT BENCKISER (UK) LIMITEDWIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • WIEDEMANN, RalfBACHMANN, FrankDANNACHER, JosephDUBS, Marie-JoseeHAZENKAMP, MennoRICHTER, GritSCHLINGLOFF, GuntherSCHMIDT, BrigitteSCHNEIDER, AlbertWEINGARTNER, PeterWIEPRECHT, Torsten
    • C11D3/39
    • C11D3/3932C11D3/168
    • An automatic dishwasher detergent formulation comprising: - (a) a metal complex compounds of formula (1) [ L n Me m ,X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a co-ordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z / (charge Y), and L is a ligand of formula (2); wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 1O and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -N(R 13 ) -NR' 13 R ' ' 13 wherein R 13 , R ' 13 and R ' ' 13 are as defined above for R 13 ; -NR 14 NR 15 or - N ⊕ R 14 R 15 R 16 wherein R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them from an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are not simultaneously hydrogen, as a catalyst for oxidation reactions; and (b) an enzyme.
    • 一种自动洗碗机洗涤剂配方,其包含:(a)式(1)的金属络合物[LnMem,Xp] zq其中Me是锰,钛,铁,钴,镍或铜,X是配位的 或桥接基团,n和m各自独立地为具有1至8的整数的整数,p为0至32的整数,z为金属络合物的电荷,Y为计数器 - ,q = z /(电荷Y),L是式(2)的配体; 其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R1O和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; SR13,-SO2R13或-OR13,其中R13各自为氢或未取代或取代的C1-C18烷基或芳基; -N(R 13)-NR 13 R 13,其中R 13,R'13和R“13如上文对R 13所定义; -NR14NR15或-N4R15R16,其中R14,R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或者R14和R15与氮原子一起与未取代或未取代的 取代的5-,6-或7-元环,其可以任选地含有另外的杂原子; 条件是作为氧化反应的催化剂,R1,R2,R3,R4,R5,R6,R7,R8,R9,R10和R11不同时为氢; 和(b)酶。
    • 4. 发明申请
    • DISHWASHING COMPOSITION
    • 洗碗组合物
    • WO2002072288A1
    • 2002-09-19
    • PCT/GB2002/001001
    • 2002-03-13
    • RECKITT BENCKISER N.V.RECKITT BENCKISER (UK) LIMITEDSCHMIDT, JürgenWIEDEMANN, RalfGIBIS, Karl-LudwigCARBONELL, Enric
    • SCHMIDT, JürgenWIEDEMANN, RalfGIBIS, Karl-LudwigCARBONELL, Enric
    • B08B3/10
    • D06F35/003A47L15/0055C11D3/0063C11D11/007C11D17/0039
    • This invention is related to a process for the controlled release into a cleaning environment of an active ingredient of a detergent or detergent additive composition wherein the cleaning environment, to which the detergent or detergent additive composition has been delivered, is exposed to an electric, magnetic or electromagnetic field at an appropriate point in time and for an appropriate time period wherein the release is effective by chemical and/or physical modification, initiated by said field, of at least one specific compound, the modified compound not being directly involved in bleaching; a detergent or detergent additive component with such functionality; a detergent or detergent composition comprising such detergent or detergent additive component; processes for cleaning dishes in an automatic dishwashing machine or for washing fabrics in a laundry washing machine using such detergent compositions; as well as the use of an electric, magnetic or electromagnetic field to control the release of an active detergent ingredient from a source thereof by selectively exposing the environment to which the source has been delivered to such a field.
    • 本发明涉及一种用于将洗涤剂或洗涤剂添加剂组合物的活性成分控制释放到清洁环境中的方法,其中洗涤剂或洗涤剂添加剂组合物已被输送到其上的清洁环境暴露于电磁场 或电磁场在合适的时间点和适当的时间段,其中释放通过化学和/或物理修饰由所述领域启动,至少一种特定化合物,所述改性化合物不直接参与漂白; 具有这种功能的洗涤剂或洗涤剂添加剂组分; 包含这种洗涤剂或洗涤添加剂组分的洗涤剂或洗涤剂组合物 使用这种洗涤剂组合物在洗衣机中清洗自动洗碗机中的菜肴或洗涤织物的方法; 以及使用电,磁或电磁场通过选择性地将源已经被输送到的环境暴露于这样的场,来控制活性洗涤剂成分从其源的释放。